用 SnO2 量子点装饰的 g-C3N4 空心管用于光电化学应用

IF 4 3区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY
I. Neelakanta Reddy , Mani Ramanuja , Nadavala Siva Kumar , Mohammad Asif , Bhargav Akkinepally , M. Dhanasekar , Jaesool Shim , Cheolho Bai
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引用次数: 0

摘要

氮化石墨碳(g-CN)具有出色的光响应和强度,已被广泛用于提高光电化学(PEC)活性。本研究结合水热法和后退火法制备了饰有氧化锡量子点的氮化石墨空心管。特别是采用了不同的表征技术,如傅立叶变换红外光谱、光致发光光谱、紫外-可见光谱和 X 射线光电子能谱,来研究样品的电学和光学行为。制备的样品表现出相当高的光响应和优异的 PEC 性能,并能产生氢气。此外,氧化锡和 g-CN 之间的异质结构促进了载流子分离,提高了 PEC 能力。此外,在 0.1M 氢氧化钠电解液中,外加电压对阳极产生电荷载流子有许多影响。因此,所提出的方法简单有效,可用于提高 PEC 活性的性能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

g-C3N4 hollow tubes decorated with SnO2 quantum dots for photoelectrochemical applications

g-C3N4 hollow tubes decorated with SnO2 quantum dots for photoelectrochemical applications

g-C3N4 hollow tubes decorated with SnO2 quantum dots for photoelectrochemical applications

Graphitic carbon nitride (g-C3N4) has been widely used to improve photoelectrochemical (PEC) activity owing to its outstanding photoresponse and strength. In this study, g-C3N4 hollow tubes decorated with SnO2 quantum dots were prepared by combining hydrothermal and post-annealing approaches. In particular, different characterization techniques such as Fourier transform infrared, photoluminescence, ultraviolet–visible, and X-ray photoelectron spectroscopies were employed to investigate the electrical and optical behaviors of the samples. The prepared samples exhibited considerable photoresponse and excellent PEC performance, producing hydrogen. Furthermore, the heterostructures among SnO2 and g-C3N4 encouraged carrier separation, improving the PEC ability. In addition, the applied voltage showed numerous effects on generating charge carriers for the anodes in a 0.1 M sodium hydroxide electrolyte. Therefore, the proposed approach is simple and effective and can be used to enhance the performance of the PEC activity.

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来源期刊
Synthetic Metals
Synthetic Metals 工程技术-材料科学:综合
CiteScore
8.30
自引率
4.50%
发文量
189
审稿时长
33 days
期刊介绍: This journal is an international medium for the rapid publication of original research papers, short communications and subject reviews dealing with research on and applications of electronic polymers and electronic molecular materials including novel carbon architectures. These functional materials have the properties of metals, semiconductors or magnets and are distinguishable from elemental and alloy/binary metals, semiconductors and magnets.
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