EPR 在多价席夫碱自旋交叉铁(III)配合物磁性研究中的应用

IF 1.1 4区物理与天体物理 Q4 PHYSICS, ATOMIC, MOLECULAR & CHEMICAL

Applied Magnetic Resonance Pub Date : 2024-07-26 DOI:10.1007/s00723-024-01685-5

E. N. Frolova, O. A. Turanova, L. V. Bazan, I. V. Ovchinnikov, A. N. Turanov

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引用次数: 0

摘要

希夫碱可以创造出具有多种结构和性质的化合物，多年来一直受到研究人员的关注。这篇微型综述介绍了 EPR 方法的一些可能性，我们用这种方法来研究具有多齿席夫碱的铁（III）配合物，其中许多配合物是首次合成的。利用 EPR 光谱法获取局部信息，使我们能够掌握分子结构与性质之间的关系，并调整合成策略，创造出具有预定性质的多功能物质。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

EPR in Research of the Magnetic Properties of Spin-Crossover Fe(III) Complexes with Polydentate Schiff Bases

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EPR in Research of the Magnetic Properties of Spin-Crossover Fe(III) Complexes with Polydentate Schiff Bases

Schiff bases allow the creation of compounds with a wide variety of architectures and properties and have been of interest to researchers for many years. This mini-review describes some of the possibilities of the EPR method, which we use to study Fe(III) complexes with polydentate Schiff bases, many of which have been synthesized for the first time. Obtaining information at the local level using EPR spectroscopy allows us to grasp the molecular structure–property relationship and to adjust the synthesis strategy to create multifunctional substances with predetermined properties.

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来源期刊

Applied Magnetic Resonance 物理-光谱学

CiteScore

1.90

自引率

10.00%

发文量

审稿时长

2.3 months

期刊介绍： Applied Magnetic Resonance provides an international forum for the application of magnetic resonance in physics, chemistry, biology, medicine, geochemistry, ecology, engineering, and related fields. The contents include articles with a strong emphasis on new applications, and on new experimental methods. Additional features include book reviews and Letters to the Editor.