Effect of ceria morphology on hydrogen production via methane steam reforming for membrane reformer

Hydrogen is a potential energy carrier in comparison to conventional fuels due to its high energy content. Methane is an attractive source for ‘on-site’ production of hydrogen by using membrane reformer due to its low cost. However, such reformers are not well studied and high temperature operation of steam methane reforming (SMR) makes the integration with membrane separation difficult. Further, the main product of SMR is CO and H₂ in which CO has an inhibition effect on the membrane separation process. Therefore, it is vital to synthesize a low temperature and low CO selective catalyst for a suitable integration with membrane reformer. Nickel-based catalyst is widely used for SMR due to its low cost and high catalytic activity. CeO₂ is a favoured support as it mobilizes the lattice oxygen and reduces the coke formation and CO selectivity. Though several studies are reported on CeO₂ based support, the effect of CeO₂ surface morphology is not studied for SMR. In the current work, Ni/CeO₂ of different shapes (nanocube and nanorod) are synthesized. The complete characterization of the support was performed. The effect of support shape, calcination temperature, and reduction temperature on SMR activity is found at different operating temperatures. For each condition conversion, CO, CO₂ selectivity, and hydrogen yield are calculated. The results show the CeO₂ morphology has a considerable effect on conversion, CO selectivity, and hydrogen yield. It is found that ceria nanocube calcined at 550°C provides better performance at high temperature.