{"title":"高温和 1 巴压力下 Al2O3 熔体与氮气的相互作用","authors":"D. V. Kostomarov, V. A. Fedorov","doi":"10.1134/s1063774524600042","DOIUrl":null,"url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>The main interaction reactions in the Al<sub>2</sub>O<sub>3</sub>−N<sub>2</sub> system are determined for a temperature of 2400 K and pressure of 1 bar. It is found that, in the absence of direct interaction of nitrogen (molecular and atomic) with the melt, chemical reactions may occur between nitrogen and the products of Al<sub>2</sub>O<sub>3</sub> melt dissociative evaporation. The reactions of nitrogen oxidation and the interaction reactions between nitrogen oxides and the melt, both direct and with participation of elementary oxygen or gaseous aluminum oxides, are determined. It is shown that the elementary nitrogen forms may interact with melt jointly with nitrogen oxides and (or) with all Al-containing components of the system. The concentrations of the gaseous materials that are in equilibrium with Al<sub>2</sub>O<sub>3</sub> are calculated by the Monte Carlo method.</p>","PeriodicalId":527,"journal":{"name":"Crystallography Reports","volume":null,"pages":null},"PeriodicalIF":0.6000,"publicationDate":"2024-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Interaction of Al2O3 Melt with Nitrogen at High Temperatures and Pressure of 1 Bar\",\"authors\":\"D. V. Kostomarov, V. A. Fedorov\",\"doi\":\"10.1134/s1063774524600042\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<h3 data-test=\\\"abstract-sub-heading\\\">Abstract</h3><p>The main interaction reactions in the Al<sub>2</sub>O<sub>3</sub>−N<sub>2</sub> system are determined for a temperature of 2400 K and pressure of 1 bar. It is found that, in the absence of direct interaction of nitrogen (molecular and atomic) with the melt, chemical reactions may occur between nitrogen and the products of Al<sub>2</sub>O<sub>3</sub> melt dissociative evaporation. The reactions of nitrogen oxidation and the interaction reactions between nitrogen oxides and the melt, both direct and with participation of elementary oxygen or gaseous aluminum oxides, are determined. It is shown that the elementary nitrogen forms may interact with melt jointly with nitrogen oxides and (or) with all Al-containing components of the system. The concentrations of the gaseous materials that are in equilibrium with Al<sub>2</sub>O<sub>3</sub> are calculated by the Monte Carlo method.</p>\",\"PeriodicalId\":527,\"journal\":{\"name\":\"Crystallography Reports\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.6000,\"publicationDate\":\"2024-07-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Crystallography Reports\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1134/s1063774524600042\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CRYSTALLOGRAPHY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Crystallography Reports","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1134/s1063774524600042","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CRYSTALLOGRAPHY","Score":null,"Total":0}
Interaction of Al2O3 Melt with Nitrogen at High Temperatures and Pressure of 1 Bar
Abstract
The main interaction reactions in the Al2O3−N2 system are determined for a temperature of 2400 K and pressure of 1 bar. It is found that, in the absence of direct interaction of nitrogen (molecular and atomic) with the melt, chemical reactions may occur between nitrogen and the products of Al2O3 melt dissociative evaporation. The reactions of nitrogen oxidation and the interaction reactions between nitrogen oxides and the melt, both direct and with participation of elementary oxygen or gaseous aluminum oxides, are determined. It is shown that the elementary nitrogen forms may interact with melt jointly with nitrogen oxides and (or) with all Al-containing components of the system. The concentrations of the gaseous materials that are in equilibrium with Al2O3 are calculated by the Monte Carlo method.
期刊介绍：
Crystallography Reports is a journal that publishes original articles short communications, and reviews on various aspects of crystallography: diffraction and scattering of X-rays, electrons, and neutrons, determination of crystal structure of inorganic and organic substances, including proteins and other biological substances; UV-VIS and IR spectroscopy; growth, imperfect structure and physical properties of crystals; thin films, liquid crystals, nanomaterials, partially disordered systems, and the methods of studies.
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