Lu-Lu Zhao , Shan Zhao , Nan Zhang , Peng-Fei Wang , Zong-Lin Liu , Ying Xie , Jie Shu , Ting-Feng Yi
{"title":"利用无机功能保护层构建稳定的锌金属阳极,实现长寿命水性锌离子电池","authors":"Lu-Lu Zhao , Shan Zhao , Nan Zhang , Peng-Fei Wang , Zong-Lin Liu , Ying Xie , Jie Shu , Ting-Feng Yi","doi":"10.1016/j.ensm.2024.103628","DOIUrl":null,"url":null,"abstract":"<div><p>Aqueous Zinc-ion batteries (AZIBs) have received widespread attention due to their high safety, low cost and environmental friendliness, making them regarded as one of the most prospective energy storage devices. To achieve the commercial application of AZIBs, the design and modification of Zn metal anodes are crucial. Current zinc metal anodes face challenges in terms of battery cycling stability, such as Zn dendrite growth, hydrogen evolution reaction (HER), corrosion and passivation. To solve these problems, strategies have been proposed to modify the Zn anode interface by improving the contact between the anode and the electrolyte, thus altering the zinc anode interface. Among these, the inorganic functional protective layer can effectively enhance the uniform deposition of Zn<sup>2+</sup>, increase the reversibility of the zinc anode, and inhibit the generation of side reactions such as zinc dendrites and HER. Herein, the review starts by providing a concise summary of the challenges faced by Zn anodes and the interrelationships behind them. Subsequently, the latest advances in inorganic functional protective layers cladding zinc anodes leading to high-performance AZIBs are presented in detail, including metal compounds, inorganic non-metal materials, novel materials (MXene/MOF/COF), and other hybrid materials. The working mechanisms of the inorganic functional protective layers and modification designs for Zn anodes are described thoroughly. Finally, the challenges and future development of zinc anode interface modification as a strategy are also discussed, which provides a reference value for the practical application of AZIBs.</p></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":null,"pages":null},"PeriodicalIF":18.9000,"publicationDate":"2024-07-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Construction of stable Zn metal anode by inorganic functional protective layer toward long-life aqueous Zn-ion battery\",\"authors\":\"Lu-Lu Zhao , Shan Zhao , Nan Zhang , Peng-Fei Wang , Zong-Lin Liu , Ying Xie , Jie Shu , Ting-Feng Yi\",\"doi\":\"10.1016/j.ensm.2024.103628\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Aqueous Zinc-ion batteries (AZIBs) have received widespread attention due to their high safety, low cost and environmental friendliness, making them regarded as one of the most prospective energy storage devices. To achieve the commercial application of AZIBs, the design and modification of Zn metal anodes are crucial. Current zinc metal anodes face challenges in terms of battery cycling stability, such as Zn dendrite growth, hydrogen evolution reaction (HER), corrosion and passivation. To solve these problems, strategies have been proposed to modify the Zn anode interface by improving the contact between the anode and the electrolyte, thus altering the zinc anode interface. Among these, the inorganic functional protective layer can effectively enhance the uniform deposition of Zn<sup>2+</sup>, increase the reversibility of the zinc anode, and inhibit the generation of side reactions such as zinc dendrites and HER. Herein, the review starts by providing a concise summary of the challenges faced by Zn anodes and the interrelationships behind them. Subsequently, the latest advances in inorganic functional protective layers cladding zinc anodes leading to high-performance AZIBs are presented in detail, including metal compounds, inorganic non-metal materials, novel materials (MXene/MOF/COF), and other hybrid materials. The working mechanisms of the inorganic functional protective layers and modification designs for Zn anodes are described thoroughly. Finally, the challenges and future development of zinc anode interface modification as a strategy are also discussed, which provides a reference value for the practical application of AZIBs.</p></div>\",\"PeriodicalId\":306,\"journal\":{\"name\":\"Energy Storage Materials\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":18.9000,\"publicationDate\":\"2024-07-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Energy Storage Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2405829724004549\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Energy Storage Materials","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2405829724004549","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Construction of stable Zn metal anode by inorganic functional protective layer toward long-life aqueous Zn-ion battery
Aqueous Zinc-ion batteries (AZIBs) have received widespread attention due to their high safety, low cost and environmental friendliness, making them regarded as one of the most prospective energy storage devices. To achieve the commercial application of AZIBs, the design and modification of Zn metal anodes are crucial. Current zinc metal anodes face challenges in terms of battery cycling stability, such as Zn dendrite growth, hydrogen evolution reaction (HER), corrosion and passivation. To solve these problems, strategies have been proposed to modify the Zn anode interface by improving the contact between the anode and the electrolyte, thus altering the zinc anode interface. Among these, the inorganic functional protective layer can effectively enhance the uniform deposition of Zn2+, increase the reversibility of the zinc anode, and inhibit the generation of side reactions such as zinc dendrites and HER. Herein, the review starts by providing a concise summary of the challenges faced by Zn anodes and the interrelationships behind them. Subsequently, the latest advances in inorganic functional protective layers cladding zinc anodes leading to high-performance AZIBs are presented in detail, including metal compounds, inorganic non-metal materials, novel materials (MXene/MOF/COF), and other hybrid materials. The working mechanisms of the inorganic functional protective layers and modification designs for Zn anodes are described thoroughly. Finally, the challenges and future development of zinc anode interface modification as a strategy are also discussed, which provides a reference value for the practical application of AZIBs.
期刊介绍:
Energy Storage Materials is a global interdisciplinary journal dedicated to sharing scientific and technological advancements in materials and devices for advanced energy storage and related energy conversion, such as in metal-O2 batteries. The journal features comprehensive research articles, including full papers and short communications, as well as authoritative feature articles and reviews by leading experts in the field.
Energy Storage Materials covers a wide range of topics, including the synthesis, fabrication, structure, properties, performance, and technological applications of energy storage materials. Additionally, the journal explores strategies, policies, and developments in the field of energy storage materials and devices for sustainable energy.
Published papers are selected based on their scientific and technological significance, their ability to provide valuable new knowledge, and their relevance to the international research community.