引力场强度对化学反应速率的影响

IF 1.8 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY
Mirza Wasif Baig
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引用次数: 0

摘要

化学反应速率的大小还取决于进行化学反应的引力场的位置。如果重力场中两个位置的温度和压力保持不变,在重力场较强的位置(即靠近某个重行星表面的位置)进行的化学反应速率要比在重力场较弱的位置(即远离重型植物表面的位置)进行的反应速率慢。几乎所有类型的反应速率理论,即过渡态理论、碰撞理论、赖斯-拉姆佩尔格-卡塞尔-马库斯理论和马库斯理论的速率常数,都是用广义相对论的语言来表述的,由此可见重力对反应速率的影响。玻尔兹曼常数的引力变换和分子的能量量子级都是用量子力学发展起来的。还提出了热力学状态函数的引力变换,成功地解释了不同引力场下反应物和活化复合物之间的准平衡状态。引力质量扩张的提出,解释了在较弱的引力场下,过渡态拥有更多的动能在反应坐标上平移,导致反应物更快地转化为产物。半衰期方程的引力变换显示了化学反应半衰期的引力时间膨胀,从而使广义相对论和本理论相互吻合。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effect of the gravitational field strength on the rate of chemical reactions
The magnitude of the rate of chemical reactions also depends on the position in the gravitational field where a chemical reaction is being carried out. The rate of chemical reaction conducted at a stronger gravitational field, i.e., near the surface of some heavy planet, is slower than the rate of reaction conducted at a weaker gravitational field, i.e., away from the surface of a heavy plant, provided temperature and pressure are kept constant at two positions in the gravitational field. The effect of gravity on the rates of reactions has been shown by formulating the rate constants from almost all types of reaction rate theories, i.e., transition state theory, collision theory, Rice–Ramsperger–Kassel–Marcus, and Marcus’s theory, in the language of the general theory of relativity. The gravitational transformation of the Boltzmann constant and the energy quantum levels of molecules have been developed quantum mechanically. A gravitational transformation of thermodynamic state functions has been formulated that successfully explains the quasi-equilibrium existing between reactants and the activated complex at different gravitational fields. Gravitational mass dilation has been developed, which explains that at weaker gravitational fields, the transition states possess more kinetic energy to sweep translation on the reaction coordinate, resulting in the faster conversion of reactants into products. The gravitational transformation of the half-life equation shows gravitational time dilation for the half-life period of chemical reactions and thus renders the general theory of relativity and the present theory in accord with each other.
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来源期刊
Open Physics
Open Physics PHYSICS, MULTIDISCIPLINARY-
CiteScore
3.20
自引率
5.30%
发文量
82
审稿时长
18 weeks
期刊介绍: Open Physics is a peer-reviewed, open access, electronic journal devoted to the publication of fundamental research results in all fields of physics. The journal provides the readers with free, instant, and permanent access to all content worldwide; and the authors with extensive promotion of published articles, long-time preservation, language-correction services, no space constraints and immediate publication. Our standard policy requires each paper to be reviewed by at least two Referees and the peer-review process is single-blind.
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