Xiaolei Fu, Yan He, Zhulei Guo, Mingfan Chen, Wenlong Du, Yuqin Zeng, Dingzhong Yuan, Bing Na
{"title":"新型双杂原子官能化超交联多孔聚合物的简易合成及其对亚甲基蓝和甲基橙的高效吸附作用","authors":"Xiaolei Fu, Yan He, Zhulei Guo, Mingfan Chen, Wenlong Du, Yuqin Zeng, Dingzhong Yuan, Bing Na","doi":"10.1007/s11164-024-05346-x","DOIUrl":null,"url":null,"abstract":"<div><p>In this work, we designed and synthesized two novel bi-heteroatom functionalized hyper-crosslinked porous polymers (HCP-CT and HCP-CF) through a simple one-step Friedel–Crafts alkylation reaction. The resulted polymers N/S bi-heteroatom functionalized polymer HCP-CT and N/O bi-heteroatom functionalized polymer HCP-CF both have good adsorption property for organic dyes such as methyl orange (MO) and methylene blue (MB) in aqueous solution due to its rich pore structure, high specific surface area and rich-heteroatoms of pore surface. It is worth mentioned that the maximum adsorption capacity (<i>q</i><sub>max</sub>) of cationic dye MB by the porous polymer HCP-CT at room temperature was reached up to 1571.46 mg/g, which is much higher than that of most reported porous materials. Furthermore, the adsorption capacity of HCP-CT for the cationic dye MB was more than seven times that of the anionic dye MO (<i>q</i><sub>max</sub> = 212.77 mg/g). Also, the polymer HCP-CF for the MB adsorption capacity (<i>q</i><sub>max</sub> = 352.11 mg/g) was more than twice higher than that of anionic dye MO (<i>q</i><sub>max</sub> = 131.75 mg/g). The above trends may be because of the stronger electrostatic interaction between the negatively charged N-S/O bi-heteroatom of HCP-CT and HCP-CF with the cationic dye MB than that of MO. In addition, the removal percentage of polymers HCP-CT and HCP-CF still remained above 80% after five adsorption–desorption cycles. Hence, this work may provide a convenient synthetic route to develop a novel hyper-crosslinked polymer with high capacity for the entrapment of dyes from aqueous solution.</p></div>","PeriodicalId":753,"journal":{"name":"Research on Chemical Intermediates","volume":"50 9","pages":"4351 - 4365"},"PeriodicalIF":2.8000,"publicationDate":"2024-07-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Facile synthesis of novel bi-heteroatom functionalized hyper-crosslinked porous polymers with efficient adsorption of methylene blue and methyl orange\",\"authors\":\"Xiaolei Fu, Yan He, Zhulei Guo, Mingfan Chen, Wenlong Du, Yuqin Zeng, Dingzhong Yuan, Bing Na\",\"doi\":\"10.1007/s11164-024-05346-x\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In this work, we designed and synthesized two novel bi-heteroatom functionalized hyper-crosslinked porous polymers (HCP-CT and HCP-CF) through a simple one-step Friedel–Crafts alkylation reaction. The resulted polymers N/S bi-heteroatom functionalized polymer HCP-CT and N/O bi-heteroatom functionalized polymer HCP-CF both have good adsorption property for organic dyes such as methyl orange (MO) and methylene blue (MB) in aqueous solution due to its rich pore structure, high specific surface area and rich-heteroatoms of pore surface. It is worth mentioned that the maximum adsorption capacity (<i>q</i><sub>max</sub>) of cationic dye MB by the porous polymer HCP-CT at room temperature was reached up to 1571.46 mg/g, which is much higher than that of most reported porous materials. Furthermore, the adsorption capacity of HCP-CT for the cationic dye MB was more than seven times that of the anionic dye MO (<i>q</i><sub>max</sub> = 212.77 mg/g). Also, the polymer HCP-CF for the MB adsorption capacity (<i>q</i><sub>max</sub> = 352.11 mg/g) was more than twice higher than that of anionic dye MO (<i>q</i><sub>max</sub> = 131.75 mg/g). The above trends may be because of the stronger electrostatic interaction between the negatively charged N-S/O bi-heteroatom of HCP-CT and HCP-CF with the cationic dye MB than that of MO. In addition, the removal percentage of polymers HCP-CT and HCP-CF still remained above 80% after five adsorption–desorption cycles. Hence, this work may provide a convenient synthetic route to develop a novel hyper-crosslinked polymer with high capacity for the entrapment of dyes from aqueous solution.</p></div>\",\"PeriodicalId\":753,\"journal\":{\"name\":\"Research on Chemical Intermediates\",\"volume\":\"50 9\",\"pages\":\"4351 - 4365\"},\"PeriodicalIF\":2.8000,\"publicationDate\":\"2024-07-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Research on Chemical Intermediates\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11164-024-05346-x\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Research on Chemical Intermediates","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11164-024-05346-x","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Facile synthesis of novel bi-heteroatom functionalized hyper-crosslinked porous polymers with efficient adsorption of methylene blue and methyl orange
In this work, we designed and synthesized two novel bi-heteroatom functionalized hyper-crosslinked porous polymers (HCP-CT and HCP-CF) through a simple one-step Friedel–Crafts alkylation reaction. The resulted polymers N/S bi-heteroatom functionalized polymer HCP-CT and N/O bi-heteroatom functionalized polymer HCP-CF both have good adsorption property for organic dyes such as methyl orange (MO) and methylene blue (MB) in aqueous solution due to its rich pore structure, high specific surface area and rich-heteroatoms of pore surface. It is worth mentioned that the maximum adsorption capacity (qmax) of cationic dye MB by the porous polymer HCP-CT at room temperature was reached up to 1571.46 mg/g, which is much higher than that of most reported porous materials. Furthermore, the adsorption capacity of HCP-CT for the cationic dye MB was more than seven times that of the anionic dye MO (qmax = 212.77 mg/g). Also, the polymer HCP-CF for the MB adsorption capacity (qmax = 352.11 mg/g) was more than twice higher than that of anionic dye MO (qmax = 131.75 mg/g). The above trends may be because of the stronger electrostatic interaction between the negatively charged N-S/O bi-heteroatom of HCP-CT and HCP-CF with the cationic dye MB than that of MO. In addition, the removal percentage of polymers HCP-CT and HCP-CF still remained above 80% after five adsorption–desorption cycles. Hence, this work may provide a convenient synthetic route to develop a novel hyper-crosslinked polymer with high capacity for the entrapment of dyes from aqueous solution.
期刊介绍:
Research on Chemical Intermediates publishes current research articles and concise dynamic reviews on the properties, structures and reactivities of intermediate species in all the various domains of chemistry.
The journal also contains articles in related disciplines such as spectroscopy, molecular biology and biochemistry, atmospheric and environmental sciences, catalysis, photochemistry and photophysics. In addition, special issues dedicated to specific topics in the field are regularly published.