紫水晶中 Fe2+ 杂质离子地面电子态的 EPR 光谱分析

IF 1.1 4区物理与天体物理 Q4 PHYSICS, ATOMIC, MOLECULAR & CHEMICAL

Applied Magnetic Resonance Pub Date : 2024-07-16 DOI:10.1007/s00723-024-01683-7

V. F. Tarasov, R. B. Zaripov

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引用次数: 0

摘要

通过 Q 波段连续波电子顺磁共振光谱研究了天然紫晶中 Fe2+ 杂质离子的两个最低电子水平的性质。结果表明，这两个电子层呈现出准双态（\left| { \pm 2} \right/rangle/），零场分裂为 30.9 ± 0.2 GHz。确定了这个顺磁中心的主磁轴方向和 g 因子值。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

EPR Spectroscopy of the Ground Electron State of the Fe2+ Impurity Ion in Amethyst

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EPR Spectroscopy of the Ground Electron State of the Fe2+ Impurity Ion in Amethyst

Properties of two lowest electron levels of the Fe²⁺ impurity ion in a natural amethyst are studied by continuous wave electron paramagnetic resonance spectroscopy in the Q-band. It is established that the these levels present quasi-doublet \(\left| { \pm 2} \right\rangle\)with zero-field splitting of 30.9 ± 0.2 GHz. Orientation of principal magnetic axes and value of g-factor of this paramagnetic center are determined.

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来源期刊

Applied Magnetic Resonance 物理-光谱学

CiteScore

1.90

自引率

10.00%

发文量

审稿时长

2.3 months

期刊介绍： Applied Magnetic Resonance provides an international forum for the application of magnetic resonance in physics, chemistry, biology, medicine, geochemistry, ecology, engineering, and related fields. The contents include articles with a strong emphasis on new applications, and on new experimental methods. Additional features include book reviews and Letters to the Editor.