{"title":"碱催化烯丙基醇的多米诺异构化/无氧脱氢环化:范围、机理和应用。","authors":"Xiongyang Zhou, Xun Li, Cheng Le, Jia-Qi Li","doi":"10.1002/adsc.202400879","DOIUrl":null,"url":null,"abstract":"<p>The front cover picture illustrates the synthesis of quinolines based on the strategy of isomerization of allylic alcohols catalyzed by the complex of 1,10-phenanthroline and <sup><i>t</i></sup>BuONa. The honeycomb symbolizes the catalyst and development of bees metaphorize the domino isomerization/oxidant-free dehydrogenative annulation sequences. The flying bees stand for the application of this protocol for the synthesis of bioactive molecules. Details can be found in the research article by Jia-Qi Li and co-workers (X. Zhou, X. Li, C. Le, J.-Q. Li, <i>Adv. Synth. Catal</i>. <b>2024</b>, <i>366</i>, 3316–3322; DOI: 10.1002/adsc.202400465)\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure>\n </p>","PeriodicalId":118,"journal":{"name":"Advanced Synthesis & Catalysis","volume":null,"pages":null},"PeriodicalIF":4.4000,"publicationDate":"2024-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adsc.202400879","citationCount":"0","resultStr":"{\"title\":\"Front Cover Picture: Base-Catalyzed Domino Isomerization/Oxidant-Free Dehydrogenative Annulation of Allylic Alcohols: Scope, Mechanism, and Application (Adv. Synth. Catal. 15/2024)\",\"authors\":\"Xiongyang Zhou, Xun Li, Cheng Le, Jia-Qi Li\",\"doi\":\"10.1002/adsc.202400879\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The front cover picture illustrates the synthesis of quinolines based on the strategy of isomerization of allylic alcohols catalyzed by the complex of 1,10-phenanthroline and <sup><i>t</i></sup>BuONa. The honeycomb symbolizes the catalyst and development of bees metaphorize the domino isomerization/oxidant-free dehydrogenative annulation sequences. The flying bees stand for the application of this protocol for the synthesis of bioactive molecules. Details can be found in the research article by Jia-Qi Li and co-workers (X. Zhou, X. Li, C. Le, J.-Q. Li, <i>Adv. Synth. Catal</i>. <b>2024</b>, <i>366</i>, 3316–3322; DOI: 10.1002/adsc.202400465)\\n <figure>\\n <div><picture>\\n <source></source></picture><p></p>\\n </div>\\n </figure>\\n </p>\",\"PeriodicalId\":118,\"journal\":{\"name\":\"Advanced Synthesis & Catalysis\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":4.4000,\"publicationDate\":\"2024-07-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adsc.202400879\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advanced Synthesis & Catalysis\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/adsc.202400879\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Synthesis & Catalysis","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/adsc.202400879","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
引用次数: 0
摘要
封面图片说明了基于 1,10-菲罗啉和 tBuONa 复合物催化的烯丙基醇异构化策略合成喹啉的过程。蜂巢象征着催化剂,蜜蜂的发展隐喻着多米诺异构化/无氧化剂脱氢环化序列。飞舞的蜜蜂代表着该方案在生物活性分子合成中的应用。详情请见李佳琦及其合作者的研究文章(X. Zhou, X. Li, C. Le, J.-Q. Li, Adv. Synth.Li,Adv.Catal.2024, 366, DOI: 10.1002/adsc.202400465)
Front Cover Picture: Base-Catalyzed Domino Isomerization/Oxidant-Free Dehydrogenative Annulation of Allylic Alcohols: Scope, Mechanism, and Application (Adv. Synth. Catal. 15/2024)
The front cover picture illustrates the synthesis of quinolines based on the strategy of isomerization of allylic alcohols catalyzed by the complex of 1,10-phenanthroline and tBuONa. The honeycomb symbolizes the catalyst and development of bees metaphorize the domino isomerization/oxidant-free dehydrogenative annulation sequences. The flying bees stand for the application of this protocol for the synthesis of bioactive molecules. Details can be found in the research article by Jia-Qi Li and co-workers (X. Zhou, X. Li, C. Le, J.-Q. Li, Adv. Synth. Catal. 2024, 366, 3316–3322; DOI: 10.1002/adsc.202400465)
期刊介绍:
Advanced Synthesis & Catalysis (ASC) is the leading primary journal in organic, organometallic, and applied chemistry.
The high impact of ASC can be attributed to the unique focus of the journal, which publishes exciting new results from academic and industrial labs on efficient, practical, and environmentally friendly organic synthesis. While homogeneous, heterogeneous, organic, and enzyme catalysis are key technologies to achieve green synthesis, significant contributions to the same goal by synthesis design, reaction techniques, flow chemistry, and continuous processing, multiphase catalysis, green solvents, catalyst immobilization, and recycling, separation science, and process development are also featured in ASC. The Aims and Scope can be found in the Notice to Authors or on the first page of the table of contents in every issue.