{"title":"木质素磺酸钠可增强市政污泥好氧堆肥中重金属钝化的不溶性硫酸盐和磷酸盐形成","authors":"G. Liu, Z. Hu, W. Huang, Y. Zheng, F. Yang, Y. Su","doi":"10.1007/s13762-024-05872-6","DOIUrl":null,"url":null,"abstract":"<p>Municipal sludge aerobic compost application in land faces limitations due to the potential hazard of heavy metals, and adding heavy metal passivator proved a pathway to relieve this issue. However, as a heavy metal passivator, sodium lignosulfonate hasn't been applied in municipal sludge aerobic compost. In this paper, we selected sodium lignosulfonate and proportionally added it to municipal sludge aerobic compost for 45 days to evaluate the passivation impact of Cr, Zn, Pb and Cu. The results showed that sodium lignosulfonate can improve the stability of heavy metals by reducing the bioavailable forms. Specifically, adding 5% sodium lignosulfonate showed the best passivation effect of heavy metals with passivation rates of Cr, Zn, Pb and Cu at 81.46%, 32.58%, 98.61% and 30.91%, respectively. What’s more, scanning electron microscope energy dispersive system, Fourier transforms infrared spectroscopy, X-ray photoelectron spectroscopy and X-ray powder diffraction revealed that sodium lignosulfonate promoted the passivation of heavy metals by enhancing the degradation of organic matter and forming new insoluble sulfates and phosphates. This study might contribute to the understanding of the mechanism of heavy metal passivation during aerobic composting.</p><h3 data-test=\"abstract-sub-heading\">Graphical abstract</h3>\n","PeriodicalId":589,"journal":{"name":"International Journal of Environmental Science and Technology","volume":null,"pages":null},"PeriodicalIF":3.0000,"publicationDate":"2024-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Sodium lignosulfonate enhances the insoluble sulfates and phosphates formation of heavy metal passivation in municipal sludge aerobic composting\",\"authors\":\"G. Liu, Z. Hu, W. Huang, Y. Zheng, F. Yang, Y. Su\",\"doi\":\"10.1007/s13762-024-05872-6\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Municipal sludge aerobic compost application in land faces limitations due to the potential hazard of heavy metals, and adding heavy metal passivator proved a pathway to relieve this issue. However, as a heavy metal passivator, sodium lignosulfonate hasn't been applied in municipal sludge aerobic compost. In this paper, we selected sodium lignosulfonate and proportionally added it to municipal sludge aerobic compost for 45 days to evaluate the passivation impact of Cr, Zn, Pb and Cu. The results showed that sodium lignosulfonate can improve the stability of heavy metals by reducing the bioavailable forms. Specifically, adding 5% sodium lignosulfonate showed the best passivation effect of heavy metals with passivation rates of Cr, Zn, Pb and Cu at 81.46%, 32.58%, 98.61% and 30.91%, respectively. What’s more, scanning electron microscope energy dispersive system, Fourier transforms infrared spectroscopy, X-ray photoelectron spectroscopy and X-ray powder diffraction revealed that sodium lignosulfonate promoted the passivation of heavy metals by enhancing the degradation of organic matter and forming new insoluble sulfates and phosphates. This study might contribute to the understanding of the mechanism of heavy metal passivation during aerobic composting.</p><h3 data-test=\\\"abstract-sub-heading\\\">Graphical abstract</h3>\\n\",\"PeriodicalId\":589,\"journal\":{\"name\":\"International Journal of Environmental Science and Technology\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.0000,\"publicationDate\":\"2024-07-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Environmental Science and Technology\",\"FirstCategoryId\":\"93\",\"ListUrlMain\":\"https://doi.org/10.1007/s13762-024-05872-6\",\"RegionNum\":4,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENVIRONMENTAL SCIENCES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Environmental Science and Technology","FirstCategoryId":"93","ListUrlMain":"https://doi.org/10.1007/s13762-024-05872-6","RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENVIRONMENTAL SCIENCES","Score":null,"Total":0}
引用次数: 0
摘要
由于重金属的潜在危害,城市污泥好氧堆肥在土地中的应用受到限制,而添加重金属钝化剂被证明是缓解这一问题的途径。然而,木质素磺酸钠作为一种重金属钝化剂,尚未在市政污泥好氧堆肥中应用过。本文选择了木质素磺酸钠,并将其按比例添加到市政污泥好氧堆肥中 45 天,以评估其对铬、锌、铅和铜的钝化效果。结果表明,木质素磺酸钠可以通过减少重金属的生物可利用形式来提高重金属的稳定性。具体来说,添加 5%的木质素磺酸钠对重金属的钝化效果最好,对 Cr、Zn、Pb 和 Cu 的钝化率分别为 81.46%、32.58%、98.61% 和 30.91%。此外,扫描电子显微镜能量色散系统、傅立叶变换红外光谱、X 射线光电子能谱和 X 射线粉末衍射显示,木质素磺酸钠通过促进有机物降解并形成新的不溶性硫酸盐和磷酸盐来促进重金属的钝化。这项研究可能有助于理解好氧堆肥过程中重金属钝化的机理。
Sodium lignosulfonate enhances the insoluble sulfates and phosphates formation of heavy metal passivation in municipal sludge aerobic composting
Municipal sludge aerobic compost application in land faces limitations due to the potential hazard of heavy metals, and adding heavy metal passivator proved a pathway to relieve this issue. However, as a heavy metal passivator, sodium lignosulfonate hasn't been applied in municipal sludge aerobic compost. In this paper, we selected sodium lignosulfonate and proportionally added it to municipal sludge aerobic compost for 45 days to evaluate the passivation impact of Cr, Zn, Pb and Cu. The results showed that sodium lignosulfonate can improve the stability of heavy metals by reducing the bioavailable forms. Specifically, adding 5% sodium lignosulfonate showed the best passivation effect of heavy metals with passivation rates of Cr, Zn, Pb and Cu at 81.46%, 32.58%, 98.61% and 30.91%, respectively. What’s more, scanning electron microscope energy dispersive system, Fourier transforms infrared spectroscopy, X-ray photoelectron spectroscopy and X-ray powder diffraction revealed that sodium lignosulfonate promoted the passivation of heavy metals by enhancing the degradation of organic matter and forming new insoluble sulfates and phosphates. This study might contribute to the understanding of the mechanism of heavy metal passivation during aerobic composting.
期刊介绍:
International Journal of Environmental Science and Technology (IJEST) is an international scholarly refereed research journal which aims to promote the theory and practice of environmental science and technology, innovation, engineering and management.
A broad outline of the journal''s scope includes: peer reviewed original research articles, case and technical reports, reviews and analyses papers, short communications and notes to the editor, in interdisciplinary information on the practice and status of research in environmental science and technology, both natural and man made.
The main aspects of research areas include, but are not exclusive to; environmental chemistry and biology, environments pollution control and abatement technology, transport and fate of pollutants in the environment, concentrations and dispersion of wastes in air, water, and soil, point and non-point sources pollution, heavy metals and organic compounds in the environment, atmospheric pollutants and trace gases, solid and hazardous waste management; soil biodegradation and bioremediation of contaminated sites; environmental impact assessment, industrial ecology, ecological and human risk assessment; improved energy management and auditing efficiency and environmental standards and criteria.