Unsia Habib, Zahid Iqbal Khan, Zurina Binti Mohamad
{"title":"含有和不含 Joncryl® 相容剂的回收聚对苯二甲酸乙二酯/聚酰胺 11 混合物的兼容性和混溶性：机械、热和热机械特性的综合研究","authors":"Unsia Habib, Zahid Iqbal Khan, Zurina Binti Mohamad","doi":"10.1007/s13726-024-01357-y","DOIUrl":null,"url":null,"abstract":"<div><p>This innovative study explores the enhanced compatibility and miscibility of recycled polyethylene terephthalate and polyamide 11 (RPET/PA-11), particularly when modified with Joncryl<sup>®</sup>, a compatibilizer. This investigation marks the first venture into the detailed thermal and thermo-mechanical properties of the blends. Remarkably, the addition of 20% (by weight) PA-11 to RPET significantly boosts tensile strength from 18.5 ± 2.64 to 32.20 ± 4.95 MPa, flexural strength from 27.90 ± 3.17 to 46.75 ± 0.78 MPa, and impact strength from 110.53 to 147.12 J/m. Furthermore, introducing 2 phr Joncryl<sup>®</sup> further fortifies these strengths to 46.24 ± 0.87 MPa, 63.12 ± 4.75 MPa, and 667.68 ± 130.74 J/m, respectively. The study revealed a rise in the storage modulus of RPET from 1128 to 1298.5 MPa with 20% (by weight) of PA-11. Compatibility and miscibility assessments through Fourier transformation infrared (FTIR), dynamic mechanical analysis (DMA), differential scanning calorimetry (DSC), thermal gravimetric analysis (TGA), and scanning electron microscopy (SEM) validate the blend's uniformity. DSC reveals that the melting temperatures for RPET/PA-11 blends with varying PA-11 concentrations closely match the melting temperature of pure RPET, signifying stable thermal properties. DSC results confirmed that the T<sub>m1</sub> temperature for cold crystallization drops with the addition of Joncryl<sup>®</sup> content, suggesting improved interaction and miscibility between RPET and PA-11. TGA results disclosed that Joncryl<sup>®</sup> compatibilizer, especially at 2 phr, boosts the thermal stability of RPET/PA-11 blends by improving miscibility. The 2 phr Joncryl<sup>®</sup> blend was identified as the most robust in properties. This ground-breaking research highlights the potential of RPET in automotive and future advancements in polymer science.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":601,"journal":{"name":"Iranian Polymer Journal","volume":null,"pages":null},"PeriodicalIF":2.4000,"publicationDate":"2024-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Compatibility and miscibility of recycled polyethylene terephthalate/polyamide 11 blends with and without Joncryl® compatibilizer: a comprehensive study of mechanical, thermal, and thermomechanical properties\",\"authors\":\"Unsia Habib, Zahid Iqbal Khan, Zurina Binti Mohamad\",\"doi\":\"10.1007/s13726-024-01357-y\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>This innovative study explores the enhanced compatibility and miscibility of recycled polyethylene terephthalate and polyamide 11 (RPET/PA-11), particularly when modified with Joncryl<sup>®</sup>, a compatibilizer. This investigation marks the first venture into the detailed thermal and thermo-mechanical properties of the blends. Remarkably, the addition of 20% (by weight) PA-11 to RPET significantly boosts tensile strength from 18.5 ± 2.64 to 32.20 ± 4.95 MPa, flexural strength from 27.90 ± 3.17 to 46.75 ± 0.78 MPa, and impact strength from 110.53 to 147.12 J/m. Furthermore, introducing 2 phr Joncryl<sup>®</sup> further fortifies these strengths to 46.24 ± 0.87 MPa, 63.12 ± 4.75 MPa, and 667.68 ± 130.74 J/m, respectively. The study revealed a rise in the storage modulus of RPET from 1128 to 1298.5 MPa with 20% (by weight) of PA-11. Compatibility and miscibility assessments through Fourier transformation infrared (FTIR), dynamic mechanical analysis (DMA), differential scanning calorimetry (DSC), thermal gravimetric analysis (TGA), and scanning electron microscopy (SEM) validate the blend's uniformity. DSC reveals that the melting temperatures for RPET/PA-11 blends with varying PA-11 concentrations closely match the melting temperature of pure RPET, signifying stable thermal properties. DSC results confirmed that the T<sub>m1</sub> temperature for cold crystallization drops with the addition of Joncryl<sup>®</sup> content, suggesting improved interaction and miscibility between RPET and PA-11. TGA results disclosed that Joncryl<sup>®</sup> compatibilizer, especially at 2 phr, boosts the thermal stability of RPET/PA-11 blends by improving miscibility. The 2 phr Joncryl<sup>®</sup> blend was identified as the most robust in properties. 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Compatibility and miscibility of recycled polyethylene terephthalate/polyamide 11 blends with and without Joncryl® compatibilizer: a comprehensive study of mechanical, thermal, and thermomechanical properties
This innovative study explores the enhanced compatibility and miscibility of recycled polyethylene terephthalate and polyamide 11 (RPET/PA-11), particularly when modified with Joncryl®, a compatibilizer. This investigation marks the first venture into the detailed thermal and thermo-mechanical properties of the blends. Remarkably, the addition of 20% (by weight) PA-11 to RPET significantly boosts tensile strength from 18.5 ± 2.64 to 32.20 ± 4.95 MPa, flexural strength from 27.90 ± 3.17 to 46.75 ± 0.78 MPa, and impact strength from 110.53 to 147.12 J/m. Furthermore, introducing 2 phr Joncryl® further fortifies these strengths to 46.24 ± 0.87 MPa, 63.12 ± 4.75 MPa, and 667.68 ± 130.74 J/m, respectively. The study revealed a rise in the storage modulus of RPET from 1128 to 1298.5 MPa with 20% (by weight) of PA-11. Compatibility and miscibility assessments through Fourier transformation infrared (FTIR), dynamic mechanical analysis (DMA), differential scanning calorimetry (DSC), thermal gravimetric analysis (TGA), and scanning electron microscopy (SEM) validate the blend's uniformity. DSC reveals that the melting temperatures for RPET/PA-11 blends with varying PA-11 concentrations closely match the melting temperature of pure RPET, signifying stable thermal properties. DSC results confirmed that the Tm1 temperature for cold crystallization drops with the addition of Joncryl® content, suggesting improved interaction and miscibility between RPET and PA-11. TGA results disclosed that Joncryl® compatibilizer, especially at 2 phr, boosts the thermal stability of RPET/PA-11 blends by improving miscibility. The 2 phr Joncryl® blend was identified as the most robust in properties. This ground-breaking research highlights the potential of RPET in automotive and future advancements in polymer science.
期刊介绍：
Iranian Polymer Journal, a monthly peer-reviewed international journal, provides a continuous forum for the dissemination of the original research and latest advances made in science and technology of polymers, covering diverse areas of polymer synthesis, characterization, polymer physics, rubber, plastics and composites, processing and engineering, biopolymers, drug delivery systems and natural polymers to meet specific applications. Also contributions from nano-related fields are regarded especially important for its versatility in modern scientific development.
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