Fei Gao , Xiaokang Wang , Wenmiao Chen , Wenjing Wang , Weidong Fan , Zixi Kang , Rongming Wang , Hailing Guo , Qin Yue , Daqiang Yuan , Daofeng Sun
{"title":"用于氢同位素分离的金属有机框架","authors":"Fei Gao , Xiaokang Wang , Wenmiao Chen , Wenjing Wang , Weidong Fan , Zixi Kang , Rongming Wang , Hailing Guo , Qin Yue , Daqiang Yuan , Daofeng Sun","doi":"10.1016/j.ccr.2024.216047","DOIUrl":null,"url":null,"abstract":"<div><p>In the face of escalating global energy demands, deuterium (D<sub>2</sub>) is receiving increasing attention as a clean and efficient energy source. However, the challenge of separating deuterium from hydrogen (H<sub>2</sub>) arises due to their considerable physical and chemical similarities. The use of porous materials to separate D<sub>2</sub>/H<sub>2</sub>, which has either high separation efficiency or ideal D<sub>2</sub> capacity and even approaches a good balance of efficiency and capacity in the case of some advanced porous materials, is one of the most promising alternative technologies for hydrogen isotope separation. Metal-organic framework (MOF) materials, with their diverse structures, highly adjustable pore channels, and surface functionality, offer tremendous potential in the field of D<sub>2</sub>/H<sub>2</sub> separation. In this review, we systematically summarize the research progress of MOFs in D<sub>2</sub>/H<sub>2</sub> separation and discuss their advantages, challenges, and future directions from the perspectives of separation mechanisms and separation technology.</p></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":null,"pages":null},"PeriodicalIF":20.3000,"publicationDate":"2024-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Metal-organic frameworks for hydrogen isotopes separation\",\"authors\":\"Fei Gao , Xiaokang Wang , Wenmiao Chen , Wenjing Wang , Weidong Fan , Zixi Kang , Rongming Wang , Hailing Guo , Qin Yue , Daqiang Yuan , Daofeng Sun\",\"doi\":\"10.1016/j.ccr.2024.216047\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In the face of escalating global energy demands, deuterium (D<sub>2</sub>) is receiving increasing attention as a clean and efficient energy source. However, the challenge of separating deuterium from hydrogen (H<sub>2</sub>) arises due to their considerable physical and chemical similarities. The use of porous materials to separate D<sub>2</sub>/H<sub>2</sub>, which has either high separation efficiency or ideal D<sub>2</sub> capacity and even approaches a good balance of efficiency and capacity in the case of some advanced porous materials, is one of the most promising alternative technologies for hydrogen isotope separation. Metal-organic framework (MOF) materials, with their diverse structures, highly adjustable pore channels, and surface functionality, offer tremendous potential in the field of D<sub>2</sub>/H<sub>2</sub> separation. In this review, we systematically summarize the research progress of MOFs in D<sub>2</sub>/H<sub>2</sub> separation and discuss their advantages, challenges, and future directions from the perspectives of separation mechanisms and separation technology.</p></div>\",\"PeriodicalId\":289,\"journal\":{\"name\":\"Coordination Chemistry Reviews\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":20.3000,\"publicationDate\":\"2024-07-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Coordination Chemistry Reviews\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S001085452400393X\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Coordination Chemistry Reviews","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S001085452400393X","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Metal-organic frameworks for hydrogen isotopes separation
In the face of escalating global energy demands, deuterium (D2) is receiving increasing attention as a clean and efficient energy source. However, the challenge of separating deuterium from hydrogen (H2) arises due to their considerable physical and chemical similarities. The use of porous materials to separate D2/H2, which has either high separation efficiency or ideal D2 capacity and even approaches a good balance of efficiency and capacity in the case of some advanced porous materials, is one of the most promising alternative technologies for hydrogen isotope separation. Metal-organic framework (MOF) materials, with their diverse structures, highly adjustable pore channels, and surface functionality, offer tremendous potential in the field of D2/H2 separation. In this review, we systematically summarize the research progress of MOFs in D2/H2 separation and discuss their advantages, challenges, and future directions from the perspectives of separation mechanisms and separation technology.
期刊介绍:
Coordination Chemistry Reviews offers rapid publication of review articles on current and significant topics in coordination chemistry, encompassing organometallic, supramolecular, theoretical, and bioinorganic chemistry. It also covers catalysis, materials chemistry, and metal-organic frameworks from a coordination chemistry perspective. Reviews summarize recent developments or discuss specific techniques, welcoming contributions from both established and emerging researchers.
The journal releases special issues on timely subjects, including those featuring contributions from specific regions or conferences. Occasional full-length book articles are also featured. Additionally, special volumes cover annual reviews of main group chemistry, transition metal group chemistry, and organometallic chemistry. These comprehensive reviews are vital resources for those engaged in coordination chemistry, further establishing Coordination Chemistry Reviews as a hub for insightful surveys in inorganic and physical inorganic chemistry.