封面特写:13 族/基于 Ylide 的 Ambiphiles 对 σ 键的活化:理解与设计(ChemistryEurope 3-4/2024)

Daniel González-Pinardo, Dr. Felix Krämer, Prof. Dr. Frank Breher, Prof. Dr. Israel Fernández
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引用次数: 0

摘要

封面说明了基于第 13 族 ylide 的双亲化合物(也称为隐藏的受挫路易斯对 (FLP))在促进σ-E-H 键活化方面的作用。在他们的研究文章中,F. Breher、I. Fernández 和合作者利用量子化学工具,通过计算探索了控制隐藏式路易斯对促进σ键活化的因素。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Cover Feature: Activation of σ-Bonds by Group 13/Ylide-Based Ambiphiles: Understanding and Design (ChemistryEurope 3-4/2024)

Cover Feature: Activation of σ-Bonds by Group 13/Ylide-Based Ambiphiles: Understanding and Design (ChemistryEurope 3-4/2024)

The cover illustrates the usefulness of the Group 13 ylide-based amphiphiles, also known as hidden frustrated Lewis pairs (FLP), towards the facile activation of σ-E−H bonds. In their Research Article, F. Breher, I. Fernández and co-workers computationally explored the factors controlling the activation of sigma bonds promoted by hidden FLP using quantum chemical tools.

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