Li Li , Shu-Hao Li , Zhuo-Yu Li , Ning-Ning Zhang , Yang-Tao Yu , Jian-Ge Zeng , Yang Hua
{"title":"基于病毒的刺激响应型晶体混合材料的研究进展","authors":"Li Li , Shu-Hao Li , Zhuo-Yu Li , Ning-Ning Zhang , Yang-Tao Yu , Jian-Ge Zeng , Yang Hua","doi":"10.1016/j.ccr.2024.216064","DOIUrl":null,"url":null,"abstract":"<div><p>Stimuli-responsive materials are a new class of smart materials that have received continuous scientific attention because they can exhibit rapid responses (with corresponding physical or chemical changes) under environmental stimuli. Among them, crystalline chromic hybrid materials that exhibit reversible color changes have become good candidates due to their variable structures as well as their highly designable and interesting properties under external stimuli such as light, heat, pressure, or electricity. A recent investigation found that viologens (4,4′-bipyridine derivatives) have been widely used for the construction of organic and inorganic hybrid chromic materials because of their good electron-deficient and redox properties. However, the development of multifunctional stimuli-responsive chromic materials remains a significant challenge. The purpose of this article is to propose design strategies for constructing viologen-based functionalized chromic materials that respond to physical, chemical, and multiple stimuli, reveal the structure–function relationship of crystalline chromic hybrids, and summarize the application potential of these chromic materials. This review will provide valuable assistance for researchers designing synthetic viologen-based chromic hybrid materials and facilitate new discoveries.</p></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":null,"pages":null},"PeriodicalIF":20.3000,"publicationDate":"2024-07-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Advances in viologen-based stimulus-responsive crystalline hybrid materials\",\"authors\":\"Li Li , Shu-Hao Li , Zhuo-Yu Li , Ning-Ning Zhang , Yang-Tao Yu , Jian-Ge Zeng , Yang Hua\",\"doi\":\"10.1016/j.ccr.2024.216064\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Stimuli-responsive materials are a new class of smart materials that have received continuous scientific attention because they can exhibit rapid responses (with corresponding physical or chemical changes) under environmental stimuli. Among them, crystalline chromic hybrid materials that exhibit reversible color changes have become good candidates due to their variable structures as well as their highly designable and interesting properties under external stimuli such as light, heat, pressure, or electricity. A recent investigation found that viologens (4,4′-bipyridine derivatives) have been widely used for the construction of organic and inorganic hybrid chromic materials because of their good electron-deficient and redox properties. However, the development of multifunctional stimuli-responsive chromic materials remains a significant challenge. The purpose of this article is to propose design strategies for constructing viologen-based functionalized chromic materials that respond to physical, chemical, and multiple stimuli, reveal the structure–function relationship of crystalline chromic hybrids, and summarize the application potential of these chromic materials. This review will provide valuable assistance for researchers designing synthetic viologen-based chromic hybrid materials and facilitate new discoveries.</p></div>\",\"PeriodicalId\":289,\"journal\":{\"name\":\"Coordination Chemistry Reviews\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":20.3000,\"publicationDate\":\"2024-07-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Coordination Chemistry Reviews\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0010854524004107\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Coordination Chemistry Reviews","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0010854524004107","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Advances in viologen-based stimulus-responsive crystalline hybrid materials
Stimuli-responsive materials are a new class of smart materials that have received continuous scientific attention because they can exhibit rapid responses (with corresponding physical or chemical changes) under environmental stimuli. Among them, crystalline chromic hybrid materials that exhibit reversible color changes have become good candidates due to their variable structures as well as their highly designable and interesting properties under external stimuli such as light, heat, pressure, or electricity. A recent investigation found that viologens (4,4′-bipyridine derivatives) have been widely used for the construction of organic and inorganic hybrid chromic materials because of their good electron-deficient and redox properties. However, the development of multifunctional stimuli-responsive chromic materials remains a significant challenge. The purpose of this article is to propose design strategies for constructing viologen-based functionalized chromic materials that respond to physical, chemical, and multiple stimuli, reveal the structure–function relationship of crystalline chromic hybrids, and summarize the application potential of these chromic materials. This review will provide valuable assistance for researchers designing synthetic viologen-based chromic hybrid materials and facilitate new discoveries.
期刊介绍:
Coordination Chemistry Reviews offers rapid publication of review articles on current and significant topics in coordination chemistry, encompassing organometallic, supramolecular, theoretical, and bioinorganic chemistry. It also covers catalysis, materials chemistry, and metal-organic frameworks from a coordination chemistry perspective. Reviews summarize recent developments or discuss specific techniques, welcoming contributions from both established and emerging researchers.
The journal releases special issues on timely subjects, including those featuring contributions from specific regions or conferences. Occasional full-length book articles are also featured. Additionally, special volumes cover annual reviews of main group chemistry, transition metal group chemistry, and organometallic chemistry. These comprehensive reviews are vital resources for those engaged in coordination chemistry, further establishing Coordination Chemistry Reviews as a hub for insightful surveys in inorganic and physical inorganic chemistry.