[鹤壁市臭氧和 VOCs 污染特征、来源及减排控制策略分析]。

Q2 Environmental Science
Yu-Ting Liu, Zhan-Xia Du, Xin-Min Zhang, Sha Chen, Ying-Ying Liu, Lan-Tian Zhang
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引用次数: 0

摘要

为了控制河南省鹤壁市日益严重的臭氧(O3)污染,明确臭氧及其前体物的污染特征至关重要。因此,我们利用 OFP-PMF-EKMA 方法,结合常规污染物和挥发性有机物在线小时分辨率监测数据,对 2022 年夏季(6 月至 9 月)的臭氧污染进行了综合分析。对 2022 年夏季(6 月至 9 月)的臭氧形成潜能值(OFP)进行了分析。臭氧形成潜能值(OFP)通过 EKMA 曲线和情景分析,确定鹤壁市臭氧主要控制区,科学合理地确定 VOCs 和 NOx 的削减比例。2022 年,鹤壁市出现了持续的臭氧污染,其中 6 月份浓度最高。高温、低湿、低气压等条件导致了 O3 的累积。芳香族和含氧挥发性有机化合物(OVOCs)对 OFP 和 VOCs 部分的贡献很大,它们是主要的活性物质和浓度优势物种。VOCs 来源分析结果表明,汽车尾气源(25.3%)是大气中 VOCs 的主要来源。其次是加工源(17.7%)和生物质燃烧源(17.7%)。生物质燃烧源(17.6%)。因此,与化石燃料燃烧和工业生产排放相关的排放源是鹤壁市亟待控制的大气 VOCs 来源。鹤壁市的 O3 产生于 VOCs 敏感区域,减排结果表明,VOCs 和氮氧化物(NOx)的协同减排可有效控制 O3 污染,其减排效果可达 0.5%。减排结果表明,VOCs 和氮氧化物(NOx)协同减排可有效控制 O3 污染,其中 VOCs 减排 75%,NOx 减排 10%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
[Analysis of Ozone and VOCs Pollution Characteristics, Sources, and Abatement Control Strategies in Hebi].

In order to control the increasing ozone (O3) pollution in Hebi, Henan Province, clarifying the pollution characteristics of ozone and its precursors is vital. Therefore, we conducted a comprehensive analysis of O3 pollution utilizing the OFP-PMF-EKMA method combined with online hourly resolution monitoring data of conventional pollutants and volatile organic compounds (VOCs) in the summer of 2022 (June-September). Ozone formation potential (OFP) was used to identify the key VOCs species, and the PMF model was used to identify the VOCs emission sources, whereas EKMA curves and scenario analysis were used to identify the main ozone control area in Hebi and to determine the reduction ratio of VOCs and NOx in a scientifically refined way. In 2022, Hebi had persistent O3 pollution, with the highest concentration in June. Conditions of high temperature, low humidity, and low atmospheric pressure contributed to the O3 accumulation. Aromatic and oxygenated volatile organic compounds (OVOCs) contributed significantly to the OFP and VOCs fraction, which were the dominant active substance and concentration dominant species. The results of the VOCs source analysis indicated that vehicle exhaust sources (25.3%) were the main source of atmospheric VOCs, followed by process sources (17.7%) and biomass combustion sources (17.6%). Thus, emission sources associated with the combustion of fossil fuels and industrial production emissions were the most urgent sources of atmospheric VOCs to be controlled in Hebi. The O3 generation in Hebi occurred in the VOCs-sensitive zones, and the emission reduction results showed that a synergistic emission reduction of VOCs and nitrogen oxide (NOx) could effectively control O3 pollution with a 75% reduction in VOCs and a 10% reduction in NOx.

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来源期刊
Huanjing Kexue/Environmental Science
Huanjing Kexue/Environmental Science Environmental Science-Environmental Science (all)
CiteScore
4.40
自引率
0.00%
发文量
15329
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