{"title":"镍铁氧体纳米流体的导电性:关于温度、体积分数和基液影响的实验研究","authors":"","doi":"10.1016/j.nanoso.2024.101266","DOIUrl":null,"url":null,"abstract":"<div><p>This study investigates the electrical conductivity of NiFe<sub>2</sub>O<sub>4</sub> nanofluids in water and ethylene glycol (EG) as base fluids, aiming to understand how varying volume fractions (φ= 0 %, 0.1 %, 0.25 %, 0.45 %, 0.7 %, and 1 %) and temperatures (20–70°C) influence electrical conductivity. NiFe<sub>2</sub>O<sub>4</sub> nanoparticles were synthesized using the chemical co-precipitation method and characterized through X-ray Diffraction (XRD), Field Emission Scanning Electron Microscopy (FESEM), and Energy Dispersive Spectroscopy (EDS). The results revealed that at 70°C, the electrical conductivity of NiFe<sub>2</sub>O<sub>4</sub>-water nanofluid increased by 1100 % within the volume fraction range of 0–1 %. For NiFe<sub>2</sub>O<sub>4</sub>-EG nanofluid, the increase in electrical conductivity was even more significant, reaching 1235 % within the same volume fraction range. Similarly, at a 1 % volume fraction within the temperature range of 20–70°C, the electrical conductivity of NiFe<sub>2</sub>O<sub>4</sub>-water nanofluid increased by 136 %, while for NiFe<sub>2</sub>O<sub>4</sub>-EG nanofluid, it was 370 %. These findings indicate that both temperature and volume fraction significantly enhance the electrical conductivity of the nanofluids, with a more pronounced effect observed in the NiFe<sub>2</sub>O<sub>4</sub>-EG nanofluid compared to the NiFe<sub>2</sub>O<sub>4</sub>-water nanofluid. The study validated Shen et al.'s model for electrical conductivity in nanofluids, contrasting with Maxwell's model. The novelty of this work lies in the comprehensive analysis of the electrical conductivity behavior of these nanofluids, which has not been extensively reported in the literature. These findings have potential applications in heat transfer enhancement and magnetic-targeted drug delivery.</p></div>","PeriodicalId":397,"journal":{"name":"Nano-Structures & Nano-Objects","volume":null,"pages":null},"PeriodicalIF":5.4500,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Electrical conductivity of Ni ferrite nanofluids: An experimental study on the effects of temperature, volume fraction, and base fluid\",\"authors\":\"\",\"doi\":\"10.1016/j.nanoso.2024.101266\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>This study investigates the electrical conductivity of NiFe<sub>2</sub>O<sub>4</sub> nanofluids in water and ethylene glycol (EG) as base fluids, aiming to understand how varying volume fractions (φ= 0 %, 0.1 %, 0.25 %, 0.45 %, 0.7 %, and 1 %) and temperatures (20–70°C) influence electrical conductivity. NiFe<sub>2</sub>O<sub>4</sub> nanoparticles were synthesized using the chemical co-precipitation method and characterized through X-ray Diffraction (XRD), Field Emission Scanning Electron Microscopy (FESEM), and Energy Dispersive Spectroscopy (EDS). The results revealed that at 70°C, the electrical conductivity of NiFe<sub>2</sub>O<sub>4</sub>-water nanofluid increased by 1100 % within the volume fraction range of 0–1 %. For NiFe<sub>2</sub>O<sub>4</sub>-EG nanofluid, the increase in electrical conductivity was even more significant, reaching 1235 % within the same volume fraction range. Similarly, at a 1 % volume fraction within the temperature range of 20–70°C, the electrical conductivity of NiFe<sub>2</sub>O<sub>4</sub>-water nanofluid increased by 136 %, while for NiFe<sub>2</sub>O<sub>4</sub>-EG nanofluid, it was 370 %. These findings indicate that both temperature and volume fraction significantly enhance the electrical conductivity of the nanofluids, with a more pronounced effect observed in the NiFe<sub>2</sub>O<sub>4</sub>-EG nanofluid compared to the NiFe<sub>2</sub>O<sub>4</sub>-water nanofluid. The study validated Shen et al.'s model for electrical conductivity in nanofluids, contrasting with Maxwell's model. The novelty of this work lies in the comprehensive analysis of the electrical conductivity behavior of these nanofluids, which has not been extensively reported in the literature. These findings have potential applications in heat transfer enhancement and magnetic-targeted drug delivery.