研究以手性宿主为重点的包涵复合物的核磁共振方法

IF 2.3 4区化学 Q2 Agricultural and Biological Sciences

Journal of Inclusion Phenomena and Macrocyclic Chemistry Pub Date : 2024-07-04 DOI:10.1007/s10847-024-01251-3

Sylwia Jopa, Jacek Wójcik, Andrzej Ejchart, Michał Nowakowski

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引用次数: 0

摘要

宿主是包涵复合物的关键组成部分，是一种环状低聚物，含有一个空腔，复合物中的另一种成分通过非共价作用力与该空腔结合。手性宿主尤其重要和有趣，因为它们可以研究特定的分子间相互作用和分子识别。本文简要评述了最重要的几类手性宿主及其理化性质。本综述的一个重要部分是对一些必要概念的描述，这些概念有助于理解用最适合研究包涵复合物的分析方法--核磁共振--来研究包涵复合物的性质和行为。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

NMR methods for studying inclusion complexes focused on chiral hosts

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NMR methods for studying inclusion complexes focused on chiral hosts

Hosts, a key component of inclusion complexes, are cyclic oligomeric compounds containing a cavity in which another component of the complex is bound by non-covalent forces. Chiral hosts are particularly important and interesting because they allow the study of specific intermolecular interactions and molecular recognition. The most important classes of chiral hosts and their physicochemical properties are briefly reviewed. An important part of this Review is the description of selected concepts necessary to understand the properties and behavior of inclusion complexes studied by the most suitable analytical method for studying inclusion complexes—nuclear magnetic resonance.

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来源期刊

Journal of Inclusion Phenomena and Macrocyclic Chemistry 化学-化学综合

CiteScore

3.30

自引率

8.70%

发文量

审稿时长

3-8 weeks

期刊介绍： The Journal of Inclusion Phenomena and Macrocyclic Chemistry is the premier interdisciplinary publication reporting on original research into all aspects of host-guest systems. Examples of specific areas of interest are: the preparation and characterization of new hosts and new host-guest systems, especially those involving macrocyclic ligands; crystallographic, spectroscopic, thermodynamic and theoretical studies; applications in chromatography and inclusion polymerization; enzyme modelling; molecular recognition and catalysis by inclusion compounds; intercalates in biological and non-biological systems, cyclodextrin complexes and their applications in the agriculture, flavoring, food and pharmaceutical industries; synthesis, characterization and applications of zeolites. The journal publishes primarily reports of original research and preliminary communications, provided the latter represent a significant advance in the understanding of inclusion science. Critical reviews dealing with recent advances in the field are a periodic feature of the journal.