I. V. Bakaev, V. I. Komlyagina, N. F. Romashev, A. L. Gushchin
{"title":"单(芳基肼)苊酮和基于吡啶取代衍生物的镍配合物的合成与研究","authors":"I. V. Bakaev, V. I. Komlyagina, N. F. Romashev, A. L. Gushchin","doi":"10.1134/S1070328423601644","DOIUrl":null,"url":null,"abstract":"<p>Three mono(arylhydrazino)acenaphthenones, that is, mono(2-pyridylhydrazino)acenaphthenone (Py-mhan, L<sup>1</sup>), mono(4-cyanophenylhydrazino)acenaphthenone (4-CN-Ph-mhan, L<sup>2</sup>), and mono(3,4,6-trifluoro-2-pyridylhydrazino)acenaphthenone (<sup>F</sup>Py-mhan, L<sup>3</sup>), were synthesized by the reaction of acenaphthene quinone with the appropriate arylhydrazine salt; compounds L<sup>2</sup> and L<sup>3</sup> were obtained for the first time. The subsequent reaction of L<sup>1</sup> with nickel chloride in 2 : 1 ratio led to the octahedral complex [Ni(Py-mhan)<sub>2</sub>] (<b>I</b>), in which Py-mhan acts as a tridentate ligand. All of the prepared compounds were characterized by elemental analysis, IR and <sup>1</sup>H NMR spectroscopy, and cyclic voltammetry; the crystal structures of L<sup>3</sup> and <b>I</b> were determined by X-ray diffraction.</p>","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"50 4","pages":"239 - 245"},"PeriodicalIF":1.1000,"publicationDate":"2024-07-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Study of Mono(arylhydrazino)acenaphthenones and Nickel Complex Based on Pyridine-Substituted Derivative\",\"authors\":\"I. V. Bakaev, V. I. Komlyagina, N. F. Romashev, A. L. Gushchin\",\"doi\":\"10.1134/S1070328423601644\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Three mono(arylhydrazino)acenaphthenones, that is, mono(2-pyridylhydrazino)acenaphthenone (Py-mhan, L<sup>1</sup>), mono(4-cyanophenylhydrazino)acenaphthenone (4-CN-Ph-mhan, L<sup>2</sup>), and mono(3,4,6-trifluoro-2-pyridylhydrazino)acenaphthenone (<sup>F</sup>Py-mhan, L<sup>3</sup>), were synthesized by the reaction of acenaphthene quinone with the appropriate arylhydrazine salt; compounds L<sup>2</sup> and L<sup>3</sup> were obtained for the first time. The subsequent reaction of L<sup>1</sup> with nickel chloride in 2 : 1 ratio led to the octahedral complex [Ni(Py-mhan)<sub>2</sub>] (<b>I</b>), in which Py-mhan acts as a tridentate ligand. All of the prepared compounds were characterized by elemental analysis, IR and <sup>1</sup>H NMR spectroscopy, and cyclic voltammetry; the crystal structures of L<sup>3</sup> and <b>I</b> were determined by X-ray diffraction.</p>\",\"PeriodicalId\":759,\"journal\":{\"name\":\"Russian Journal of Coordination Chemistry\",\"volume\":\"50 4\",\"pages\":\"239 - 245\"},\"PeriodicalIF\":1.1000,\"publicationDate\":\"2024-07-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Coordination Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1070328423601644\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Coordination Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1070328423601644","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Synthesis and Study of Mono(arylhydrazino)acenaphthenones and Nickel Complex Based on Pyridine-Substituted Derivative
Three mono(arylhydrazino)acenaphthenones, that is, mono(2-pyridylhydrazino)acenaphthenone (Py-mhan, L1), mono(4-cyanophenylhydrazino)acenaphthenone (4-CN-Ph-mhan, L2), and mono(3,4,6-trifluoro-2-pyridylhydrazino)acenaphthenone (FPy-mhan, L3), were synthesized by the reaction of acenaphthene quinone with the appropriate arylhydrazine salt; compounds L2 and L3 were obtained for the first time. The subsequent reaction of L1 with nickel chloride in 2 : 1 ratio led to the octahedral complex [Ni(Py-mhan)2] (I), in which Py-mhan acts as a tridentate ligand. All of the prepared compounds were characterized by elemental analysis, IR and 1H NMR spectroscopy, and cyclic voltammetry; the crystal structures of L3 and I were determined by X-ray diffraction.
期刊介绍：
Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.
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