{"title":"具有可控磁性和光学特性的 Ba_0.9Ca_0.1Zr_0.05M_0.10Ti_0.85O_3(M = Mn、Fe、Co)氧化物陶瓷的合成与相形成","authors":"A. V. Fedorova, A. A. Selyutin, N. A. Medzatyi","doi":"10.1134/S0036023623603276","DOIUrl":null,"url":null,"abstract":"<p>Ceramic Ba<sub>0.9</sub>Ca<sub>0.1</sub>Zr<sub>0.05</sub>M<sub>0.10</sub>Ti<sub>0.85</sub>O<sub>3</sub> (M = Mn, Fe, or Co) samples with perovskite structure were prepared by ordinary solid-phase technology. Phase formation in the prepared samples was investigated, and their unit cell parameters were determined by X-ray powder diffraction. Magnetic and optical properties of the samples were investigated by magnetic susceptibility measurements and diffuse reflectance spectroscopy. The phase composition, magnetic and optical properties were found to depend on the nature of the doped paramagnetic element.</p>","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"69 3","pages":"369 - 376"},"PeriodicalIF":1.8000,"publicationDate":"2024-07-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Phase Formation in Ba0.9Ca0.1Zr0.05M0.10Ti0.85O3 (M = Mn, Fe, Co) Oxide Ceramics Having Controllable Magnetic and Optical Properties\",\"authors\":\"A. V. Fedorova, A. A. Selyutin, N. A. Medzatyi\",\"doi\":\"10.1134/S0036023623603276\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Ceramic Ba<sub>0.9</sub>Ca<sub>0.1</sub>Zr<sub>0.05</sub>M<sub>0.10</sub>Ti<sub>0.85</sub>O<sub>3</sub> (M = Mn, Fe, or Co) samples with perovskite structure were prepared by ordinary solid-phase technology. Phase formation in the prepared samples was investigated, and their unit cell parameters were determined by X-ray powder diffraction. Magnetic and optical properties of the samples were investigated by magnetic susceptibility measurements and diffuse reflectance spectroscopy. The phase composition, magnetic and optical properties were found to depend on the nature of the doped paramagnetic element.</p>\",\"PeriodicalId\":762,\"journal\":{\"name\":\"Russian Journal of Inorganic Chemistry\",\"volume\":\"69 3\",\"pages\":\"369 - 376\"},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2024-07-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Inorganic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0036023623603276\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0036023623603276","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Synthesis and Phase Formation in Ba0.9Ca0.1Zr0.05M0.10Ti0.85O3 (M = Mn, Fe, Co) Oxide Ceramics Having Controllable Magnetic and Optical Properties
Ceramic Ba0.9Ca0.1Zr0.05M0.10Ti0.85O3 (M = Mn, Fe, or Co) samples with perovskite structure were prepared by ordinary solid-phase technology. Phase formation in the prepared samples was investigated, and their unit cell parameters were determined by X-ray powder diffraction. Magnetic and optical properties of the samples were investigated by magnetic susceptibility measurements and diffuse reflectance spectroscopy. The phase composition, magnetic and optical properties were found to depend on the nature of the doped paramagnetic element.
期刊介绍:
Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.