Ziyi Xue, Hansong Wang, Jiaxuan Chen, Zidan Cao, Tao Li, Yu Li, Baozeng Ren
{"title":"不同温度下氟化钾在八种单一溶剂和四种二元溶剂混合物中的溶解度测定及相关性分析","authors":"Ziyi Xue, Hansong Wang, Jiaxuan Chen, Zidan Cao, Tao Li, Yu Li, Baozeng Ren","doi":"10.1021/acs.jced.4c00059","DOIUrl":null,"url":null,"abstract":"This study investigated the mole fraction solubility of potassium fluoride in eight single solvents (methanol, ethanol, n-propanol, n-butanol, 2-methoxyethanol, 2-ethoxyethanol, 2-propoxyethanol, and 1-methoxy-2-propanol) and four binary solvent mixtures (methanol + isopropanol, methanol + acetone, methanol + acetonitrile, and methanol + ethyl acetate) using the gravimetric method within the temperature range of 278.15 to 323.15 K (with 5 K intervals). The results demonstrated a gradual decrease in the solubility of potassium fluoride with increasing temperatures across all investigated solvent systems. For the four binary solvent mixtures studied, the solubility of potassium fluoride exhibited an increase with a higher mass fraction of methanol at a constant temperature. The experimental solubility data were correlated using four empirical models (van’t Hoff model, modified Apelblat model, CNIBS/R-K model, and Jouyban–Acree–Apelblat model), all of which exhibited excellent fitting performance. Comparison of different model fitting results revealed that the modified Apelblat model yielded lower values for relative deviation (ARD) and root-mean-square deviation (RMSD), indicating its superior fitting accuracy and suitability for fitting the experimental data of potassium fluoride in the selected solvents.","PeriodicalId":42,"journal":{"name":"Journal of Chemical & Engineering Data","volume":null,"pages":null},"PeriodicalIF":2.0000,"publicationDate":"2024-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Determination and Correlation of the Solubility of Potassium Fluoride in Eight Single Solvents and Four Binary Solvent Mixtures at Different Temperatures\",\"authors\":\"Ziyi Xue, Hansong Wang, Jiaxuan Chen, Zidan Cao, Tao Li, Yu Li, Baozeng Ren\",\"doi\":\"10.1021/acs.jced.4c00059\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"This study investigated the mole fraction solubility of potassium fluoride in eight single solvents (methanol, ethanol, n-propanol, n-butanol, 2-methoxyethanol, 2-ethoxyethanol, 2-propoxyethanol, and 1-methoxy-2-propanol) and four binary solvent mixtures (methanol + isopropanol, methanol + acetone, methanol + acetonitrile, and methanol + ethyl acetate) using the gravimetric method within the temperature range of 278.15 to 323.15 K (with 5 K intervals). The results demonstrated a gradual decrease in the solubility of potassium fluoride with increasing temperatures across all investigated solvent systems. For the four binary solvent mixtures studied, the solubility of potassium fluoride exhibited an increase with a higher mass fraction of methanol at a constant temperature. The experimental solubility data were correlated using four empirical models (van’t Hoff model, modified Apelblat model, CNIBS/R-K model, and Jouyban–Acree–Apelblat model), all of which exhibited excellent fitting performance. Comparison of different model fitting results revealed that the modified Apelblat model yielded lower values for relative deviation (ARD) and root-mean-square deviation (RMSD), indicating its superior fitting accuracy and suitability for fitting the experimental data of potassium fluoride in the selected solvents.\",\"PeriodicalId\":42,\"journal\":{\"name\":\"Journal of Chemical & Engineering Data\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.0000,\"publicationDate\":\"2024-07-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Chemical & Engineering Data\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://doi.org/10.1021/acs.jced.4c00059\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Chemical & Engineering Data","FirstCategoryId":"1","ListUrlMain":"https://doi.org/10.1021/acs.jced.4c00059","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Determination and Correlation of the Solubility of Potassium Fluoride in Eight Single Solvents and Four Binary Solvent Mixtures at Different Temperatures
This study investigated the mole fraction solubility of potassium fluoride in eight single solvents (methanol, ethanol, n-propanol, n-butanol, 2-methoxyethanol, 2-ethoxyethanol, 2-propoxyethanol, and 1-methoxy-2-propanol) and four binary solvent mixtures (methanol + isopropanol, methanol + acetone, methanol + acetonitrile, and methanol + ethyl acetate) using the gravimetric method within the temperature range of 278.15 to 323.15 K (with 5 K intervals). The results demonstrated a gradual decrease in the solubility of potassium fluoride with increasing temperatures across all investigated solvent systems. For the four binary solvent mixtures studied, the solubility of potassium fluoride exhibited an increase with a higher mass fraction of methanol at a constant temperature. The experimental solubility data were correlated using four empirical models (van’t Hoff model, modified Apelblat model, CNIBS/R-K model, and Jouyban–Acree–Apelblat model), all of which exhibited excellent fitting performance. Comparison of different model fitting results revealed that the modified Apelblat model yielded lower values for relative deviation (ARD) and root-mean-square deviation (RMSD), indicating its superior fitting accuracy and suitability for fitting the experimental data of potassium fluoride in the selected solvents.
期刊介绍:
The Journal of Chemical & Engineering Data is a monthly journal devoted to the publication of data obtained from both experiment and computation, which are viewed as complementary. It is the only American Chemical Society journal primarily concerned with articles containing data on the phase behavior and the physical, thermodynamic, and transport properties of well-defined materials, including complex mixtures of known compositions. While environmental and biological samples are of interest, their compositions must be known and reproducible. As a result, adsorption on natural product materials does not generally fit within the scope of Journal of Chemical & Engineering Data.