{"title":"一种在低温下快速固化酚醛环氧树脂的潜伏固化剂","authors":"Jian-Qiao Guo, Xing-Hong Zhang","doi":"10.1002/app.56003","DOIUrl":null,"url":null,"abstract":"<p>Developing effective latent curing agent for rapid curing of epoxy resins at low temperatures remains challenging. This study reports a latent curing agent, ortho-cresol phenolic epoxy resin-bisphenol A (EOCN-BPA), prepared through the addition reaction of o-methyl phenolic epoxy resin with BPA. When blended with dicyandiamide (DICY) in a 1:3 molar ratio, EOCN-BPA/DICY is used to cure a linear epoxy phenolic novolac (EPN) resin (epoxy equivalent: 550 g eq<sup>−1</sup>, softening point: approximately 82°C), at an onset curing temperature of 90°C, which is considerably lower than the onset curing temperature of DICY with EPN (160°C). However, EOCN-BPA does not react with EPN without a catalyst. Therefore, this latent curing system is successfully applied in powder coatings, rapid curing at 120°C within 3 min without an additional catalyst, outperforming the EPN/EOCN-BPA system using cocatalyst 2-methylimidazole. Consequently, DICY catalyzes the curing reaction between the phenol hydroxyl group and epoxy resin and participates in it. The prepared powder coating exhibits excellent storage stability, maintaining its properties for over 3 months at room temperature. These findings demonstrate the excellent latent properties of EOCN-BPA/DICY, highlighting its potential as a highly effective latent curing agent.</p>","PeriodicalId":183,"journal":{"name":"Journal of Applied Polymer Science","volume":"141 39","pages":""},"PeriodicalIF":2.8000,"publicationDate":"2024-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A latent curing agent for rapid curing of phenolic epoxy resin at low temperature\",\"authors\":\"Jian-Qiao Guo, Xing-Hong Zhang\",\"doi\":\"10.1002/app.56003\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Developing effective latent curing agent for rapid curing of epoxy resins at low temperatures remains challenging. This study reports a latent curing agent, ortho-cresol phenolic epoxy resin-bisphenol A (EOCN-BPA), prepared through the addition reaction of o-methyl phenolic epoxy resin with BPA. When blended with dicyandiamide (DICY) in a 1:3 molar ratio, EOCN-BPA/DICY is used to cure a linear epoxy phenolic novolac (EPN) resin (epoxy equivalent: 550 g eq<sup>−1</sup>, softening point: approximately 82°C), at an onset curing temperature of 90°C, which is considerably lower than the onset curing temperature of DICY with EPN (160°C). However, EOCN-BPA does not react with EPN without a catalyst. Therefore, this latent curing system is successfully applied in powder coatings, rapid curing at 120°C within 3 min without an additional catalyst, outperforming the EPN/EOCN-BPA system using cocatalyst 2-methylimidazole. Consequently, DICY catalyzes the curing reaction between the phenol hydroxyl group and epoxy resin and participates in it. The prepared powder coating exhibits excellent storage stability, maintaining its properties for over 3 months at room temperature. These findings demonstrate the excellent latent properties of EOCN-BPA/DICY, highlighting its potential as a highly effective latent curing agent.</p>\",\"PeriodicalId\":183,\"journal\":{\"name\":\"Journal of Applied Polymer Science\",\"volume\":\"141 39\",\"pages\":\"\"},\"PeriodicalIF\":2.8000,\"publicationDate\":\"2024-07-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Applied Polymer Science\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/app.56003\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Applied Polymer Science","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/app.56003","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
A latent curing agent for rapid curing of phenolic epoxy resin at low temperature
Developing effective latent curing agent for rapid curing of epoxy resins at low temperatures remains challenging. This study reports a latent curing agent, ortho-cresol phenolic epoxy resin-bisphenol A (EOCN-BPA), prepared through the addition reaction of o-methyl phenolic epoxy resin with BPA. When blended with dicyandiamide (DICY) in a 1:3 molar ratio, EOCN-BPA/DICY is used to cure a linear epoxy phenolic novolac (EPN) resin (epoxy equivalent: 550 g eq−1, softening point: approximately 82°C), at an onset curing temperature of 90°C, which is considerably lower than the onset curing temperature of DICY with EPN (160°C). However, EOCN-BPA does not react with EPN without a catalyst. Therefore, this latent curing system is successfully applied in powder coatings, rapid curing at 120°C within 3 min without an additional catalyst, outperforming the EPN/EOCN-BPA system using cocatalyst 2-methylimidazole. Consequently, DICY catalyzes the curing reaction between the phenol hydroxyl group and epoxy resin and participates in it. The prepared powder coating exhibits excellent storage stability, maintaining its properties for over 3 months at room temperature. These findings demonstrate the excellent latent properties of EOCN-BPA/DICY, highlighting its potential as a highly effective latent curing agent.
期刊介绍：
The Journal of Applied Polymer Science is the largest peer-reviewed publication in polymers, #3 by total citations, and features results with real-world impact on membranes, polysaccharides, and much more.
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