利用 DSC 和 Logger Pro 对 8OCB 液晶进行等温和非等温研究

Grace Petrarca, Dipti Sharma (PhD)
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引用次数: 0

摘要

本研究的重点是探索 4-氧-4'-氰基联苯(8OCB)液晶(LC)的等温和非等温特性。本文报告了通过 DSC 技术收集到的数据,以及 8OCB 在加热 0°C/100°C 和冷却 100°C/-40°C 时的行为,升温速率分别为 5、10 和 20°C/分钟。我们使用 LoggerPro 程序计算了热速度、加速度和跃迁,以进一步了解分子的行为,观察重复加热和冷却对 8OCB 的影响,以及这与液晶显示器 (LCD) 中使用的 LC 的关系,特别是观察向列相是否有任何类型的降解。这些数据可以用来与在加热和冷却阶段期间、之前和之间收集的热流数据进行比较,以了解在温度不变的情况下,持续加热和冷却的斜率增加对分子的进一步影响。可以看出,随着斜率的增加,DSC 的等温段的热流也在增加,这对于向列液晶显示器的应用是非常重要的。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Isothermal and Non-Isothermal Study of 8OCB Liquid Crystal using DSC and Logger Pro.
The focus of this research is to explore the isothermal and non-isothermal properties of 4-oxy-4'-cyano­biphenyls (8OCB) Liquid Crystal (LC). This paper reports on the data collected from the technique of DSC and the behavior of 8OCB when heated 0°C/100°C and cooled 100°C/-40°C for ramp rates of 5, 10, and 20 °C/min. The thermal speed, acceleration, and jerk we calculated using the program LoggerPro to further understand the molecules' behavior to observe the effects of repetitive heating and cooling on 8OCB and how that would relate to LC’s use in Liquid Crystal Displays (LCDs), specifically looking at if there is any type of degradation in the nematic phase. This data can be used to compare to data collected on the heat flow during, before, and in between the heating and cooling phases to understand how the molecule is further affected by increased ramp rates of constant heating and cooling at times when the temperature is not changing. The isothermal segments of the DSC were seen to have increased heat flow as the ramp rate was increased which is important to consider when applying to the application of nematic LCDs.
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