{"title":"被还原氧化石墨烯包裹的硫化钴锰纳米颗粒：作为高效电化学传感平台测定香兰素的神奇纳米复合材料","authors":"","doi":"10.1016/j.jfutfo.2024.05.005","DOIUrl":null,"url":null,"abstract":"<div><p>In this work, a fascinating nanocomposite based on manganese-cobalt sulfide (MnS/Co<sub>3</sub>S<sub>4</sub>) wrapped by electrochemically reduced graphene oxide (ERGO) has been successfully synthesized on the surface of a glassy carbon electrode (GCE) by a facile hydrothermal assisted electrochemical reduction method. The modified electrode was fully characterized by scanning electron microscopy, cyclic voltammetry and electrochemical impedance spectroscopy. The morphological results illustrate that MnS/Co<sub>3</sub>S<sub>4</sub> are embedded in the ERGO layers, resulting in a rough surface and three-dimensional (3D) microstructure. The as-synthesized MnS/Co<sub>3</sub>S<sub>4</sub>-ERGO/GCE displays distinctly enhanced electrocatalytic activity for vanillin oxidation in comparison with that of the ERGO/GCE and MnS/Co<sub>3</sub>S<sub>4</sub>/GCE. Therefore, the MnS/Co<sub>3</sub>S<sub>4</sub>-ERGO/GCE can be used as an effective electrochemical sensing platform for the sensitive determination of vanillin, and the fabricated sensor displays a wide linear range of 0.02−1.00 μmol/L and 1.0−40.0 μmol/L, low detection limit of 4.0 nmol/L and satisfactory recoveries between 98.0% and 102.8%.</p></div>","PeriodicalId":100784,"journal":{"name":"Journal of Future Foods","volume":null,"pages":null},"PeriodicalIF":5.2000,"publicationDate":"2024-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772566924000181/pdfft?md5=5213621a093b5c26b64459f620b0c30b&pid=1-s2.0-S2772566924000181-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Manganese cobalt sulfide nanoparticles wrapped by reduced graphene oxide: a fascinating nanocomposite as an efficient electrochemical sensing platform for vanillin determination\",\"authors\":\"\",\"doi\":\"10.1016/j.jfutfo.2024.05.005\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In this work, a fascinating nanocomposite based on manganese-cobalt sulfide (MnS/Co<sub>3</sub>S<sub>4</sub>) wrapped by electrochemically reduced graphene oxide (ERGO) has been successfully synthesized on the surface of a glassy carbon electrode (GCE) by a facile hydrothermal assisted electrochemical reduction method. The modified electrode was fully characterized by scanning electron microscopy, cyclic voltammetry and electrochemical impedance spectroscopy. The morphological results illustrate that MnS/Co<sub>3</sub>S<sub>4</sub> are embedded in the ERGO layers, resulting in a rough surface and three-dimensional (3D) microstructure. The as-synthesized MnS/Co<sub>3</sub>S<sub>4</sub>-ERGO/GCE displays distinctly enhanced electrocatalytic activity for vanillin oxidation in comparison with that of the ERGO/GCE and MnS/Co<sub>3</sub>S<sub>4</sub>/GCE. Therefore, the MnS/Co<sub>3</sub>S<sub>4</sub>-ERGO/GCE can be used as an effective electrochemical sensing platform for the sensitive determination of vanillin, and the fabricated sensor displays a wide linear range of 0.02−1.00 μmol/L and 1.0−40.0 μmol/L, low detection limit of 4.0 nmol/L and satisfactory recoveries between 98.0% and 102.8%.</p></div>\",\"PeriodicalId\":100784,\"journal\":{\"name\":\"Journal of Future Foods\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":5.2000,\"publicationDate\":\"2024-07-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S2772566924000181/pdfft?md5=5213621a093b5c26b64459f620b0c30b&pid=1-s2.0-S2772566924000181-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Future Foods\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2772566924000181\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"FOOD SCIENCE & TECHNOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Future Foods","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2772566924000181","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"FOOD SCIENCE & TECHNOLOGY","Score":null,"Total":0}
Manganese cobalt sulfide nanoparticles wrapped by reduced graphene oxide: a fascinating nanocomposite as an efficient electrochemical sensing platform for vanillin determination
In this work, a fascinating nanocomposite based on manganese-cobalt sulfide (MnS/Co3S4) wrapped by electrochemically reduced graphene oxide (ERGO) has been successfully synthesized on the surface of a glassy carbon electrode (GCE) by a facile hydrothermal assisted electrochemical reduction method. The modified electrode was fully characterized by scanning electron microscopy, cyclic voltammetry and electrochemical impedance spectroscopy. The morphological results illustrate that MnS/Co3S4 are embedded in the ERGO layers, resulting in a rough surface and three-dimensional (3D) microstructure. The as-synthesized MnS/Co3S4-ERGO/GCE displays distinctly enhanced electrocatalytic activity for vanillin oxidation in comparison with that of the ERGO/GCE and MnS/Co3S4/GCE. Therefore, the MnS/Co3S4-ERGO/GCE can be used as an effective electrochemical sensing platform for the sensitive determination of vanillin, and the fabricated sensor displays a wide linear range of 0.02−1.00 μmol/L and 1.0−40.0 μmol/L, low detection limit of 4.0 nmol/L and satisfactory recoveries between 98.0% and 102.8%.
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