T. Kavitha, Jothimani Kannupaiyan, Ranjith Rajendran, Aswini Rangayasami
{"title":"评估 Ni-ZnO/g-C3N4 纳米复合材料的光催化降解有机缺陷和抗菌活性","authors":"T. Kavitha, Jothimani Kannupaiyan, Ranjith Rajendran, Aswini Rangayasami","doi":"10.1007/s10876-024-02663-4","DOIUrl":null,"url":null,"abstract":"<div><p>In the present work, an effective, ecofriendly and novel photocatalytic composite of Ni-ZnO/g-C<sub>3</sub>N<sub>4</sub> (NZG) has been successfully prepared via a hydrothermal method. The crystalline structure and phase purity of the produced g-C<sub>3</sub>N<sub>4</sub>, Ni-ZnO, and Ni-ZnO/g-C<sub>3</sub>N<sub>4</sub> nanocomposite were ascertained using XRD analysis. Both the g-C<sub>3</sub>N<sub>4</sub>, and Ni-ZnO retained peaks showed minor changes that suggested component interaction. Determine the functional groups and validate the composite’s development using FTIR analysis of the combined g-C<sub>3</sub>N<sub>4</sub>, and Ni-ZnO characteristics, along with the addition of new Zn-O and C-N stretching bands. The optical properties and bandgap energy were observed for g-C<sub>3</sub>N<sub>4</sub>, Ni-ZnO, and Ni-ZnO/g-C<sub>3</sub>N<sub>4</sub> nanocomposite were 360, 380, and 470 nm<sup>−1</sup> with 2.74, 2.94 and 2.86 eV. The homogeneous distribution of Ni-ZnO nanoparticles on g-C<sub>3</sub>N<sub>4</sub>, sheets, with strong contact at the interface and consistent elemental composition, was shown by using TEM analysis to investigate the morphological and elemental composition. The photocatalytic degradation efficiency was investigated against RB5 dyes. The <i>Ni-ZnO/g-C</i><sub><i>3</i></sub><i>N</i><sub><i>4</i></sub> nanocomposite showed excellent than pure Ni-ZnO and <i>g-C</i><sub><i>3</i></sub><i>N</i><sub><i>4</i></sub> catalyst reached 89.7% degradation for RB5 after 120 min under UV light. Due to this enhanced stability, in addition to the improved electron hole separations and synergistic photocatalytic mechanism between Ni-ZnO and <i>g-C</i><sub><i>3</i></sub><i>N</i><sub><i>4</i></sub> is an excellent photocatalytic activity against waste water management. The positive control chloramphenicol was showed the inhibition zone was against <i>Sterptococcus aureus</i> and <i>Enterococcus faecalis</i> for 16 nm and 18 nm, for negative control there was no zone of inhibition, and the Ni-ZnO/g-C<sub>3</sub>N<sub>4</sub> NCs showed the maximum zone of inhibition was observed in <i>Enterococcus faecalis</i> for 21 nm at and 100 µg/mL respectively.</p></div>","PeriodicalId":618,"journal":{"name":"Journal of Cluster Science","volume":"35 7","pages":"2363 - 2375"},"PeriodicalIF":2.7000,"publicationDate":"2024-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Evaluate the Ni-ZnO/g-C3N4 Nanocomposite for Photocatalytic Degradation of Organic Defect Degradation and Antibacterial Activity\",\"authors\":\"T. Kavitha, Jothimani Kannupaiyan, Ranjith Rajendran, Aswini Rangayasami\",\"doi\":\"10.1007/s10876-024-02663-4\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In the present work, an effective, ecofriendly and novel photocatalytic composite of Ni-ZnO/g-C<sub>3</sub>N<sub>4</sub> (NZG) has been successfully prepared via a hydrothermal method. The crystalline structure and phase purity of the produced g-C<sub>3</sub>N<sub>4</sub>, Ni-ZnO, and Ni-ZnO/g-C<sub>3</sub>N<sub>4</sub> nanocomposite were ascertained using XRD analysis. Both the g-C<sub>3</sub>N<sub>4</sub>, and Ni-ZnO retained peaks showed minor changes that suggested component interaction. Determine the functional groups and validate the composite’s development using FTIR analysis of the combined g-C<sub>3</sub>N<sub>4</sub>, and Ni-ZnO characteristics, along with the addition of new Zn-O and C-N stretching bands. The optical properties and bandgap energy were observed for g-C<sub>3</sub>N<sub>4</sub>, Ni-ZnO, and Ni-ZnO/g-C<sub>3</sub>N<sub>4</sub> nanocomposite were 360, 380, and 470 nm<sup>−1</sup> with 2.74, 2.94 and 2.86 eV. The homogeneous distribution of Ni-ZnO nanoparticles on g-C<sub>3</sub>N<sub>4</sub>, sheets, with