{"title":"用于增强卡马西平催化降解和制氢的协同双金属 MOF 集成 MXene 纳米片:用于水修复和能源应用的双功能方法","authors":"Van-Anh Thai, Thanh-Binh Nguyen, Chiu-Wen Chen, Xuan-Thanh Bui, Ruey-an Doong and Cheng-Di Dong","doi":"10.1039/D4EN00324A","DOIUrl":null,"url":null,"abstract":"<p >This study introduces a novel metallic MOF composite, MIL-100@ZIF-67, anchored on MXene nanosheets, designated as MIL-100@ZIF-67@MXene, for the enhanced degradation of carbamazepine (CBZ) and activation of peroxymonosulfate (PMS). The efficacy of the composite in CBZ degradation and the underlying reaction parameters and mechanisms were thoroughly investigated. Remarkably, the MIL-100@ZIF-67@MXene/PMS system achieved a 95% reduction of CBZ within 30 min under neutral pH conditions. Scavenger experiments and electron paramagnetic resonance (EPR) analysis confirmed that a combination of radicals (SO<small><sub>4</sub></small>˙<small><sup>−</sup></small>, ˙OH and O<small><sub>2</sub></small>˙<small><sup>−</sup></small>) and non-radicals (<small><sup>1</sup></small>O<small><sub>2</sub></small> and high-valent metal–oxo species) contributed to the degradation process, with singlet oxygen (<small><sup>1</sup></small>O<small><sub>2</sub></small>) identified as the predominant active species. Additionally, the composite exhibited superior performance in the hydrogen evolution reaction (HER), generating 130 μmol L<small><sup>−1</sup></small> mg<small><sup>−1</sup></small> min<small><sup>−1</sup></small> dissolved hydrogen under alkaline conditions (pH 10) and a potential of −1.2 V. This research demonstrates the potential of bimetallic MOFs combined with carbon materials for effective antibiotic removal and PMS activation. Furthermore, it highlights their promising capability in the HER, offering a multifaceted approach to addressing environmental pollution and promoting energy sustainability.</p>","PeriodicalId":73,"journal":{"name":"Environmental Science: Nano","volume":null,"pages":null},"PeriodicalIF":5.8000,"publicationDate":"2024-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synergistic bimetallic MOF-integrated MXene nanosheets for enhanced catalytic degradation of carbamazepine and hydrogen production: a dual-function approach for water remediation and energy applications†\",\"authors\":\"Van-Anh Thai, Thanh-Binh Nguyen, Chiu-Wen Chen, Xuan-Thanh Bui, Ruey-an Doong and Cheng-Di Dong\",\"doi\":\"10.1039/D4EN00324A\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >This study introduces a novel metallic MOF composite, MIL-100@ZIF-67, anchored on MXene nanosheets, designated as MIL-100@ZIF-67@MXene, for the enhanced degradation of carbamazepine (CBZ) and activation of peroxymonosulfate (PMS). The efficacy of the composite in CBZ degradation and the underlying reaction parameters and mechanisms were thoroughly investigated. Remarkably, the MIL-100@ZIF-67@MXene/PMS system achieved a 95% reduction of CBZ within 30 min under neutral pH conditions. Scavenger experiments and electron paramagnetic resonance (EPR) analysis confirmed that a combination of radicals (SO<small><sub>4</sub></small>˙<small><sup>−</sup></small>, ˙OH and O<small><sub>2</sub></small>˙<small><sup>−</sup></small>) and non-radicals (<small><sup>1</sup></small>O<small><sub>2</sub></small> and high-valent metal–oxo species) contributed to the degradation process, with singlet oxygen (<small><sup>1</sup></small>O<small><sub>2</sub></small>) identified as the predominant active species. Additionally, the composite exhibited superior performance in the hydrogen evolution reaction (HER), generating 130 μmol L<small><sup>−1</sup></small> mg<small><sup>−1</sup></small> min<small><sup>−1</sup></small> dissolved hydrogen under alkaline conditions (pH 10) and a potential of −1.2 V. This research demonstrates the potential of bimetallic MOFs combined with carbon materials for effective antibiotic removal and PMS activation. Furthermore, it highlights their promising capability in the HER, offering a multifaceted approach to addressing environmental pollution and promoting energy sustainability.</p>\",\"PeriodicalId\":73,\"journal\":{\"name\":\"Environmental Science: Nano\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":5.8000,\"publicationDate\":\"2024-07-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Environmental Science: Nano\",\"FirstCategoryId\":\"6\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2024/en/d4en00324a\",\"RegionNum\":2,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Environmental Science: Nano","FirstCategoryId":"6","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/en/d4en00324a","RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Synergistic bimetallic MOF-integrated MXene nanosheets for enhanced catalytic degradation of carbamazepine and hydrogen production: a dual-function approach for water remediation and energy applications†
This study introduces a novel metallic MOF composite, MIL-100@ZIF-67, anchored on MXene nanosheets, designated as MIL-100@ZIF-67@MXene, for the enhanced degradation of carbamazepine (CBZ) and activation of peroxymonosulfate (PMS). The efficacy of the composite in CBZ degradation and the underlying reaction parameters and mechanisms were thoroughly investigated. Remarkably, the MIL-100@ZIF-67@MXene/PMS system achieved a 95% reduction of CBZ within 30 min under neutral pH conditions. Scavenger experiments and electron paramagnetic resonance (EPR) analysis confirmed that a combination of radicals (SO4˙−, ˙OH and O2˙−) and non-radicals (1O2 and high-valent metal–oxo species) contributed to the degradation process, with singlet oxygen (1O2) identified as the predominant active species. Additionally, the composite exhibited superior performance in the hydrogen evolution reaction (HER), generating 130 μmol L−1 mg−1 min−1 dissolved hydrogen under alkaline conditions (pH 10) and a potential of −1.2 V. This research demonstrates the potential of bimetallic MOFs combined with carbon materials for effective antibiotic removal and PMS activation. Furthermore, it highlights their promising capability in the HER, offering a multifaceted approach to addressing environmental pollution and promoting energy sustainability.
期刊介绍:
Environmental Science: Nano serves as a comprehensive and high-impact peer-reviewed source of information on the design and demonstration of engineered nanomaterials for environment-based applications. It also covers the interactions between engineered, natural, and incidental nanomaterials with biological and environmental systems. This scope includes, but is not limited to, the following topic areas:
Novel nanomaterial-based applications for water, air, soil, food, and energy sustainability
Nanomaterial interactions with biological systems and nanotoxicology
Environmental fate, reactivity, and transformations of nanoscale materials
Nanoscale processes in the environment
Sustainable nanotechnology including rational nanomaterial design, life cycle assessment, risk/benefit analysis