{"title":"含有 Fe3+/支链淀粉的聚乙烯醇/PEDOT:PSS 水凝胶具有高韧性、抗冻性和可愈合性,可用于多功能可穿戴传感器。","authors":"","doi":"10.1016/j.talanta.2024.126592","DOIUrl":null,"url":null,"abstract":"<div><p>In recent years, hydrogel-based flexible sensors have garnered increasing attention in research. Ionic hydrogels, enriched with large amounts of ionic liquids, exhibit electrical conductivity, excellent electrochemical stability, anti-freezing, and antimicrobial properties. However, most ionic hydrogels suffer from poor mechanical properties, limiting their adaptability to more complex application scenarios. Integrating conductive polymers into hydrogels leads to desirable features such as increased specific surface area, soft and biocompatible interfaces, and high electrolyte permeability. In this study, we successfully prepared Fe<sup>3+/</sup>Ap@PVA/PEDOT double-network hydrogel. Utilizing polyvinyl alcohol (PVA) as the primary matrix, we introduced PEDOT:PSS and FeCl<sub>3</sub> to confer conductivity to the hydrogel. The incorporation of amylopectin (Ap) further enhanced mechanical performance. The resulted hydrogel sensor exhibits outstanding mechanical properties, allowing for stretching up to 347 % and withstanding a tensile force of 505 kPa. In addition, it exhibits excellent antifreeze properties (can work at −30 °C), healability, water retention, and high sensitivity to stretching (GF = 4.72 at a 200 % strain ratio), compression (GF = 2.97 at a 12 % compressive ratio), and temperature (TCR = 2.46). These remarkable properties of the hydrogel make it possible in applications such as human motion monitoring, handwriting recognition, and temperature sensing.</p></div>","PeriodicalId":435,"journal":{"name":"Talanta","volume":null,"pages":null},"PeriodicalIF":5.6000,"publicationDate":"2024-07-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Polyvinyl alcohol/PEDOT:PSS with Fe3+/amylopectin enabled highly tough, anti-freezing and healable hydrogels for multifunctional wearable sensors\",\"authors\":\"\",\"doi\":\"10.1016/j.talanta.2024.126592\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In recent years, hydrogel-based flexible sensors have garnered increasing attention in research. Ionic hydrogels, enriched with large amounts of ionic liquids, exhibit electrical conductivity, excellent electrochemical stability, anti-freezing, and antimicrobial properties. However, most ionic hydrogels suffer from poor mechanical properties, limiting their adaptability to more complex application scenarios. Integrating conductive polymers into hydrogels leads to desirable features such as increased specific surface area, soft and biocompatible interfaces, and high electrolyte permeability. In this study, we successfully prepared Fe<sup>3+/</sup>Ap@PVA/PEDOT double-network hydrogel. Utilizing polyvinyl alcohol (PVA) as the primary matrix, we introduced PEDOT:PSS and FeCl<sub>3</sub> to confer conductivity to the hydrogel. The incorporation of amylopectin (Ap) further enhanced mechanical performance. The resulted hydrogel sensor exhibits outstanding mechanical properties, allowing for stretching up to 347 % and withstanding a tensile force of 505 kPa. In addition, it exhibits excellent antifreeze properties (can work at −30 °C), healability, water retention, and high sensitivity to stretching (GF = 4.72 at a 200 % strain ratio), compression (GF = 2.97 at a 12 % compressive ratio), and temperature (TCR = 2.46). These remarkable properties of the hydrogel make it possible in applications such as human motion monitoring, handwriting recognition, and temperature sensing.</p></div>\",\"PeriodicalId\":435,\"journal\":{\"name\":\"Talanta\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":5.6000,\"publicationDate\":\"2024-07-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Talanta\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0039914024009718\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Talanta","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0039914024009718","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
Polyvinyl alcohol/PEDOT:PSS with Fe3+/amylopectin enabled highly tough, anti-freezing and healable hydrogels for multifunctional wearable sensors
In recent years, hydrogel-based flexible sensors have garnered increasing attention in research. Ionic hydrogels, enriched with large amounts of ionic liquids, exhibit electrical conductivity, excellent electrochemical stability, anti-freezing, and antimicrobial properties. However, most ionic hydrogels suffer from poor mechanical properties, limiting their adaptability to more complex application scenarios. Integrating conductive polymers into hydrogels leads to desirable features such as increased specific surface area, soft and biocompatible interfaces, and high electrolyte permeability. In this study, we successfully prepared Fe3+/Ap@PVA/PEDOT double-network hydrogel. Utilizing polyvinyl alcohol (PVA) as the primary matrix, we introduced PEDOT:PSS and FeCl3 to confer conductivity to the hydrogel. The incorporation of amylopectin (Ap) further enhanced mechanical performance. The resulted hydrogel sensor exhibits outstanding mechanical properties, allowing for stretching up to 347 % and withstanding a tensile force of 505 kPa. In addition, it exhibits excellent antifreeze properties (can work at −30 °C), healability, water retention, and high sensitivity to stretching (GF = 4.72 at a 200 % strain ratio), compression (GF = 2.97 at a 12 % compressive ratio), and temperature (TCR = 2.46). These remarkable properties of the hydrogel make it possible in applications such as human motion monitoring, handwriting recognition, and temperature sensing.
期刊介绍:
Talanta provides a forum for the publication of original research papers, short communications, and critical reviews in all branches of pure and applied analytical chemistry. Papers are evaluated based on established guidelines, including the fundamental nature of the study, scientific novelty, substantial improvement or advantage over existing technology or methods, and demonstrated analytical applicability. Original research papers on fundamental studies, and on novel sensor and instrumentation developments, are encouraged. Novel or improved applications in areas such as clinical and biological chemistry, environmental analysis, geochemistry, materials science and engineering, and analytical platforms for omics development are welcome.
Analytical performance of methods should be determined, including interference and matrix effects, and methods should be validated by comparison with a standard method, or analysis of a certified reference material. Simple spiking recoveries may not be sufficient. The developed method should especially comprise information on selectivity, sensitivity, detection limits, accuracy, and reliability. However, applying official validation or robustness studies to a routine method or technique does not necessarily constitute novelty. Proper statistical treatment of the data should be provided. Relevant literature should be cited, including related publications by the authors, and authors should discuss how their proposed methodology compares with previously reported methods.