Danyang Li , Yongqi Li , Dagui Liao , Mengqing Cao , Lulu Zhang , Shasha Zhang , Ling Chen , Yawen Chen , Huan Wang , Jian Qi , Feifei You
{"title":"增强中空铂/二氧化钛纳米反应器的光收集能力，促进四环素的光降解","authors":"Danyang Li , Yongqi Li , Dagui Liao , Mengqing Cao , Lulu Zhang , Shasha Zhang , Ling Chen , Yawen Chen , Huan Wang , Jian Qi , Feifei You","doi":"10.1016/j.pnsc.2024.07.005","DOIUrl":null,"url":null,"abstract":"<div><p><span>Utilizing solar energy to decompose tetracycline (TC) is a green strategy to treat wastewater. Herein, a heterogeneous hollow structured TiO</span><sub>2</sub><span><span> decorated Pt nanoparticles were successfully designed and synthesized via hard-template approach and photo-deposition process toward TC </span>photodegradation<span>. The Pt nanoparticles loaded on the surface of hollow structured TiO</span></span><sub>2</sub><span><span> can increase the visible light absorption due to the local </span>surface plasmon resonance<span><span> (LSPR) effect. Furthermore, owing to the tough electron oscillation of the LSPR excitation, the plasmonic hot holes on the surface of Pt </span>nanoparticles can capture the electrons of TiO</span></span><sub>2</sub>, effectively facilitating the separation of photo-excited charge carriers because of the formation of Schottky junction constructed between Pt and TiO<sub>2</sub><span>. Combined the natural merits of shorten conveying path of charge carriers and physical structural stability for hollow structure, the optimal Pt/TiO</span><sub>2</sub><span> hetero-junction hybrid showed superior photocatalytic activity<span> and durability for TC photodegradation with the degradation efficiency of 93.8 % after 30 min and the rate constant of 0.09196 min</span></span><sup>−1</sup><span> under 300 W Xe lamp irradiation. This work displays a heterogeneous hybrids catalyst based on eco-friendly metal and semiconductor materials which can be used in the fields including without limitation TC photodegradation.</span></p></div>","PeriodicalId":20742,"journal":{"name":"Progress in Natural Science: Materials International","volume":"34 4","pages":"Pages 767-775"},"PeriodicalIF":4.8000,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Enhanced light harvesting ability in hollow Pt/TiO2 nanoreactor for boosting tetracycline photodegradation\",\"authors\":\"Danyang Li , Yongqi Li , Dagui Liao , Mengqing Cao , Lulu Zhang , Shasha Zhang , Ling Chen , Yawen Chen , Huan Wang , Jian Qi , Feifei You\",\"doi\":\"10.1016/j.pnsc.2024.07.005\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p><span>Utilizing solar energy to decompose tetracycline (TC) is a green strategy to treat wastewater. Herein, a heterogeneous hollow structured TiO</span><sub>2</sub><span><span> decorated Pt nanoparticles were successfully designed and synthesized via hard-template approach and photo-deposition process toward TC </span>photodegradation<span>. The Pt nanoparticles loaded on the surface of hollow structured TiO</span></span><sub>2</sub><span><span> can increase the visible light absorption due to the local </span>surface plasmon resonance<span><span> (LSPR) effect. Furthermore, owing to the tough electron oscillation of the LSPR excitation, the plasmonic hot holes on the surface of Pt </span>nanoparticles can capture the electrons of TiO</span></span><sub>2</sub>, effectively facilitating the separation of photo-excited charge carriers because of the formation of Schottky junction constructed between Pt and TiO<sub>2</sub><span>. Combined the natural merits of shorten conveying path of charge carriers and physical structural stability for hollow structure, the optimal Pt/TiO</span><sub>2</sub><span> hetero-junction hybrid showed superior photocatalytic activity<span> and durability for TC photodegradation with the degradation efficiency of 93.8 % after 30 min and the rate constant of 0.09196 min</span></span><sup>−1</sup><span> under 300 W Xe lamp irradiation. This work displays a heterogeneous hybrids catalyst based on eco-friendly metal and semiconductor materials which can be used in the fields including without limitation TC photodegradation.</span></p></div>\",\"PeriodicalId\":20742,\"journal\":{\"name\":\"Progress in Natural Science: Materials International\",\"volume\":\"34 4\",\"pages\":\"Pages 767-775\"},\"PeriodicalIF\":4.8000,\"publicationDate\":\"2024-08-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Progress in Natural Science: Materials International\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1002007124001540\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Progress in Natural Science: Materials International","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1002007124001540","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Enhanced light harvesting ability in hollow Pt/TiO2 nanoreactor for boosting tetracycline photodegradation
Utilizing solar energy to decompose tetracycline (TC) is a green strategy to treat wastewater. Herein, a heterogeneous hollow structured TiO2 decorated Pt nanoparticles were successfully designed and synthesized via hard-template approach and photo-deposition process toward TC photodegradation. The Pt nanoparticles loaded on the surface of hollow structured TiO2 can increase the visible light absorption due to the local surface plasmon resonance (LSPR) effect. Furthermore, owing to the tough electron oscillation of the LSPR excitation, the plasmonic hot holes on the surface of Pt nanoparticles can capture the electrons of TiO2, effectively facilitating the separation of photo-excited charge carriers because of the formation of Schottky junction constructed between Pt and TiO2. Combined the natural merits of shorten conveying path of charge carriers and physical structural stability for hollow structure, the optimal Pt/TiO2 hetero-junction hybrid showed superior photocatalytic activity and durability for TC photodegradation with the degradation efficiency of 93.8 % after 30 min and the rate constant of 0.09196 min−1 under 300 W Xe lamp irradiation. This work displays a heterogeneous hybrids catalyst based on eco-friendly metal and semiconductor materials which can be used in the fields including without limitation TC photodegradation.
期刊介绍：
Progress in Natural Science: Materials International provides scientists and engineers throughout the world with a central vehicle for the exchange and dissemination of basic theoretical studies and applied research of advanced materials. The emphasis is placed on original research, both analytical and experimental, which is of permanent interest to engineers and scientists, covering all aspects of new materials and technologies, such as, energy and environmental materials; advanced structural materials; advanced transportation materials, functional and electronic materials; nano-scale and amorphous materials; health and biological materials; materials modeling and simulation; materials characterization; and so on. The latest research achievements and innovative papers in basic theoretical studies and applied research of material science will be carefully selected and promptly reported. Thus, the aim of this Journal is to serve the global materials science and technology community with the latest research findings.
As a service to readers, an international bibliography of recent publications in advanced materials is published bimonthly.
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