利用回收采石场粉尘开发陶瓷中空纤维:探索其作为 ZIF-8 膜在气体分离中的支持物的特性

IF 1.8 4区 材料科学 Q2 MATERIALS SCIENCE, CERAMICS
Nur Ain Shazwani Roslee Ab. Jamal, Nur Hidayati Othman, Nurina Adriana Abd Razak, Nur Hashimah Alias, Muhammad Shafiq Mat Shayuti, Fauziah Marpani, Mohd Rizuan Mohd Razlan, Aidah Jumahat, Mohd Hafiz Dzarfan Othman, Woei Jye Lau, Mohd Ridhwan Adam, Mohammad Arif Budiman Pauzan, Ahmad Fauzi Ismail
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引用次数: 0

摘要

这项工作研究了涂覆在由采石场粉尘(QD)开发的低成本陶瓷中空纤维(CHF)支撑物上的 ZIF-8 膜的性能。首先利用相位反转和烧结技术制造了陶瓷中空纤维(CHF)。系统评估了孔内流体流速(6-10 ml-min- 1)和烧结温度(1050-1150 °C)对最终 CHF 形状和机械强度的影响。当使用较长的气隙距离时,可观察到较大的指状大空腔结构。较高的烧结温度会因孔隙致密化而提高 CHF 的机械性能,但同时也会导致 CHF 的多孔性降低,从而影响其渗透通量。基于 QD 的 CHF 所需的烧结温度相对较低(1150 °C),从而降低了能耗,这对未来的商业化具有经济吸引力。通过控制镀膜溶液中的 ZIF-8 含量(0.4-1.6 wt%),镀上了一层均匀且镀层良好的 ZIF-8 选择层,形成了石矿粉陶瓷中空纤维膜(QD-CHFM)。在 2-6 巴的条件下进行了单次气体渗透研究,结果表明,当 ZIF-8 的负载量较低时,气体的渗透率较大,尤其是二氧化碳(1.19 × 10- 4 cm3(STP)-cm-cm- 2-s- 1-cm- 1-Hg-1)。进一步增加涂层溶液中的 ZIF-8 浓度会导致团聚,同时增加路径曲折度。因此,气体在膜上的扩散速率降低。据观察,ZIF-8/QD-CHFM 的性能与文献中其他陶瓷膜的性能相似。这项工作表明,ZIF-8 的负载会显著影响气体分离性能。此外,重新利用 QDs 作为陶瓷膜制造的原材料有助于减少处理问题,并降低陶瓷膜的总体成本,以利于未来的发展。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Development of ceramic hollow fiber from recycled quarry dust: exploring its properties as a support for ZIF-8 membrane in gas separation

Development of ceramic hollow fiber from recycled quarry dust: exploring its properties as a support for ZIF-8 membrane in gas separation

This work investigated the performances of ZIF-8 membranes coated on a low-cost ceramic hollow fiber (CHF) support developed from quarry dust (QD). The ceramic hollow fiber (CHF) was first fabricated using phase inversion and sintering techniques. The effects of the bore fluid flow rate (6–10 ml·min− 1) and sintering temperature (1050–1150 °C) on the morphology and mechanical strength of the final CHF were systematically evaluated. A larger finger-like macrovoid structure was observed when a longer air gap distance was used. A higher sintering temperature enhances the mechanical properties of CHFs due to pore densification, but it also leads to a less porous CHF, which can affect their permeation flux. The relatively low sintering temperature needed for QD-based CHF (< 1150 °C) leads to a reduction in energy consumption, which is economically attractive for future commercialization. By controlling the ZIF-8 loading (0.4–1.6 wt%) in the coating solution, a uniform and well-coated ZIF-8 selective layer was coated to form a quarry dust ceramic hollow fiber membrane (QD-CHFM). A single gas permeation study was conducted at 2–6 bar, and it was observed that the permeability of gases was greater when the ZIF-8 loading was lower, particularly for CO2 (1.19 × 10− 4 cm3(STP)·cm·cm− 2·s− 1·cm− 1·Hg− 1). A further increase in the ZIF-8 concentration in the coating solution caused agglomeration, which simultaneously increased the path tortuosity. Therefore, the gas diffusion rate across the membrane decreased. The performances of ZIF-8/QD-CHFM were observed to be similar to those of other ceramic membranes available in the literature. This work indicated that ZIF-8 loading could significantly affect gas separation performance. In addition, reutilizing QDs as a raw material for ceramic membrane fabrication can help reduce disposal issues and reduce the overall cost of ceramic membranes for future development.

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来源期刊
Journal of the Australian Ceramic Society
Journal of the Australian Ceramic Society Materials Science-Materials Chemistry
CiteScore
3.70
自引率
5.30%
发文量
123
期刊介绍: Publishes high quality research and technical papers in all areas of ceramic and related materials Spans the broad and growing fields of ceramic technology, material science and bioceramics Chronicles new advances in ceramic materials, manufacturing processes and applications Journal of the Australian Ceramic Society since 1965 Professional language editing service is available through our affiliates Nature Research Editing Service and American Journal Experts at the author''s cost and does not guarantee that the manuscript will be reviewed or accepted
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