通过掺杂 Sm3+ 的钠钙硼酸铝玻璃产生橙色激光介质材料的浓度依赖性

IF 1.9 4区材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY

Physica Status Solidi A-applications and Materials Science Pub Date : 2024-07-09 DOI:10.1002/pssa.202400174

Nawarut Jarucha, Yotsakit Ruangtaweep, Piyachat Meejitpaisan, Hong Joo Kim, Phongnared Boontueng, Chinorat Kobdaj, Narongrit Ritjoho, Taweap Sanghangthum, Damir Valiev, Jakrapong Kaewkhao

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引用次数: 0

摘要

利用熔融淬火技术制造了掺杂不同浓度 Sm3+ 离子的钙钠硼酸铝玻璃（Sm：ANCB）。分析了 ANCBSm 玻璃的特性，包括密度、摩尔体积、折射率、吸收、发射（通过可见光、X 射线和质子激发）、衰减时间和 CIE 色坐标。ANCBSm 玻璃的密度、摩尔体积和折射率随 Sm2O3 浓度的增加而增加。Sm3+ 离子在可见光和近红外区域都有光子吸收，在各种激发下，由于 6H5/2 → 6P3/2 转变，在 600 纳米处有强烈的橘红色发射。X 射线激发也与 BGO 闪烁晶体进行了比较。J-O 理论预测了 Sm3+ 离子发射水平的辐射特性。6H5/2 级的衰减曲线显示出单指数性质，寿命为毫秒级。ANCBSm 玻璃的 CIE 色度为橘红色。ANCBSm 玻璃有望应用于橙色激光介质材料。

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Concentration Dependence Orange Light Generation Through Sm3+‐Doped Soda Lime Alumino Borate Glasses for Orange Laser Medium Material

The melt‐quenching technique is used to fabricate calcium sodium aluminum borate glasses (Sm: ANCB) doped with varying concentrations of Sm3+ ions. Characteristics of ANCBSm glasses, including density, molar volume, refractive index, absorption, emission (via visible light, X‐ray, and proton excitation), decay time, and CIE color coordinates, are analyzed. The density, molar volume, and refractive index of ANCBSm glass increased with Sm2O3 concentration. Sm3+ ions enabled photon absorption in both visible and NIR regions, with a strong reddish‐orange emission at 600 nm due to the 6H5/2 → 6P3/2 transition under various excitations. X‐ray excitation is also compared with BGO scintillation crystals. The J–O theory predicted the radiative properties of Sm3+ ion emission levels. Decay curves of the 6H5/2 levels showed a single exponential nature with a millisecond‐order lifetime. CIE chromaticity of ANCBSm glasses is in the reddish‐orange region. ANCBSm glasses have potential applications in orange laser medium material.

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来源期刊

Physica Status Solidi A-applications and Materials Science 工程技术-材料科学：综合

CiteScore

3.70

自引率

5.00%

发文量

393

审稿时长

2 months

期刊介绍： The physica status solidi (pss) journal group is devoted to the thorough peer review and the rapid publication of new and important results in all fields of solid state and materials physics, from basic science to applications and devices. Among the largest and most established international publications, the pss journals publish reviews, letters and original articles, as regular content as well as in special issues and topical sections.