Van Nhieu Le, Hoai Duc Tran, Minh Tien Nguyen, Hai Bang Truong, Toan Minh Pham, Jinsoo Kim
{"title":"从 Fe2O3 纳米颗粒轻松合成铁基金属有机框架及其在 CO2/N2 分离中的应用。","authors":"Van Nhieu Le, Hoai Duc Tran, Minh Tien Nguyen, Hai Bang Truong, Toan Minh Pham, Jinsoo Kim","doi":"10.3762/bjnano.15.74","DOIUrl":null,"url":null,"abstract":"<p><p>A facile approach was employed to fabricate MIL-100(Fe) materials from Fe<sub>2</sub>O<sub>3</sub> nanoparticles through a conventional hydrothermal reaction without the presence of HF and HNO<sub>3</sub>. Effects of trimesic acid content in the reaction system on the quality and CO<sub>2</sub>/N<sub>2</sub> separation performance of the as-prepared MIL-100(Fe) samples were investigated. Using 1.80 g of trimesic acid in the reaction system yielded the sample M-100Fe@Fe<sub>2</sub>O<sub>3</sub>#1.80, which proved to be the optimal sample. This choice struck a balance between the amount of required trimesic acid and the quality of the resulting material, resulting in a high yield of 81% and an impressive BET surface area of 1365.4 m<sup>2</sup>·g<sup>-1</sup>. At 25 °C and 1 bar, M-100Fe@Fe<sub>2</sub>O<sub>3</sub>#1.80 showed a CO<sub>2</sub> adsorption capacity of 1.10 mmol·g<sup>-1</sup> and an IAST-predicted CO<sub>2</sub>/N<sub>2</sub> selectivity of 18, outperforming conventional adsorbents in CO<sub>2</sub>/N<sub>2</sub> separation. Importantly, this route opens a new approach to utilizing Fe<sub>2</sub>O<sub>3</sub>-based waste materials from the iron and steel industry in manufacturing Fe-based MIL-100 materials.</p>","PeriodicalId":8802,"journal":{"name":"Beilstein Journal of Nanotechnology","volume":"15 ","pages":"897-908"},"PeriodicalIF":2.6000,"publicationDate":"2024-07-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11285048/pdf/","citationCount":"0","resultStr":"{\"title\":\"Facile synthesis of Fe-based metal-organic frameworks from Fe<sub>2</sub>O<sub>3</sub> nanoparticles and their application for CO<sub>2</sub>/N<sub>2</sub> separation.\",\"authors\":\"Van Nhieu Le, Hoai Duc Tran, Minh Tien Nguyen, Hai Bang Truong, Toan Minh Pham, Jinsoo Kim\",\"doi\":\"10.3762/bjnano.15.74\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>A facile approach was employed to fabricate MIL-100(Fe) materials from Fe<sub>2</sub>O<sub>3</sub> nanoparticles through a conventional hydrothermal reaction without the presence of HF and HNO<sub>3</sub>. Effects of trimesic acid content in the reaction system on the quality and CO<sub>2</sub>/N<sub>2</sub> separation performance of the as-prepared MIL-100(Fe) samples were investigated. Using 1.80 g of trimesic acid in the reaction system yielded the sample M-100Fe@Fe<sub>2</sub>O<sub>3</sub>#1.80, which proved to be the optimal sample. This choice struck a balance between the amount of required trimesic acid and the quality of the resulting material, resulting in a high yield of 81% and an impressive BET surface area of 1365.4 m<sup>2</sup>·g<sup>-1</sup>. At 25 °C and 1 bar, M-100Fe@Fe<sub>2</sub>O<sub>3</sub>#1.80 showed a CO<sub>2</sub> adsorption capacity of 1.10 mmol·g<sup>-1</sup> and an IAST-predicted CO<sub>2</sub>/N<sub>2</sub> selectivity of 18, outperforming conventional adsorbents in CO<sub>2</sub>/N<sub>2</sub> separation. Importantly, this route opens a new approach to utilizing Fe<sub>2</sub>O<sub>3</sub>-based waste materials from the iron and steel industry in manufacturing Fe-based MIL-100 materials.</p>\",\"PeriodicalId\":8802,\"journal\":{\"name\":\"Beilstein Journal of Nanotechnology\",\"volume\":\"15 \",\"pages\":\"897-908\"},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2024-07-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11285048/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Beilstein Journal of Nanotechnology\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.3762/bjnano.15.74\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2024/1/1 0:00:00\",\"PubModel\":\"eCollection\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Beilstein Journal of Nanotechnology","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.3762/bjnano.15.74","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/1/1 0:00:00","PubModel":"eCollection","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Facile synthesis of Fe-based metal-organic frameworks from Fe2O3 nanoparticles and their application for CO2/N2 separation.
A facile approach was employed to fabricate MIL-100(Fe) materials from Fe2O3 nanoparticles through a conventional hydrothermal reaction without the presence of HF and HNO3. Effects of trimesic acid content in the reaction system on the quality and CO2/N2 separation performance of the as-prepared MIL-100(Fe) samples were investigated. Using 1.80 g of trimesic acid in the reaction system yielded the sample M-100Fe@Fe2O3#1.80, which proved to be the optimal sample. This choice struck a balance between the amount of required trimesic acid and the quality of the resulting material, resulting in a high yield of 81% and an impressive BET surface area of 1365.4 m2·g-1. At 25 °C and 1 bar, M-100Fe@Fe2O3#1.80 showed a CO2 adsorption capacity of 1.10 mmol·g-1 and an IAST-predicted CO2/N2 selectivity of 18, outperforming conventional adsorbents in CO2/N2 separation. Importantly, this route opens a new approach to utilizing Fe2O3-based waste materials from the iron and steel industry in manufacturing Fe-based MIL-100 materials.
期刊介绍:
The Beilstein Journal of Nanotechnology is an international, peer-reviewed, Open Access journal. It provides a unique platform for rapid publication without any charges (free for author and reader) – Platinum Open Access. The content is freely accessible 365 days a year to any user worldwide. Articles are available online immediately upon publication and are publicly archived in all major repositories. In addition, it provides a platform for publishing thematic issues (theme-based collections of articles) on topical issues in nanoscience and nanotechnology.
The journal is published and completely funded by the Beilstein-Institut, a non-profit foundation located in Frankfurt am Main, Germany. The editor-in-chief is Professor Thomas Schimmel – Karlsruhe Institute of Technology. He is supported by more than 20 associate editors who are responsible for a particular subject area within the scope of the journal.