Impact origin of lunar zircon melt inclusions in Apollo impact melt breccia 14311

Investigations of trapped melt inclusions in minerals can yield insights into the compositions and conditions of parent magmas. These insights are particularly important for detrital grains like many of the lunar zircons found in samples returned by the Apollo missions. However, unlike their terrestrial counterparts, lunar zircons have potentially been exposed to billions of years of impact bombardment. Samples from terrestrial impact structures and impact shock experiments have revealed that deformation during an impact event produces melt and glass blebs that can mimic igneous melt inclusions in both morphology and composition. We have undertaken a geochemical and textural investigation of zircons from Apollo impact melt breccia 14311 to assess their formation mechanisms. The association of trapped melts with shock microtwins and monomineralic melt compositions suggests some inclusions formed as a result of the high pressures and temperatures of impact shock. All other inclusions in this study are associated with curviplanar features, planar features, crystal plastic deformation, or embayments (large regions in contact with adjacent melts or minerals) suggesting that they are not igneous melt inclusions. While these textures can be produced in tectonic environments, impacts are a likely formation mechanism since impacts are the main driver of tectonics on the Moon. The results of this study demonstrate that a combination of textural and compositional analyses can be employed distinguish between igneous melt inclusions and melt blebs in zircons from impact environments.