Geotechnical performance of black cotton clay in the presence of lead and cadmium solutions for geoenvironmental application.

The usage of bentonites and sand-bentonite mixtures as liners has become prevalent due to their low permeability. However, these materials are scarce and prohibitively expensive in India. Black cotton clay (BCC) was chosen as an alternative clay liner for this research due to its abundance in India and its mineralogical composition. Since heavy metals accumulation in municipal landfills is a rising issue with devastating effects on the ecosystem and human health, in this investigation, two heavy metals (lead and cadmium) were intended as permeants at three different concentrations (100, 500, and 1000 ppm) to imitate the impact of heavy metal leachate on BCC. The essential index and engineering properties of BCC were evaluated and compared under these two permeants from the liner perspective. Experimental results revealed that the free swell index, Atterberg limits, swelling and swelling pressures were reduced for a rise in concentration irrespective of metal type. However, this reduction was more with cadmium permeants compared to lead. The measured swelling data was compared with predicted swelling data using a rectangular hyperbola model, and a good correlation was achieved. The hydraulic conductivity (k) and unconfined compressive strength (UCS) values were increased for a rise in concentration with both metal permeants. At 1000 ppm concentration, the k values were raised to 3.5 and 6.7 times, and UCS values were enhanced by 8.3 and 5.5% for lead and cadmium permeants, respectively. At high concentrations, field emission scanning electron microscopy (FESEM) results showed the formation of huge voids and aggregation.