{"title":"增强改性钛酸钼复合材料对锶放射性核素的吸附。","authors":"","doi":"10.1016/j.apradiso.2024.111447","DOIUrl":null,"url":null,"abstract":"<div><p>A study was conducted to investigate the sorption of <sup>85</sup>Sr from aqueous solutions using a fabricated magnesium molybdenum titanate (MgMoTi) composite. The MgMoTi composites were synthesized through the co-precipitation technique and characterized using different analytical tools, including FT-IR, XRD, SEM, and EDX. The sorption studies focused on <sup>85</sup>Sr and examined factors such as shaking time, pH, ionic strength, temperature, initial ion concentration, and saturation capacity. The results obtained from the study indicated that, under optimum sorption conditions, the saturation capacity for <sup>85</sup>Sr onto S-4 and S-5 was determined to be 23.31 and 37.72 mg g<sup>−1</sup>, respectively. The sorption of <sup>85</sup>Sr exhibited dependence on pH and ionic strength. The kinetics of the sorption process followed the pseudo-2nd-order model, while the thermodynamics revealed an endothermic and spontaneous nature. Desorption studies revealed that 0.1 M HCl was the most effective eluent for the complete recovery of <sup>85</sup>Sr. Furthermore, the recycling results demonstrated the excellent recyclability of MgMoTi, suggesting its potential application as a sorbent for the removal of <sup>85</sup>Sr from aqueous solutions. Overall, the study highlights MgMoTi as a promising composite with practical utility in the sorption of <sup>85</sup>Sr from aqueous solutions.</p></div>","PeriodicalId":8096,"journal":{"name":"Applied Radiation and Isotopes","volume":null,"pages":null},"PeriodicalIF":1.6000,"publicationDate":"2024-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Enhanced sorption of strontium radionuclides onto a modified molybdenum titanate composite\",\"authors\":\"\",\"doi\":\"10.1016/j.apradiso.2024.111447\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A study was conducted to investigate the sorption of <sup>85</sup>Sr from aqueous solutions using a fabricated magnesium molybdenum titanate (MgMoTi) composite. The MgMoTi composites were synthesized through the co-precipitation technique and characterized using different analytical tools, including FT-IR, XRD, SEM, and EDX. The sorption studies focused on <sup>85</sup>Sr and examined factors such as shaking time, pH, ionic strength, temperature, initial ion concentration, and saturation capacity. The results obtained from the study indicated that, under optimum sorption conditions, the saturation capacity for <sup>85</sup>Sr onto S-4 and S-5 was determined to be 23.31 and 37.72 mg g<sup>−1</sup>, respectively. The sorption of <sup>85</sup>Sr exhibited dependence on pH and ionic strength. The kinetics of the sorption process followed the pseudo-2nd-order model, while the thermodynamics revealed an endothermic and spontaneous nature. Desorption studies revealed that 0.1 M HCl was the most effective eluent for the complete recovery of <sup>85</sup>Sr. Furthermore, the recycling results demonstrated the excellent recyclability of MgMoTi, suggesting its potential application as a sorbent for the removal of <sup>85</sup>Sr from aqueous solutions. Overall, the study highlights MgMoTi as a promising composite with practical utility in the sorption of <sup>85</sup>Sr from aqueous solutions.</p></div>\",\"PeriodicalId\":8096,\"journal\":{\"name\":\"Applied Radiation and Isotopes\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.6000,\"publicationDate\":\"2024-07-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Radiation and Isotopes\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0969804324002756\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Radiation and Isotopes","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0969804324002756","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Enhanced sorption of strontium radionuclides onto a modified molybdenum titanate composite
A study was conducted to investigate the sorption of 85Sr from aqueous solutions using a fabricated magnesium molybdenum titanate (MgMoTi) composite. The MgMoTi composites were synthesized through the co-precipitation technique and characterized using different analytical tools, including FT-IR, XRD, SEM, and EDX. The sorption studies focused on 85Sr and examined factors such as shaking time, pH, ionic strength, temperature, initial ion concentration, and saturation capacity. The results obtained from the study indicated that, under optimum sorption conditions, the saturation capacity for 85Sr onto S-4 and S-5 was determined to be 23.31 and 37.72 mg g−1, respectively. The sorption of 85Sr exhibited dependence on pH and ionic strength. The kinetics of the sorption process followed the pseudo-2nd-order model, while the thermodynamics revealed an endothermic and spontaneous nature. Desorption studies revealed that 0.1 M HCl was the most effective eluent for the complete recovery of 85Sr. Furthermore, the recycling results demonstrated the excellent recyclability of MgMoTi, suggesting its potential application as a sorbent for the removal of 85Sr from aqueous solutions. Overall, the study highlights MgMoTi as a promising composite with practical utility in the sorption of 85Sr from aqueous solutions.
期刊介绍:
Applied Radiation and Isotopes provides a high quality medium for the publication of substantial, original and scientific and technological papers on the development and peaceful application of nuclear, radiation and radionuclide techniques in chemistry, physics, biochemistry, biology, medicine, security, engineering and in the earth, planetary and environmental sciences, all including dosimetry. Nuclear techniques are defined in the broadest sense and both experimental and theoretical papers are welcome. They include the development and use of α- and β-particles, X-rays and γ-rays, neutrons and other nuclear particles and radiations from all sources, including radionuclides, synchrotron sources, cyclotrons and reactors and from the natural environment.
The journal aims to publish papers with significance to an international audience, containing substantial novelty and scientific impact. The Editors reserve the rights to reject, with or without external review, papers that do not meet these criteria.
Papers dealing with radiation processing, i.e., where radiation is used to bring about a biological, chemical or physical change in a material, should be directed to our sister journal Radiation Physics and Chemistry.