I. Neelakanta Reddy , Mani Ramanuja , Nadavala Siva Kumar , Mohammad Asif , Bhargav Akkinepally , M. Dhanasekar , Jaesool Shim , Cheolho Bai
{"title":"用 SnO2 量子点装饰的 g-C3N4 空心管用于光电化学应用","authors":"I. Neelakanta Reddy , Mani Ramanuja , Nadavala Siva Kumar , Mohammad Asif , Bhargav Akkinepally , M. Dhanasekar , Jaesool Shim , Cheolho Bai","doi":"10.1016/j.synthmet.2024.117704","DOIUrl":null,"url":null,"abstract":"<div><p>Graphitic carbon nitride (g-C<sub>3</sub>N<sub>4</sub>) has been widely used to improve photoelectrochemical (PEC) activity owing to its outstanding photoresponse and strength. In this study, g-C<sub>3</sub>N<sub>4</sub> hollow tubes decorated with SnO<sub>2</sub> quantum dots were prepared by combining hydrothermal and post-annealing approaches. In particular, different characterization techniques such as Fourier transform infrared, photoluminescence, ultraviolet–visible, and X-ray photoelectron spectroscopies were employed to investigate the electrical and optical behaviors of the samples. The prepared samples exhibited considerable photoresponse and excellent PEC performance, producing hydrogen. Furthermore, the heterostructures among SnO<sub>2</sub> and g-C<sub>3</sub>N<sub>4</sub> encouraged carrier separation, improving the PEC ability. In addition, the applied voltage showed numerous effects on generating charge carriers for the anodes in a 0.1 M sodium hydroxide electrolyte. Therefore, the proposed approach is simple and effective and can be used to enhance the performance of the PEC activity.</p></div>","PeriodicalId":22245,"journal":{"name":"Synthetic Metals","volume":"307 ","pages":"Article 117704"},"PeriodicalIF":4.0000,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"g-C3N4 hollow tubes decorated with SnO2 quantum dots for photoelectrochemical applications\",\"authors\":\"I. Neelakanta Reddy , Mani Ramanuja , Nadavala Siva Kumar , Mohammad Asif , Bhargav Akkinepally , M. Dhanasekar , Jaesool Shim , Cheolho Bai\",\"doi\":\"10.1016/j.synthmet.2024.117704\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Graphitic carbon nitride (g-C<sub>3</sub>N<sub>4</sub>) has been widely used to improve photoelectrochemical (PEC) activity owing to its outstanding photoresponse and strength. In this study, g-C<sub>3</sub>N<sub>4</sub> hollow tubes decorated with SnO<sub>2</sub> quantum dots were prepared by combining hydrothermal and post-annealing approaches. In particular, different characterization techniques such as Fourier transform infrared, photoluminescence, ultraviolet–visible, and X-ray photoelectron spectroscopies were employed to investigate the electrical and optical behaviors of the samples. The prepared samples exhibited considerable photoresponse and excellent PEC performance, producing hydrogen. Furthermore, the heterostructures among SnO<sub>2</sub> and g-C<sub>3</sub>N<sub>4</sub> encouraged carrier separation, improving the PEC ability. In addition, the applied voltage showed numerous effects on generating charge carriers for the anodes in a 0.1 M sodium hydroxide electrolyte. Therefore, the proposed approach is simple and effective and can be used to enhance the performance of the PEC activity.</p></div>\",\"PeriodicalId\":22245,\"journal\":{\"name\":\"Synthetic Metals\",\"volume\":\"307 \",\"pages\":\"Article 117704\"},\"PeriodicalIF\":4.0000,\"publicationDate\":\"2024-07-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Synthetic Metals\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0379677924001668\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthetic Metals","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0379677924001668","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
g-C3N4 hollow tubes decorated with SnO2 quantum dots for photoelectrochemical applications
Graphitic carbon nitride (g-C3N4) has been widely used to improve photoelectrochemical (PEC) activity owing to its outstanding photoresponse and strength. In this study, g-C3N4 hollow tubes decorated with SnO2 quantum dots were prepared by combining hydrothermal and post-annealing approaches. In particular, different characterization techniques such as Fourier transform infrared, photoluminescence, ultraviolet–visible, and X-ray photoelectron spectroscopies were employed to investigate the electrical and optical behaviors of the samples. The prepared samples exhibited considerable photoresponse and excellent PEC performance, producing hydrogen. Furthermore, the heterostructures among SnO2 and g-C3N4 encouraged carrier separation, improving the PEC ability. In addition, the applied voltage showed numerous effects on generating charge carriers for the anodes in a 0.1 M sodium hydroxide electrolyte. Therefore, the proposed approach is simple and effective and can be used to enhance the performance of the PEC activity.
期刊介绍:
This journal is an international medium for the rapid publication of original research papers, short communications and subject reviews dealing with research on and applications of electronic polymers and electronic molecular materials including novel carbon architectures. These functional materials have the properties of metals, semiconductors or magnets and are distinguishable from elemental and alloy/binary metals, semiconductors and magnets.