Christian Harito, Munawar Khalil, Leanddas Nurdiwijayanto, Ni Luh Wulan Septiani, Syauqi Abdurrahman Abrori, Budi Riza Putra, Syed Z. J. Zaidi, Takaaki Taniguchi, Brian Yuliarto and Frank C. Walsh
{"title":"二维二氧化钛纳米片的面控生长和软化学剥离","authors":"Christian Harito, Munawar Khalil, Leanddas Nurdiwijayanto, Ni Luh Wulan Septiani, Syauqi Abdurrahman Abrori, Budi Riza Putra, Syed Z. J. Zaidi, Takaaki Taniguchi, Brian Yuliarto and Frank C. Walsh","doi":"10.1039/D4NA00442F","DOIUrl":null,"url":null,"abstract":"<p >TiO<small><sub>2</sub></small> remains one of the most popular materials used in catalysts, photovoltaics, coatings, and electronics due to its abundance, chemical stability, and excellent catalytic properties. The tailoring of the TiO<small><sub>2</sub></small> structure into two-dimensional nanosheets prompted the successful isolation of graphene and MXenes. In this review, facet-controlled TiO<small><sub>2</sub></small> and monolayer titanate are outlined, covering their synthesis route and formation mechanism. The reactive facet of TiO<small><sub>2</sub></small> is usually controlled by a capping agent. In contrast, the monolayer titanate is achieved by ion-exchange and delamination of layered titanates. Each route leads to 2D structures with unique physical and chemical properties, which expands its utilisation into several niche applications. We elaborate the detailed outlook for the future use and research studies of facet-controlled TiO<small><sub>2</sub></small> and monolayer titanates. Advantages and disadvantages of both structures are provided, along with suggested applications for each type of 2D TiO<small><sub>2</sub></small> nanosheets.</p>","PeriodicalId":18806,"journal":{"name":"Nanoscale Advances","volume":null,"pages":null},"PeriodicalIF":4.6000,"publicationDate":"2024-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/na/d4na00442f?page=search","citationCount":"0","resultStr":"{\"title\":\"Facet-controlled growth and soft-chemical exfoliation of two-dimensional titanium dioxide nanosheets\",\"authors\":\"Christian Harito, Munawar Khalil, Leanddas Nurdiwijayanto, Ni Luh Wulan Septiani, Syauqi Abdurrahman Abrori, Budi Riza Putra, Syed Z. J. Zaidi, Takaaki Taniguchi, Brian Yuliarto and Frank C. Walsh\",\"doi\":\"10.1039/D4NA00442F\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >TiO<small><sub>2</sub></small> remains one of the most popular materials used in catalysts, photovoltaics, coatings, and electronics due to its abundance, chemical stability, and excellent catalytic properties. The tailoring of the TiO<small><sub>2</sub></small> structure into two-dimensional nanosheets prompted the successful isolation of graphene and MXenes. In this review, facet-controlled TiO<small><sub>2</sub></small> and monolayer titanate are outlined, covering their synthesis route and formation mechanism. The reactive facet of TiO<small><sub>2</sub></small> is usually controlled by a capping agent. In contrast, the monolayer titanate is achieved by ion-exchange and delamination of layered titanates. Each route leads to 2D structures with unique physical and chemical properties, which expands its utilisation into several niche applications. We elaborate the detailed outlook for the future use and research studies of facet-controlled TiO<small><sub>2</sub></small> and monolayer titanates. Advantages and disadvantages of both structures are provided, along with suggested applications for each type of 2D TiO<small><sub>2</sub></small> nanosheets.</p>\",\"PeriodicalId\":18806,\"journal\":{\"name\":\"Nanoscale Advances\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":4.6000,\"publicationDate\":\"2024-07-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://pubs.rsc.org/en/content/articlepdf/2024/na/d4na00442f?page=search\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nanoscale Advances\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2024/na/d4na00442f\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nanoscale Advances","FirstCategoryId":"88","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/na/d4na00442f","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Facet-controlled growth and soft-chemical exfoliation of two-dimensional titanium dioxide nanosheets
TiO2 remains one of the most popular materials used in catalysts, photovoltaics, coatings, and electronics due to its abundance, chemical stability, and excellent catalytic properties. The tailoring of the TiO2 structure into two-dimensional nanosheets prompted the successful isolation of graphene and MXenes. In this review, facet-controlled TiO2 and monolayer titanate are outlined, covering their synthesis route and formation mechanism. The reactive facet of TiO2 is usually controlled by a capping agent. In contrast, the monolayer titanate is achieved by ion-exchange and delamination of layered titanates. Each route leads to 2D structures with unique physical and chemical properties, which expands its utilisation into several niche applications. We elaborate the detailed outlook for the future use and research studies of facet-controlled TiO2 and monolayer titanates. Advantages and disadvantages of both structures are provided, along with suggested applications for each type of 2D TiO2 nanosheets.