</p></div>\",\"PeriodicalId\":397,\"journal\":{\"name\":\"Nano-Structures & Nano-Objects\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":5.4500,\"publicationDate\":\"2024-07-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nano-Structures & Nano-Objects\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2352507X2400177X\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"Physics and Astronomy\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nano-Structures & Nano-Objects","FirstCategoryId":"1","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2352507X2400177X","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Physics and Astronomy","Score":null,"Total":0}
Electrical conductivity of Ni ferrite nanofluids: An experimental study on the effects of temperature, volume fraction, and base fluid
This study investigates the electrical conductivity of NiFe2O4 nanofluids in water and ethylene glycol (EG) as base fluids, aiming to understand how varying volume fractions (φ= 0 %, 0.1 %, 0.25 %, 0.45 %, 0.7 %, and 1 %) and temperatures (20–70°C) influence electrical conductivity. NiFe2O4 nanoparticles were synthesized using the chemical co-precipitation method and characterized through X-ray Diffraction (XRD), Field Emission Scanning Electron Microscopy (FESEM), and Energy Dispersive Spectroscopy (EDS). The results revealed that at 70°C, the electrical conductivity of NiFe2O4-water nanofluid increased by 1100 % within the volume fraction range of 0–1 %. For NiFe2O4-EG nanofluid, the increase in electrical conductivity was even more significant, reaching 1235 % within the same volume fraction range. Similarly, at a 1 % volume fraction within the temperature range of 20–70°C, the electrical conductivity of NiFe2O4-water nanofluid increased by 136 %, while for NiFe2O4-EG nanofluid, it was 370 %. These findings indicate that both temperature and volume fraction significantly enhance the electrical conductivity of the nanofluids, with a more pronounced effect observed in the NiFe2O4-EG nanofluid compared to the NiFe2O4-water nanofluid. The study validated Shen et al.'s model for electrical conductivity in nanofluids, contrasting with Maxwell's model. The novelty of this work lies in the comprehensive analysis of the electrical conductivity behavior of these nanofluids, which has not been extensively reported in the literature. These findings have potential applications in heat transfer enhancement and magnetic-targeted drug delivery.
期刊介绍:
Nano-Structures & Nano-Objects is a new journal devoted to all aspects of the synthesis and the properties of this new flourishing domain. The journal is devoted to novel architectures at the nano-level with an emphasis on new synthesis and characterization methods. The journal is focused on the objects rather than on their applications. However, the research for new applications of original nano-structures & nano-objects in various fields such as nano-electronics, energy conversion, catalysis, drug delivery and nano-medicine is also welcome. The scope of Nano-Structures & Nano-Objects involves: -Metal and alloy nanoparticles with complex nanostructures such as shape control, core-shell and dumbells -Oxide nanoparticles and nanostructures, with complex oxide/metal, oxide/surface and oxide /organic interfaces -Inorganic semi-conducting nanoparticles (quantum dots) with an emphasis on new phases, structures, shapes and complexity -Nanostructures involving molecular inorganic species such as nanoparticles of coordination compounds, molecular magnets, spin transition nanoparticles etc. or organic nano-objects, in particular for molecular electronics -Nanostructured materials such as nano-MOFs and nano-zeolites -Hetero-junctions between molecules and nano-objects, between different nano-objects & nanostructures or between nano-objects & nanostructures and surfaces -Methods of characterization specific of the nano size or adapted for the nano size such as X-ray and neutron scattering, light scattering, NMR, Raman, Plasmonics, near field microscopies, various TEM and SEM techniques, magnetic studies, etc .