Chengrong Wang , Ling Liao , Lisheng Fan , Wenqi Ge , Bing Fan , Qi Huang , Rufang Peng , Bo Jin
{"title":"富勒烯膦酸盐衍生物掺杂 PCBM 可增强界面能量排列和协同钝化能力","authors":"Chengrong Wang , Ling Liao , Lisheng Fan , Wenqi Ge , Bing Fan , Qi Huang , Rufang Peng , Bo Jin","doi":"10.1016/j.jechem.2024.06.056","DOIUrl":null,"url":null,"abstract":"<div><p>Phenyl-C<sub>61</sub>-butyric acid methyl ester (PCBM) serves as a common electron transport layer (ETL) in inverted p-i-n structure perovskite solar cells (IPSCs), yet energy barriers and insufficient passivation at the PCBM-perovskite interface hinder device effectiveness and durability. In this study, we present a series of novel Fullerene Phenylacid Ester Derivatives (FPEDs: FPP, FTPP, FDPP) incorporated into PCBM. Our investigations illustrate that FPEDs effectively act to passivate the perovskite surface by forming robust interactions with uncoordinated Pb<sup>2+</sup> ions via the phosphine oxide groups present in their molecular structures, thereby enhancing the stability of the devices. Moreover, these additives elevate the energy level of the lowest unoccupied molecular orbital (LUMO) of ETL, diminish the electron injection barrier, and enhance the efficiency of interlayer electron transport. Incorporating FPEDs enhances ETL coverage on the perovskite layer, reducing leakage current significantly. Notably, Devices with PCBM/FTPP achieved a peak PCE of 23.62% and showed superior stability, maintaining 96.8% of the initial PCE after 500 h, while control devices retained merely 80.7% over the same period.</p></div>","PeriodicalId":15728,"journal":{"name":"Journal of Energy Chemistry","volume":"98 ","pages":"Pages 656-662"},"PeriodicalIF":13.1000,"publicationDate":"2024-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Doping PCBM with fullerene phosphinate derivatives enhances the interface energy alignment and synergistic passivation capability\",\"authors\":\"Chengrong Wang , Ling Liao , Lisheng Fan , Wenqi Ge , Bing Fan , Qi Huang , Rufang Peng , Bo Jin\",\"doi\":\"10.1016/j.jechem.2024.06.056\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Phenyl-C<sub>61</sub>-butyric acid methyl ester (PCBM) serves as a common electron transport layer (ETL) in inverted p-i-n structure perovskite solar cells (IPSCs), yet energy barriers and insufficient passivation at the PCBM-perovskite interface hinder device effectiveness and durability. In this study, we present a series of novel Fullerene Phenylacid Ester Derivatives (FPEDs: FPP, FTPP, FDPP) incorporated into PCBM. Our investigations illustrate that FPEDs effectively act to passivate the perovskite surface by forming robust interactions with uncoordinated Pb<sup>2+</sup> ions via the phosphine oxide groups present in their molecular structures, thereby enhancing the stability of the devices. Moreover, these additives elevate the energy level of the lowest unoccupied molecular orbital (LUMO) of ETL, diminish the electron injection barrier, and enhance the efficiency of interlayer electron transport. Incorporating FPEDs enhances ETL coverage on the perovskite layer, reducing leakage current significantly. Notably, Devices with PCBM/FTPP achieved a peak PCE of 23.62% and showed superior stability, maintaining 96.8% of the initial PCE after 500 h, while control devices retained merely 80.7% over the same period.</p></div>\",\"PeriodicalId\":15728,\"journal\":{\"name\":\"Journal of Energy Chemistry\",\"volume\":\"98 \",\"pages\":\"Pages 656-662\"},\"PeriodicalIF\":13.1000,\"publicationDate\":\"2024-07-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Energy Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2095495624004704\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"Energy\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Energy Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2095495624004704","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Energy","Score":null,"Total":0}
Doping PCBM with fullerene phosphinate derivatives enhances the interface energy alignment and synergistic passivation capability
Phenyl-C61-butyric acid methyl ester (PCBM) serves as a common electron transport layer (ETL) in inverted p-i-n structure perovskite solar cells (IPSCs), yet energy barriers and insufficient passivation at the PCBM-perovskite interface hinder device effectiveness and durability. In this study, we present a series of novel Fullerene Phenylacid Ester Derivatives (FPEDs: FPP, FTPP, FDPP) incorporated into PCBM. Our investigations illustrate that FPEDs effectively act to passivate the perovskite surface by forming robust interactions with uncoordinated Pb2+ ions via the phosphine oxide groups present in their molecular structures, thereby enhancing the stability of the devices. Moreover, these additives elevate the energy level of the lowest unoccupied molecular orbital (LUMO) of ETL, diminish the electron injection barrier, and enhance the efficiency of interlayer electron transport. Incorporating FPEDs enhances ETL coverage on the perovskite layer, reducing leakage current significantly. Notably, Devices with PCBM/FTPP achieved a peak PCE of 23.62% and showed superior stability, maintaining 96.8% of the initial PCE after 500 h, while control devices retained merely 80.7% over the same period.
期刊介绍:
The Journal of Energy Chemistry, the official publication of Science Press and the Dalian Institute of Chemical Physics, Chinese Academy of Sciences, serves as a platform for reporting creative research and innovative applications in energy chemistry. It mainly reports on creative researches and innovative applications of chemical conversions of fossil energy, carbon dioxide, electrochemical energy and hydrogen energy, as well as the conversions of biomass and solar energy related with chemical issues to promote academic exchanges in the field of energy chemistry and to accelerate the exploration, research and development of energy science and technologies.
This journal focuses on original research papers covering various topics within energy chemistry worldwide, including:
Optimized utilization of fossil energy
Hydrogen energy
Conversion and storage of electrochemical energy
Capture, storage, and chemical conversion of carbon dioxide
Materials and nanotechnologies for energy conversion and storage
Chemistry in biomass conversion
Chemistry in the utilization of solar energy