[Bi10{RuPPh3}3]-：顺磁 13 顶点多铋杂阴离子。

IF 4.7 2区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Inorganic Chemistry Pub Date : 2024-10-28 Epub Date: 2024-07-16 DOI:10.1021/acs.inorgchem.4c01287

Yueyue Wang, Yankai Li, Ruili Sang, Li Xu

引用次数: 0

摘要

Ru（PPh3）3Cl2 与 K5Bi4 的乙二胺（en）溶液中的 Binn- 发生反应，生成了一种新的 13 阶 [Bi10{RuPPh3}3]- (1)，它由前所未有的不完整立方体 Bi73- 和三角形 Bi33- 组成，并由 {RuPPh3}2+ 保持在一起。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

[Bi10{RuPPh3}3]-: Paramagnetic 13-Vertex Polybismuthide Heteroanion.

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[Bi₁₀{RuPPh₃}₃]^-: Paramagnetic 13-Vertex Polybismuthide Heteroanion.

Ru(PPh₃)₃Cl₂ reacts with Bi_n^n- from an ethylenediamine (en) solution of K₅Bi₄ to yield a new architype of 13-vertex [Bi₁₀{RuPPh₃}₃]^- (1) composed of unprecedented incomplete cuboidal Bi₇^3- and triangular Bi₃^3- held together by {RuPPh₃}²⁺.

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来源期刊

Inorganic Chemistry 化学-无机化学与核化学

CiteScore

7.60

自引率

13.00%

发文量

1960

审稿时长

1.9 months

期刊介绍： Inorganic Chemistry publishes fundamental studies in all phases of inorganic chemistry. Coverage includes experimental and theoretical reports on quantitative studies of structure and thermodynamics, kinetics, mechanisms of inorganic reactions, bioinorganic chemistry, and relevant aspects of organometallic chemistry, solid-state phenomena, and chemical bonding theory. Emphasis is placed on the synthesis, structure, thermodynamics, reactivity, spectroscopy, and bonding properties of significant new and known compounds.