strong contact at the interface and consistent elemental composition, was shown by using TEM analysis to investigate the morphological and elemental composition. The photocatalytic degradation efficiency was investigated against RB5 dyes. The <i>Ni-ZnO/g-C</i><sub><i>3</i></sub><i>N</i><sub><i>4</i></sub> nanocomposite showed excellent than pure Ni-ZnO and <i>g-C</i><sub><i>3</i></sub><i>N</i><sub><i>4</i></sub> catalyst reached 89.7% degradation for RB5 after 120 min under UV light. Due to this enhanced stability, in addition to the improved electron hole separations and synergistic photocatalytic mechanism between Ni-ZnO and <i>g-C</i><sub><i>3</i></sub><i>N</i><sub><i>4</i></sub> is an excellent photocatalytic activity against waste water management. The positive control chloramphenicol was showed the inhibition zone was against <i>Sterptococcus aureus</i> and <i>Enterococcus faecalis</i> for 16 nm and 18 nm, for negative control there was no zone of inhibition, and the Ni-ZnO/g-C<sub>3</sub>N<sub>4</sub> NCs showed the maximum zone of inhibition was observed in <i>Enterococcus faecalis</i> for 21 nm at and 100 µg/mL respectively.</p></div>\",\"PeriodicalId\":618,\"journal\":{\"name\":\"Journal of Cluster Science\",\"volume\":\"35 7\",\"pages\":\"2363 - 2375\"},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2024-07-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Cluster Science\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10876-024-02663-4\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Cluster Science","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10876-024-02663-4","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Evaluate the Ni-ZnO/g-C3N4 Nanocomposite for Photocatalytic Degradation of Organic Defect Degradation and Antibacterial Activity
In the present work, an effective, ecofriendly and novel photocatalytic composite of Ni-ZnO/g-C3N4 (NZG) has been successfully prepared via a hydrothermal method. The crystalline structure and phase purity of the produced g-C3N4, Ni-ZnO, and Ni-ZnO/g-C3N4 nanocomposite were ascertained using XRD analysis. Both the g-C3N4, and Ni-ZnO retained peaks showed minor changes that suggested component interaction. Determine the functional groups and validate the composite’s development using FTIR analysis of the combined g-C3N4, and Ni-ZnO characteristics, along with the addition of new Zn-O and C-N stretching bands. The optical properties and bandgap energy were observed for g-C3N4, Ni-ZnO, and Ni-ZnO/g-C3N4 nanocomposite were 360, 380, and 470 nm−1 with 2.74, 2.94 and 2.86 eV. The homogeneous distribution of Ni-ZnO nanoparticles on g-C3N4, sheets, with strong contact at the interface and consistent elemental composition, was shown by using TEM analysis to investigate the morphological and elemental composition. The photocatalytic degradation efficiency was investigated against RB5 dyes. The Ni-ZnO/g-C3N4 nanocomposite showed excellent than pure Ni-ZnO and g-C3N4 catalyst reached 89.7% degradation for RB5 after 120 min under UV light. Due to this enhanced stability, in addition to the improved electron hole separations and synergistic photocatalytic mechanism between Ni-ZnO and g-C3N4 is an excellent photocatalytic activity against waste water management. The positive control chloramphenicol was showed the inhibition zone was against Sterptococcus aureus and Enterococcus faecalis for 16 nm and 18 nm, for negative control there was no zone of inhibition, and the Ni-ZnO/g-C3N4 NCs showed the maximum zone of inhibition was observed in Enterococcus faecalis for 21 nm at and 100 µg/mL respectively.
期刊介绍:
The journal publishes the following types of papers: (a) original and important research;
(b) authoritative comprehensive reviews or short overviews of topics of current
interest; (c) brief but urgent communications on new significant research; and (d)
commentaries intended to foster the exchange of innovative or provocative ideas, and
to encourage dialogue, amongst researchers working in different cluster
disciplines.