通过催化方法控制挥发性有机化合物污染的最新进展

IF 15.7 1区 化学 Q1 CHEMISTRY, APPLIED
Honghong Zhang, Zhiwei Wang, Lu Wei, Yuxi Liu, Hongxing Dai, Jiguang Deng
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引用次数: 0

摘要

挥发性有机化合物(VOCs)会引发灰霾、光化学烟雾等大气环境问题,严重制约环境的可持续发展,威胁人类健康。有效、全面地防治挥发性有机化合物是一项艰巨的任务。催化氧化法可以实现低能耗、高效率地去除挥发性有机化合物。本综述介绍了近十年来热催化或光热催化领域具有代表性的研究进展,集中展示了为研究单组分或多组分 VOC 净化、VOC 和 NOx 协同消除以及 VOC 资源化而设计和制备的具有独特形态和结构的各种催化剂。此外,还总结了 H2O、CO2 和 SO2 对催化稳定性的影响机理。催化剂的活性和稳定性会影响其使用寿命和使用成本。特别是对于稳定性较差的支撑惰性金属催化剂,总结了一些独特的设计策略,以高效去除挥发性有机化合物,同时兼顾低惰性金属用量和优化催化性能。最后,介绍了科学问题和未来研究方向。应考虑协调处理大气污染物和温室气体。本研究有望为高活性、高选择性和高稳定性催化剂的设计以及通过催化方法控制空气污染提供深刻的见解。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Recent progress on VOC pollution control via the catalytic method

Volatile organic compounds (VOCs) can cause atmospheric environmental problems such as haze and photochemical smog, which seriously restrict the sustainable development of the environment and threaten human health. Effective and comprehensive implementation of VOC prevention is an arduous task. Catalytic oxidation can achieve VOC removal with low energy costs and high efficiency. This review presents representative research progress in thermal or photothermal catalysis over the past ten years, concentrating on various catalysts with distinctive morphologies and structures designed and prepared for investigating single- or multi-component VOC purification, synergetic elimination of VOCs and NOx, and VOCs resource utilization. Furthermore, the influence mechanisms of H2O, CO2, and SO2 on the catalytic stability are summarized. The activity and stability of the catalysts affect their lifespan and cost of use. In particular, for supported noble-metal catalysts with poor stability, some unique design strategies have been summarized for the efficient removal of VOCs while balancing low noble-metal usage and optimized catalytic performance. Finally, the scientific problems and future research directions are presented. Coordinated treatment of atmospheric pollutants and greenhouse gases should be considered. This study is expected to provide profound insights into the design of catalysts with high activity, selectivity, and stability, as well as air pollution control via catalytic methods.

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来源期刊
Chinese Journal of Catalysis
Chinese Journal of Catalysis 工程技术-工程:化工
CiteScore
25.80
自引率
10.30%
发文量
235
审稿时长
1.2 months
期刊介绍: The journal covers a broad scope, encompassing new trends in catalysis for applications in energy production, environmental protection, and the preparation of materials, petroleum chemicals, and fine chemicals. It explores the scientific foundation for preparing and activating catalysts of commercial interest, emphasizing representative models.The focus includes spectroscopic methods for structural characterization, especially in situ techniques, as well as new theoretical methods with practical impact in catalysis and catalytic reactions.The journal delves into the relationship between homogeneous and heterogeneous catalysis and includes theoretical studies on the structure and reactivity of catalysts.Additionally, contributions on photocatalysis, biocatalysis, surface science, and catalysis-related chemical kinetics are welcomed.
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