掺铬 45S 生物活性玻璃陶瓷的制备、表征和光学分析

IF 0.5 Q4 ENGINEERING, BIOMEDICAL
I. S. Çardaklı
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引用次数: 0

摘要

本研究成功制备了 45S 生物活性玻璃陶瓷 (BG) 和掺铬(Cr)BG 材料。利用 XRD、FTIR 和 ICP-MS 技术对制备的材料进行了表征。XRD 测试表明,所有样品都含有纯 BG。铬离子含量的增加使 BG 衍射峰向较低的 2 Theta 值移动,并增加了结晶度。傅立叶变换红外光谱用于检测 Si-O、P-O 和 Ca-O 官能团。铬离子使 Ca-振动模式面积稳步减少。紫外-可见分光光度法用于测量纯材料和掺杂铬的 BG 的光学特性。掺杂铬的 BG 呈绿色,而实验室合成的 BG 呈白色。在 BG 结构中掺入铬离子后,在波长 433 纳米和 615 纳米处形成了两个额外的波段。这些波段可能是由 4A2 → 4T1 和 4A2 → 4T2 电子 d-d 转变引起的。研究结果表明,用 Cr-BG 材料制造的荧光探针可应用于生物医学领域。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Preparation, Characterization and Optical Analysis of Chromium Doped 45S Bioactive Glass-Ceramic
The 45S Bioactive glass-ceramic (BG) and Chromium (Cr)-doped BG materials were successfully produced in this study. XRD, FTIR, and ICP-MS techniques were used to characterize the prepared materials. The XRD testing showed that all samples contained pure BG. Increased Cr ion inclusion shifted the BG diffraction peaks to a lower value of 2 Theta and increased crystallinity. FTIR was used to detect Si-O, P-O, and Ca-O functional groups. Cr ions steadily decreased the Ca-vibration mode area. The ultraviolet-visible spectrophotometry was used to measure the optical characteristics of pure and Cr BG-doped materials. The Cr-doped BG was green in colour, whereas the lab-synthesized BG was white. Two additional bands formed at 433 and 615 nm when Cr ions were doped into the BG structure. These bands may be caused by 4A2 → 4T1 and 4A2 → 4T2 electronic d-d transitions. The findings show that biomedical applications may exist for fluorescent probes manufactured from Cr-BG materials.
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来源期刊
CiteScore
1.40
自引率
14.30%
发文量
73
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