伏尔加河地表水苯酚污染的动态变化

A. Taneeva, A.V. Pavlov, V.F. Novikov
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引用次数: 0

摘要

酚类是自然环境中的重点污染物,通过工业企业的废水处理厂进入水源。它们对人体构成一定的威胁,因为其中许多都有剧毒,属于第一类危险物质。苯酚的有机氯衍生物表现出特别高的毒性;在使用含氯制剂进行水消毒的条件下,它们会形成多氯二苯并-n-二恶英,这种物质被列为超级生态毒物,对人体的遗传密码有负面影响。根据研究结果,使用气液色谱法对喀山市水域库比谢夫水库伏尔加河流域的地表水进行了苯酚及其衍生物含量分析。在分析水生环境中的酚类时发现,对人体和野生动物具有高毒性的正氯酚、偏氯酚和对位氯酚的最大允许浓度标准已经超标。伏尔加河地表水中苯酚及其衍生物浓度的季节性动态变化已经确定,这与夏季氧化还原过程的加强有关,是在涉及溶解氧的温度因素影响下发生的。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
DYNAMICS OF POLLUTION OF SURFACE WATERS OF THE VOLGA RIVER WITH PHENOL
Phenols are priority pollutants of the natural environment and enter water sources through wastewater treatment plants of industrial enterprises. They pose a certain threat to the human body, since many of them are highly toxic and belong to the first class of danger. Organochlorine derivatives of phenol exhibit particularly high toxicity; under conditions of water disinfection with chlorine-containing preparations, they can form polychlorinated dibenzo-n-dioxins, which are classified as super-ecotoxicants and have a negative effect on the genetic code of the human body. As a result of the studies, the surface waters of the Volga river basin of the Kuibyshev reservoir in the water area of the city of Kazan were analyzed for the content of phenol and its derivatives using gas-liquid chromatography. When analyzing phenols in the aquatic environment, it was established that the maximum permissible concentrations norms for ortho-, meta-, para- chlorophenols, which are characterized by high toxicity to the human body and wildlife, were exceeded. The dynamics of seasonal changes in the concentration of phenol and its derivatives in the surface waters of the Volga river has been established, which are associated with the intensification of redox processes in the summer, occurring under the influence of temperature factors involving dissolved oxygen.
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