增强改性钛酸钼复合材料对锶放射性核素的吸附。

IF 1.6 3区 工程技术 Q3 CHEMISTRY, INORGANIC & NUCLEAR
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引用次数: 0

摘要

本研究利用一种制备的钛酸镁钼(MgMoTi)复合材料对水溶液中的 85Sr 进行了吸附。MgMoTi 复合材料是通过共沉淀技术合成的,并使用不同的分析工具(包括 FT-IR、XRD、SEM 和 EDX)对其进行了表征。吸附研究的重点是 85Sr,考察的因素包括振荡时间、pH 值、离子强度、温度、初始离子浓度和饱和容量。研究结果表明,在最佳吸附条件下,S-4 和 S-5 吸附 85Sr 的饱和容量分别为 23.31 和 37.72 mg g-1。85Sr 的吸附量与 pH 值和离子强度有关。吸附过程的动力学遵循伪 2 阶模型,而热力学则显示出内热和自发性质。解吸研究表明,0.1 M HCl 是完全回收 85Sr 的最有效洗脱剂。 此外,回收结果表明钼钛具有极佳的可回收性,这表明它有可能被用作从水溶液中去除 85Sr 的吸附剂。总之,这项研究表明镁钼钛是一种很有前途的复合材料,在从水溶液中吸附 85Sr 方面具有实用价值。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Enhanced sorption of strontium radionuclides onto a modified molybdenum titanate composite

A study was conducted to investigate the sorption of 85Sr from aqueous solutions using a fabricated magnesium molybdenum titanate (MgMoTi) composite. The MgMoTi composites were synthesized through the co-precipitation technique and characterized using different analytical tools, including FT-IR, XRD, SEM, and EDX. The sorption studies focused on 85Sr and examined factors such as shaking time, pH, ionic strength, temperature, initial ion concentration, and saturation capacity. The results obtained from the study indicated that, under optimum sorption conditions, the saturation capacity for 85Sr onto S-4 and S-5 was determined to be 23.31 and 37.72 mg g−1, respectively. The sorption of 85Sr exhibited dependence on pH and ionic strength. The kinetics of the sorption process followed the pseudo-2nd-order model, while the thermodynamics revealed an endothermic and spontaneous nature. Desorption studies revealed that 0.1 M HCl was the most effective eluent for the complete recovery of 85Sr. Furthermore, the recycling results demonstrated the excellent recyclability of MgMoTi, suggesting its potential application as a sorbent for the removal of 85Sr from aqueous solutions. Overall, the study highlights MgMoTi as a promising composite with practical utility in the sorption of 85Sr from aqueous solutions.

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来源期刊
Applied Radiation and Isotopes
Applied Radiation and Isotopes 工程技术-核科学技术
CiteScore
3.00
自引率
12.50%
发文量
406
审稿时长
13.5 months
期刊介绍: Applied Radiation and Isotopes provides a high quality medium for the publication of substantial, original and scientific and technological papers on the development and peaceful application of nuclear, radiation and radionuclide techniques in chemistry, physics, biochemistry, biology, medicine, security, engineering and in the earth, planetary and environmental sciences, all including dosimetry. Nuclear techniques are defined in the broadest sense and both experimental and theoretical papers are welcome. They include the development and use of α- and β-particles, X-rays and γ-rays, neutrons and other nuclear particles and radiations from all sources, including radionuclides, synchrotron sources, cyclotrons and reactors and from the natural environment. The journal aims to publish papers with significance to an international audience, containing substantial novelty and scientific impact. The Editors reserve the rights to reject, with or without external review, papers that do not meet these criteria. Papers dealing with radiation processing, i.e., where radiation is used to bring about a biological, chemical or physical change in a material, should be directed to our sister journal Radiation Physics and Chemistry.
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