关于 "应用 PFP 理论测量正十三烷或正十四烷与癸醛的过剩摩尔体积和过剩焓并建立相关模型 "的评论

IF 1.4 4区化学 Q4 CHEMISTRY, PHYSICAL

Journal of Solution Chemistry Pub Date : 2024-07-19 DOI:10.1007/s10953-024-01404-5

William E. Acree

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引用次数: 0

摘要

对 Touazi 和同事在其发表的论文中报告的一些体积特性进行了论证。对已发表的癸醛 + 十三烷和癸醛 + 十四烷二元混合物的过量摩尔体积进行的批判性分析表明，在低癸醛摩尔分数成分下测定的值与在高癸醛成分下测定的值不一致。分析进一步表明，癸烷 + 十三烷和癸烷 + 十四烷系统的过量摩尔体积与独立研究小组报告的含有较小（C5 至 C12）和较大（C16）线性烷烃分子的二元癸烷混合物的公开数据有很大差异。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Comments Regarding “Measurement and Modeling of Excess Molar Volume and Excess Enthalpy of n-Tridecane or n-Tetradecane with Decalin by Application of PFP Theory”

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Comments Regarding “Measurement and Modeling of Excess Molar Volume and Excess Enthalpy of n-Tridecane or n-Tetradecane with Decalin by Application of PFP Theory”

A polemic is given regarding several of the volumetric properties that Touazi and coworkers reported in their published paper. A critical analysis of the published excess molar volumes for binary decalin + tridecane and decalin + tetradecane mixtures revealed that the values determined at low decalin mole fraction compositions were not consistent with values measured at higher decalin compositions. The analysis further showed that the excess molar volumes for the decalin + tridecane and decalin + tetradecane systems differ significantly from published data reported by independent research groups for binary decalin mixtures containing both smaller (C₅ to C₁₂) and larger (C₁₆) linear alkane molecules.

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来源期刊

Journal of Solution Chemistry 化学-物理化学

CiteScore

2.30

自引率

0.00%

发文量

审稿时长

3-8 weeks

期刊介绍： Journal of Solution Chemistry offers a forum for research on the physical chemistry of liquid solutions in such fields as physical chemistry, chemical physics, molecular biology, statistical mechanics, biochemistry, and biophysics. The emphasis is on papers in which the solvent plays a dominant rather than incidental role. Featured topics include experimental investigations of the dielectric, spectroscopic, thermodynamic, transport, or relaxation properties of both electrolytes and nonelectrolytes in liquid solutions.