{"title":"使用过氧化物法活化钒以获得混合凯金型杂多化合物","authors":"Yu. A. Rodikova, T. Yu. Kardash, E. G. Zhizhina","doi":"10.1134/S1070427223110012","DOIUrl":null,"url":null,"abstract":"<p>The possibility of preparing mixed Keggin-type heteropoly compounds by introducing catalytically active vanadium(V) atoms activated by the peroxide method into the framework of Mo- and W-containing heteropoly anions was demonstrated. The pretreatment of the required amount of vanadium(V) in the form of V<sub>2</sub>O<sub>5</sub> with a concentrated H<sub>2</sub>O<sub>2</sub> solution ensures a considerable decrease in the content of foreign ions in solutions of heteropoly compounds and in salts based on them. Incorporation of vanadium(V) atoms into the heteropoly anion framework with preservation of the structural integrity was proved by the example of acidic salts Cs<sub>3.5</sub>H<sub>0.5</sub>PMo<sub>11</sub>VO<sub>40</sub>, Cs<sub>3.5</sub>H<sub>0.5</sub>PW<sub>11</sub>VO<sub>40</sub>, and Cs<sub>4.5</sub>H<sub>0.5</sub>SiW<sub>11</sub>VO<sub>40</sub>. The textural characteristics of the target compounds were studied, their thermograms were recorded, and the phase composition was determined. High stability and low solubility of the Cs-containing salts in three cycles of hydrothermal treatment were demonstrated.</p>","PeriodicalId":757,"journal":{"name":"Russian Journal of Applied Chemistry","volume":null,"pages":null},"PeriodicalIF":0.6000,"publicationDate":"2024-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Use of the Peroxide Method for Vanadium Activation to Obtain Mixed Keggin-Type Heteropoly Compounds\",\"authors\":\"Yu. A. Rodikova, T. Yu. Kardash, E. G. Zhizhina\",\"doi\":\"10.1134/S1070427223110012\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The possibility of preparing mixed Keggin-type heteropoly compounds by introducing catalytically active vanadium(V) atoms activated by the peroxide method into the framework of Mo- and W-containing heteropoly anions was demonstrated. The pretreatment of the required amount of vanadium(V) in the form of V<sub>2</sub>O<sub>5</sub> with a concentrated H<sub>2</sub>O<sub>2</sub> solution ensures a considerable decrease in the content of foreign ions in solutions of heteropoly compounds and in salts based on them. Incorporation of vanadium(V) atoms into the heteropoly anion framework with preservation of the structural integrity was proved by the example of acidic salts Cs<sub>3.5</sub>H<sub>0.5</sub>PMo<sub>11</sub>VO<sub>40</sub>, Cs<sub>3.5</sub>H<sub>0.5</sub>PW<sub>11</sub>VO<sub>40</sub>, and Cs<sub>4.5</sub>H<sub>0.5</sub>SiW<sub>11</sub>VO<sub>40</sub>. The textural characteristics of the target compounds were studied, their thermograms were recorded, and the phase composition was determined. High stability and low solubility of the Cs-containing salts in three cycles of hydrothermal treatment were demonstrated.</p>\",\"PeriodicalId\":757,\"journal\":{\"name\":\"Russian Journal of Applied Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.6000,\"publicationDate\":\"2024-07-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Applied Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1070427223110012\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Applied Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1070427223110012","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
Use of the Peroxide Method for Vanadium Activation to Obtain Mixed Keggin-Type Heteropoly Compounds
The possibility of preparing mixed Keggin-type heteropoly compounds by introducing catalytically active vanadium(V) atoms activated by the peroxide method into the framework of Mo- and W-containing heteropoly anions was demonstrated. The pretreatment of the required amount of vanadium(V) in the form of V2O5 with a concentrated H2O2 solution ensures a considerable decrease in the content of foreign ions in solutions of heteropoly compounds and in salts based on them. Incorporation of vanadium(V) atoms into the heteropoly anion framework with preservation of the structural integrity was proved by the example of acidic salts Cs3.5H0.5PMo11VO40, Cs3.5H0.5PW11VO40, and Cs4.5H0.5SiW11VO40. The textural characteristics of the target compounds were studied, their thermograms were recorded, and the phase composition was determined. High stability and low solubility of the Cs-containing salts in three cycles of hydrothermal treatment were demonstrated.
期刊介绍：
Russian Journal of Applied Chemistry (Zhurnal prikladnoi khimii) was founded in 1928. It covers all application problems of modern chemistry, including the structure of inorganic and organic compounds, kinetics and mechanisms of chemical reactions, problems of chemical processes and apparatus, borderline problems of chemistry, and applied research.
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