Dr. Vladimir Motornov, Martin Procházka, Nora Alpuente, Dr. Pedro Salvador, Prof. Petr Slavíček, Dr. Blanka Klepetářová, Prof. Xavi Ribas, Dr. Petr Beier
{"title":"封面专题：弱连接三(三氟甲基)铜(III)介绍（欧洲化学 3-4/2024）","authors":"Dr. Vladimir Motornov, Martin Procházka, Nora Alpuente, Dr. Pedro Salvador, Prof. Petr Slavíček, Dr. Blanka Klepetářová, Prof. Xavi Ribas, Dr. Petr Beier","doi":"10.1002/ceur.202400049","DOIUrl":null,"url":null,"abstract":"<p><b>An elusive T-shaped high-valent Cu<sup>III</sup> derivative</b>, Cu(CF<sub>3</sub>)<sub>3</sub> which is depicted on the cover, was stabilized in the form of solvates and theoretically studied. In their Research Article, V. Motornov, X. Ribas, P. Beier, and co-workers report the synthesis of solvates Cu(CF<sub>3</sub>)<sub>3</sub>⋅2DMF and Cu(CF<sub>3</sub>)<sub>3</sub>⋅MeCN, which were fully characterized including X-ray crystallography. Ligand substitution in these solvates enables access to a variety of new high-valent Cu<sup>III</sup> complexes. The authors would like to thank Tomáš Belloň for creating the artwork.\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure>\n </p>","PeriodicalId":100234,"journal":{"name":"ChemistryEurope","volume":"2 3-4","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-07-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ceur.202400049","citationCount":"0","resultStr":"{\"title\":\"Cover Feature: Introducing Weakly Ligated Tris(trifluoromethyl)copper(III) (ChemistryEurope 3-4/2024)\",\"authors\":\"Dr. Vladimir Motornov, Martin Procházka, Nora Alpuente, Dr. Pedro Salvador, Prof. Petr Slavíček, Dr. Blanka Klepetářová, Prof. Xavi Ribas, Dr. Petr Beier\",\"doi\":\"10.1002/ceur.202400049\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><b>An elusive T-shaped high-valent Cu<sup>III</sup> derivative</b>, Cu(CF<sub>3</sub>)<sub>3</sub> which is depicted on the cover, was stabilized in the form of solvates and theoretically studied. In their Research Article, V. Motornov, X. Ribas, P. Beier, and co-workers report the synthesis of solvates Cu(CF<sub>3</sub>)<sub>3</sub>⋅2DMF and Cu(CF<sub>3</sub>)<sub>3</sub>⋅MeCN, which were fully characterized including X-ray crystallography. Ligand substitution in these solvates enables access to a variety of new high-valent Cu<sup>III</sup> complexes. The authors would like to thank Tomáš Belloň for creating the artwork.\\n <figure>\\n <div><picture>\\n <source></source></picture><p></p>\\n </div>\\n </figure>\\n </p>\",\"PeriodicalId\":100234,\"journal\":{\"name\":\"ChemistryEurope\",\"volume\":\"2 3-4\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-07-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ceur.202400049\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ChemistryEurope\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/ceur.202400049\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemistryEurope","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ceur.202400049","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
一种难以捉摸的 T 型高价 CuIII 衍生物 Cu(CF3)3（如封面所示）以溶胶的形式得到了稳定，并进行了理论研究。在研究文章中，V. Motornov、X. Ribas、P. Beier 及其合作者报告了 Cu(CF3)3⋅2DMF 和 Cu(CF3)3⋅MeCN 溶合物的合成，并对其进行了包括 X 射线晶体学在内的全面表征。在这些溶解物中进行配体置换可以获得各种新的高价 CuIII 复合物。作者感谢 Tomáš Belloň 创作了这幅作品。
An elusive T-shaped high-valent CuIII derivative, Cu(CF3)3 which is depicted on the cover, was stabilized in the form of solvates and theoretically studied. In their Research Article, V. Motornov, X. Ribas, P. Beier, and co-workers report the synthesis of solvates Cu(CF3)3⋅2DMF and Cu(CF3)3⋅MeCN, which were fully characterized including X-ray crystallography. Ligand substitution in these solvates enables access to a variety of new high-valent CuIII complexes. The authors would like to thank Tomáš Belloň for creating the artwork.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
