Vadakkaveedu Subramanian Niranjana, Jae Uk Yoon, Insun Woo, Prasad Gajula, Jin Woo Bae, Arun Anand Prabu
{"title":"利用电纺丝技术探索一种新型 PVDF/3-氨基丙基三乙氧基硅烷(芯材)和 2,2-双(羟甲基)丁酸(单体)基超支化聚酯杂化纤维,以提高三电性能","authors":"Vadakkaveedu Subramanian Niranjana, Jae Uk Yoon, Insun Woo, Prasad Gajula, Jin Woo Bae, Arun Anand Prabu","doi":"10.1002/adsu.202400311","DOIUrl":null,"url":null,"abstract":"<p>With the rapid advancement in sensor technologies, triboelectric nanogenerators (TENGs) have emerged as a promising sustainable power source for intelligent electronics. Herein, fabricated a novel 3-aminopropyltriethoxysilane (core) and 2,2-bis(hydroxymethyl)butyric acid (monomer)-based hyperbranched polyester by facile single-step polycondensation technique generation 2 (Si-HBP-G2). Further, a new class of polyvinylidene fluoride (PVDF) and different weight percentages (0, 5, 10, 15, and 20 wt%) of Si-HBP-G2 hybrid fiber blends are prepared by traditional electrospinning technique. The as-prepared Si-HBP-G2 and its blends are well characterized using SEM/EDS, FTIR, NMR, and XRD studies. The influence of Si-HBP-G2 content on triboelectric performance in terms of the open circuit potential (V<sub>OC</sub>) and short circuit current (I<sub>SC</sub>) is evaluated using aluminum (Al) as a counter electrode. Among them, 15 wt% of Si-HBP-G2/PVDF hybrid fiber mat (PG2-15) exhibits superior electrical performance. Which is almost increased 5.9 times (22–130 V) of V<sub>OC</sub> and 4.9 times (0.71–3.5 µA) of I<sub>SC</sub> than PVDF fiber mate. These results reveal the significance of Si-HBP-G2 in the triboelectric performance. The optimized TENG device (PG2-15/Al-TENG) exhibits a peak power density of 0.2 Wm<sup>−2</sup> at 100 MΩ external load. Finally, the PG2-15/Al-TENG practically demonstrates real-time application energy harvesting applications such as powering 100 LEDs and a stopwatch.</p>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"8 11","pages":""},"PeriodicalIF":6.5000,"publicationDate":"2024-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adsu.202400311","citationCount":"0","resultStr":"{\"title\":\"Exploring a New Class of PVDF/3-Aminopropyltriethoxysilane (core) and 2,2-Bis(hydroxymethyl)butyric Acid (monomer)-Based Hyperbranched Polyester Hybrid Fibers by Electrospinning Technique for Enhancing Triboelectric Performance\",\"authors\":\"Vadakkaveedu Subramanian Niranjana, Jae Uk Yoon, Insun Woo, Prasad Gajula, Jin Woo Bae, Arun Anand Prabu\",\"doi\":\"10.1002/adsu.202400311\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>With the rapid advancement in sensor technologies, triboelectric nanogenerators (TENGs) have emerged as a promising sustainable power source for intelligent electronics. Herein, fabricated a novel 3-aminopropyltriethoxysilane (core) and 2,2-bis(hydroxymethyl)butyric acid (monomer)-based hyperbranched polyester by facile single-step polycondensation technique generation 2 (Si-HBP-G2). Further, a new class of polyvinylidene fluoride (PVDF) and different weight percentages (0, 5, 10, 15, and 20 wt%) of Si-HBP-G2 hybrid fiber blends are prepared by traditional electrospinning technique. The as-prepared Si-HBP-G2 and its blends are well characterized using SEM/EDS, FTIR, NMR, and XRD studies. The influence of Si-HBP-G2 content on triboelectric performance in terms of the open circuit potential (V<sub>OC</sub>) and short circuit current (I<sub>SC</sub>) is evaluated using aluminum (Al) as a counter electrode. Among them, 15 wt% of Si-HBP-G2/PVDF hybrid fiber mat (PG2-15) exhibits superior electrical performance. Which is almost increased 5.9 times (22–130 V) of V<sub>OC</sub> and 4.9 times (0.71–3.5 µA) of I<sub>SC</sub> than PVDF fiber mate. These results reveal the significance of Si-HBP-G2 in the triboelectric performance. The optimized TENG device (PG2-15/Al-TENG) exhibits a peak power density of 0.2 Wm<sup>−2</sup> at 100 MΩ external load. Finally, the PG2-15/Al-TENG practically demonstrates real-time application energy harvesting applications such as powering 100 LEDs and a stopwatch.</p>\",\"PeriodicalId\":7294,\"journal\":{\"name\":\"Advanced Sustainable Systems\",\"volume\":\"8 11\",\"pages\":\"\"},\"PeriodicalIF\":6.5000,\"publicationDate\":\"2024-07-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adsu.202400311\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advanced Sustainable Systems\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/adsu.202400311\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Sustainable Systems","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/adsu.202400311","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY","Score":null,"Total":0}
Exploring a New Class of PVDF/3-Aminopropyltriethoxysilane (core) and 2,2-Bis(hydroxymethyl)butyric Acid (monomer)-Based Hyperbranched Polyester Hybrid Fibers by Electrospinning Technique for Enhancing Triboelectric Performance
With the rapid advancement in sensor technologies, triboelectric nanogenerators (TENGs) have emerged as a promising sustainable power source for intelligent electronics. Herein, fabricated a novel 3-aminopropyltriethoxysilane (core) and 2,2-bis(hydroxymethyl)butyric acid (monomer)-based hyperbranched polyester by facile single-step polycondensation technique generation 2 (Si-HBP-G2). Further, a new class of polyvinylidene fluoride (PVDF) and different weight percentages (0, 5, 10, 15, and 20 wt%) of Si-HBP-G2 hybrid fiber blends are prepared by traditional electrospinning technique. The as-prepared Si-HBP-G2 and its blends are well characterized using SEM/EDS, FTIR, NMR, and XRD studies. The influence of Si-HBP-G2 content on triboelectric performance in terms of the open circuit potential (VOC) and short circuit current (ISC) is evaluated using aluminum (Al) as a counter electrode. Among them, 15 wt% of Si-HBP-G2/PVDF hybrid fiber mat (PG2-15) exhibits superior electrical performance. Which is almost increased 5.9 times (22–130 V) of VOC and 4.9 times (0.71–3.5 µA) of ISC than PVDF fiber mate. These results reveal the significance of Si-HBP-G2 in the triboelectric performance. The optimized TENG device (PG2-15/Al-TENG) exhibits a peak power density of 0.2 Wm−2 at 100 MΩ external load. Finally, the PG2-15/Al-TENG practically demonstrates real-time application energy harvesting applications such as powering 100 LEDs and a stopwatch.
期刊介绍:
Advanced Sustainable Systems, a part of the esteemed Advanced portfolio, serves as an interdisciplinary sustainability science journal. It focuses on impactful research in the advancement of sustainable, efficient, and less wasteful systems and technologies. Aligned with the UN's Sustainable Development Goals, the journal bridges knowledge gaps between fundamental research, implementation, and policy-making. Covering diverse topics such as climate change, food sustainability, environmental science, renewable energy, water, urban development, and socio-economic challenges, it contributes to the understanding and promotion of sustainable systems.