基于 N-2-(2-吡啶基)乙基-2-氨基乙磺酸的铜(II)络合物的合成与结构

IF 16.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Accounts of Chemical Research Pub Date : 2024-07-26 DOI:10.1134/S0022476624070102

E. O. Zemlyakova, G. P. Zharkov, Y. S. Petrova, L. K. Neudachina, P. A. Slepukhin, T. V. Aksenova, A. V. Pestov

{"title":"基于 N-2-(2-吡啶基)乙基-2-氨基乙磺酸的铜(II)络合物的合成与结构","authors":"E. O. Zemlyakova, G. P. Zharkov, Y. S. Petrova, L. K. Neudachina, P. A. Slepukhin, T. V. Aksenova, A. V. Pestov","doi":"10.1134/S0022476624070102","DOIUrl":null,"url":null,"abstract":"A novel copper(II) complex based on N-2-(2-pyridyl)ethyl-2-aminoethanesulfonic acid is prepared, its structure is studied by XRD (CCDC No. 2215117). The crystal of the complex is formed by monomeric [CuLH2O]NO3 units. The metal centers of the units have an octahedral coordination environment formed by nitrogen atoms of pyridine and the amino group, oxygen atoms of the sulfo group, and water molecules located in the equatorial plane. On the axial axis, there are oxygen atoms of the sulfo groups of the neighboring ligands forming a 1D coordination polymer.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2024-07-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Structure of a Copper(II) Complex Based on N-2-(2-pyridyl)Ethyl-2-Aminoethanesulfonic Acid\",\"authors\":\"E. O. Zemlyakova, G. P. Zharkov, Y. S. Petrova, L. K. Neudachina, P. A. Slepukhin, T. V. Aksenova, A. V. Pestov\",\"doi\":\"10.1134/S0022476624070102\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A novel copper(II) complex based on N-2-(2-pyridyl)ethyl-2-aminoethanesulfonic acid is prepared, its structure is studied by XRD (CCDC No. 2215117). The crystal of the complex is formed by monomeric [CuLH2O]NO3 units. The metal centers of the units have an octahedral coordination environment formed by nitrogen atoms of pyridine and the amino group, oxygen atoms of the sulfo group, and water molecules located in the equatorial plane. On the axial axis, there are oxygen atoms of the sulfo groups of the neighboring ligands forming a 1D coordination polymer.\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":16.4000,\"publicationDate\":\"2024-07-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0022476624070102\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0022476624070102","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

摘要制备了一种基于 N-2-(2-吡啶基)乙基-2-氨基乙磺酸的新型铜(II)配合物，并对其结构进行了 XRD 研究（CCDC 编号：2215117）。该配合物的晶体由单体 [CuLH2O]NO3 单元组成。单元的金属中心具有一个由吡啶和氨基的氮原子、磺基的氧原子以及位于赤道面的水分子形成的八面体配位环境。在轴向，相邻配体的磺基氧原子形成了一维配位聚合物。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Synthesis and Structure of a Copper(II) Complex Based on N-2-(2-pyridyl)Ethyl-2-Aminoethanesulfonic Acid

查看原文本刊更多论文

Synthesis and Structure of a Copper(II) Complex Based on N-2-(2-pyridyl)Ethyl-2-Aminoethanesulfonic Acid

A novel copper(II) complex based on N-2-(2-pyridyl)ethyl-2-aminoethanesulfonic acid is prepared, its structure is studied by XRD (CCDC No. 2215117). The crystal of the complex is formed by monomeric [CuLH₂O]NO₃ units. The metal centers of the units have an octahedral coordination environment formed by nitrogen atoms of pyridine and the amino group, oxygen atoms of the sulfo group, and water molecules located in the equatorial plane. On the axial axis, there are oxygen atoms of the sulfo groups of the neighboring ligands forming a 1D coordination polymer.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Accounts of Chemical Research 化学-化学综合

CiteScore

31.40

自引率

1.10%

发文量

312

审稿时长

2 months

期刊介绍： Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.