有机锡 S-硫代苯甲酰巯基乙酸酯复合物的合成及其作为 SnS2 薄膜单源前驱体的应用

IF 2 4区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

European Journal of Inorganic Chemistry Pub Date : 2024-07-11 DOI:10.1002/ejic.202400297

Rajesh Pratap, Sajal Rai, Anchal Srivastava, Subrato Bhattacharya

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引用次数: 0

摘要

利用具有两个硫原子和两个氧原子的 S-硫代苯甲酰基硫代乙醇酸合成了氧代有机锡（IV）羧酸分子 [BuSn(O)(O2CCH2SC(S)Ph)]6。该分子是一个六核团簇，已通过单晶 X 射线衍射分析确定了其结构特征。该复合物被用作单源前驱体，通过化学气相沉积技术制备 SnS2 薄膜。通过光谱和显微测量，对 SnS2 的独特三角形结构进行了表征。已经确定了 SnS2 结构的明确边界和相当大的尺寸。

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Synthesis of an Organotin S-thiobenzoylthioglycolate Complex and its Application as a Single Source Precursor to SnS2 Thin Film

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Synthesis of an Organotin S-thiobenzoylthioglycolate Complex and its Application as a Single Source Precursor to SnS2 Thin Film

S-thiobenzoylthioglycolic acid possessing two sulfur and two oxygen atoms was used to synthesize an oxoorganotin(IV) carboxylate molecule, [BuSn(O)(O₂CCH₂SC(S)Ph)]₆. The molecule is a hexanuclear cluster that has been characterized structurally by single-crystal X-ray diffraction analysis. The complex was used as a single-source precursor to prepare a thin film of SnS₂ by the chemical vapor deposition technique. The distinct triangular formations of SnS₂ were characterized by spectral and microscopic measurements. Well-defined boundaries and considerable sizes of SnS₂ structures have been identified.

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来源期刊

European Journal of Inorganic Chemistry 化学-无机化学与核化学

CiteScore

4.30

自引率

4.30%

发文量

419

审稿时长

1.3 months

期刊介绍： The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry: Chemische Berichte Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.