Comparison of electrochemical depositing and spin coating methods as electrode modification methods in order to ozone production and dye decomposition

In the field of electrochemical ozone production, electrodes need to have exceptional catalytic activity, long-term stability, and cost-effectiveness. In this case, TiO2-NTs/SnO₂-Sb₂O₅-NiO electrodes were fabricated using a combination of anodization, electrochemical deposition, spin coating and annealing techniques. The coating of electrodes was analyzed using EDS, XRD and SEM techniques. According to the obtained cyclic voltammetry (CV) data, the TiO2-NTs/SnO₂-Sb₂O₅-NiO electrode revealed a less positive potential for oxygen evolution compared to other constructed electrodes. The conversion of Ti to Ti-NTs improved the ozone production efficiency and resulted in higher concentrations of water-soluble ozone. To evaluate the performance of the electrodes and the corresponding electrocatalytic activity, a textile dye was used as a pollutant. The most effective modified electrode proved to have an impressive decomposition rate of 96% for the cationic yellow 28 dye within a 60-min timeframe. Furthermore, this modified electrode could substantially remove chemical oxygen demand (COD) of up to 53.6% during 60-min electrolysis.