Qing Zhou, Yanjun Du, Zihao Feng, Qi Ren, Yang Wang, Xiaoyong Chen, Yang Li, Yun Wang
{"title":"制备 MnO2 改性冬瓜生物炭以增强水溶液中 U(VI) 的吸附能力","authors":"Qing Zhou, Yanjun Du, Zihao Feng, Qi Ren, Yang Wang, Xiaoyong Chen, Yang Li, Yun Wang","doi":"10.1515/ract-2024-0301","DOIUrl":null,"url":null,"abstract":"This work synthesized MnO<jats:sub>2</jats:sub> modified winter melon-derived biochar (MnO<jats:sub>2</jats:sub>@WBC) using potassium permanganate oxidation/hydrothermal method for uranium(VI) removal. The factors influencing uranium(VI) adsorption by MnO<jats:sub>2</jats:sub>@WBC, including pH, adsorbent dosage, time, temperature, and initial U(VI) concentration were explored. The material’s performance was characterized, and the underlying mechanism of U(VI) removal was analyzed using various techniques. The characterization results indicated that the MnO<jats:sub>2</jats:sub>@WBC exhibited excellent dispersibility, suggesting that MnO<jats:sub>2</jats:sub> effectively prevented WBC aggregation and enhanced the reactive surface area, and providing more active sites that can effectively promote the complexation and adsorption of U(VI). The process suggested a dominant role for chemical adsorption. The Freundlich isotherm model demonstrated a high degree of alignment with the observed adsorption behavior, indicating a predominantly multilayer adsorption process. Thermodynamic studies indicated that adsorption was a spontaneous endothermic process. The XPS analysis demonstrated that the adsorption process was primarily due to the formation of stable complexes with C–O, Mn–O–H and C=O. The results demonstrated that MnO<jats:sub>2</jats:sub>@WBC effectively removed U(VI), achieving a maximum adsorption capacity of 240.86 mg g<jats:sup>−1</jats:sup> at a pH of 5.0. These findings provided a theoretical basis for the treatment of wastewater contaminated with U(VI).","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2024-07-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Preparation of MnO2 modified winter melon-derived biochar for enhanced adsorption of U(VI) from aqueous solution\",\"authors\":\"Qing Zhou, Yanjun Du, Zihao Feng, Qi Ren, Yang Wang, Xiaoyong Chen, Yang Li, Yun Wang\",\"doi\":\"10.1515/ract-2024-0301\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"This work synthesized MnO<jats:sub>2</jats:sub> modified winter melon-derived biochar (MnO<jats:sub>2</jats:sub>@WBC) using potassium permanganate oxidation/hydrothermal method for uranium(VI) removal. The factors influencing uranium(VI) adsorption by MnO<jats:sub>2</jats:sub>@WBC, including pH, adsorbent dosage, time, temperature, and initial U(VI) concentration were explored. The material’s performance was characterized, and the underlying mechanism of U(VI) removal was analyzed using various techniques. The characterization results indicated that the MnO<jats:sub>2</jats:sub>@WBC exhibited excellent dispersibility, suggesting that MnO<jats:sub>2</jats:sub> effectively prevented WBC aggregation and enhanced the reactive surface area, and providing more active sites that can effectively promote the complexation and adsorption of U(VI). The process suggested a dominant role for chemical adsorption. The Freundlich isotherm model demonstrated a high degree of alignment with the observed adsorption behavior, indicating a predominantly multilayer adsorption process. Thermodynamic studies indicated that adsorption was a spontaneous endothermic process. The XPS analysis demonstrated that the adsorption process was primarily due to the formation of stable complexes with C–O, Mn–O–H and C=O. The results demonstrated that MnO<jats:sub>2</jats:sub>@WBC effectively removed U(VI), achieving a maximum adsorption capacity of 240.86 mg g<jats:sup>−1</jats:sup> at a pH of 5.0. These findings provided a theoretical basis for the treatment of wastewater contaminated with U(VI).\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":16.4000,\"publicationDate\":\"2024-07-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1515/ract-2024-0301\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1515/ract-2024-0301","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Preparation of MnO2 modified winter melon-derived biochar for enhanced adsorption of U(VI) from aqueous solution
This work synthesized MnO2 modified winter melon-derived biochar (MnO2@WBC) using potassium permanganate oxidation/hydrothermal method for uranium(VI) removal. The factors influencing uranium(VI) adsorption by MnO2@WBC, including pH, adsorbent dosage, time, temperature, and initial U(VI) concentration were explored. The material’s performance was characterized, and the underlying mechanism of U(VI) removal was analyzed using various techniques. The characterization results indicated that the MnO2@WBC exhibited excellent dispersibility, suggesting that MnO2 effectively prevented WBC aggregation and enhanced the reactive surface area, and providing more active sites that can effectively promote the complexation and adsorption of U(VI). The process suggested a dominant role for chemical adsorption. The Freundlich isotherm model demonstrated a high degree of alignment with the observed adsorption behavior, indicating a predominantly multilayer adsorption process. Thermodynamic studies indicated that adsorption was a spontaneous endothermic process. The XPS analysis demonstrated that the adsorption process was primarily due to the formation of stable complexes with C–O, Mn–O–H and C=O. The results demonstrated that MnO2@WBC effectively removed U(VI), achieving a maximum adsorption capacity of 240.86 mg g−1 at a pH of 5.0. These findings provided a theoretical basis for the treatment of wastewater contaminated with U(VI).
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.