Duixiong Sun, Hanyun Li, Guoding Zhang, Yaopeng Yin, Maogen Su, Xueshi Bai, Marek Sikorski, Denghong Zhang
{"title":"探索结合激光诱导击穿光谱法和拉曼光谱法对含有异构颜料的壁画进行地层分析的可行性：关于雄黄和雌黄的案例研究","authors":"Duixiong Sun, Hanyun Li, Guoding Zhang, Yaopeng Yin, Maogen Su, Xueshi Bai, Marek Sikorski, Denghong Zhang","doi":"10.1186/s40494-024-01376-1","DOIUrl":null,"url":null,"abstract":"<p>A novel combined measurements techniques has been designed in this work, enabling the acquisition of laser-induced breakdown spectroscopy (LIBS) and Raman spectral signals at the same point on a sample. The application of this combined technique to the analysis of multi-layered mock-up blocks painted with orpiment and realgar pigments has yielded significant insights. By correlating variations in the emission line intensity of characteristic elements within the LIBS spectra with depth-specific Raman spectra, the number of laser pulses that penetrated the pigment layers has been accurately determined, thereby establishing a method to measure layer thickness. Finally, the technique wasto analysis the actual mural fragment from Mogao Cave 196, determining the types of pigment and the thickness of the pigment layers.</p><h3 data-test=\"abstract-sub-heading\">Graphical Abstract</h3>","PeriodicalId":13109,"journal":{"name":"Heritage Science","volume":"56 1","pages":""},"PeriodicalIF":2.6000,"publicationDate":"2024-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Exploring the viability of combined laser-induced breakdown spectroscopy and Raman spectroscopy for stratigraphic analysis of murals containing isomeric pigments: a case study on realgar and orpiment\",\"authors\":\"Duixiong Sun, Hanyun Li, Guoding Zhang, Yaopeng Yin, Maogen Su, Xueshi Bai, Marek Sikorski, Denghong Zhang\",\"doi\":\"10.1186/s40494-024-01376-1\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>A novel combined measurements techniques has been designed in this work, enabling the acquisition of laser-induced breakdown spectroscopy (LIBS) and Raman spectral signals at the same point on a sample. The application of this combined technique to the analysis of multi-layered mock-up blocks painted with orpiment and realgar pigments has yielded significant insights. By correlating variations in the emission line intensity of characteristic elements within the LIBS spectra with depth-specific Raman spectra, the number of laser pulses that penetrated the pigment layers has been accurately determined, thereby establishing a method to measure layer thickness. Finally, the technique wasto analysis the actual mural fragment from Mogao Cave 196, determining the types of pigment and the thickness of the pigment layers.</p><h3 data-test=\\\"abstract-sub-heading\\\">Graphical Abstract</h3>\",\"PeriodicalId\":13109,\"journal\":{\"name\":\"Heritage Science\",\"volume\":\"56 1\",\"pages\":\"\"},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2024-07-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Heritage Science\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1186/s40494-024-01376-1\",\"RegionNum\":1,\"RegionCategory\":\"艺术学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Heritage Science","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1186/s40494-024-01376-1","RegionNum":1,"RegionCategory":"艺术学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
Exploring the viability of combined laser-induced breakdown spectroscopy and Raman spectroscopy for stratigraphic analysis of murals containing isomeric pigments: a case study on realgar and orpiment
A novel combined measurements techniques has been designed in this work, enabling the acquisition of laser-induced breakdown spectroscopy (LIBS) and Raman spectral signals at the same point on a sample. The application of this combined technique to the analysis of multi-layered mock-up blocks painted with orpiment and realgar pigments has yielded significant insights. By correlating variations in the emission line intensity of characteristic elements within the LIBS spectra with depth-specific Raman spectra, the number of laser pulses that penetrated the pigment layers has been accurately determined, thereby establishing a method to measure layer thickness. Finally, the technique wasto analysis the actual mural fragment from Mogao Cave 196, determining the types of pigment and the thickness of the pigment layers.
期刊介绍：
Heritage Science is an open access journal publishing original peer-reviewed research covering:
Understanding of the manufacturing processes, provenances, and environmental contexts of material types, objects, and buildings, of cultural significance including their historical significance.
Understanding and prediction of physico-chemical and biological degradation processes of cultural artefacts, including climate change, and predictive heritage studies.
Development and application of analytical and imaging methods or equipments for non-invasive, non-destructive or portable analysis of artwork and objects of cultural significance to identify component materials, degradation products and deterioration markers.
Development and application of invasive and destructive methods for understanding the provenance of objects of cultural significance.
Development and critical assessment of treatment materials and methods for artwork and objects of cultural significance.
Development and application of statistical methods and algorithms for data analysis to further understanding of culturally significant objects.
Publication of reference and corpus datasets as supplementary information to the statistical and analytical studies above.
Description of novel technologies that can assist in the understanding of cultural heritage.
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