{"title":"深入了解用酶水解残渣代替苯酚制备苯酚-甲醛粘合剂的替代效果","authors":"Zhenwen Peng, Aldo Joao Cárdenas-Oscanoa, Youming Dong, Juan He, Caoxing Huang","doi":"10.1002/adsu.202400289","DOIUrl":null,"url":null,"abstract":"<p>In order to valorize the enzymatic hydrolysis residues (EHR) from the bioethanol industry, this work studies the effects on the structure, properties as well as shear resistance of EHR-based phenol formaldehyde (EPF) adhesives prepared from EHR instead of commercial phenol. 2D heteronuclear signal quantum coherence NMR (2D HSQC NMR) and <sup>31</sup>P NMR analysis reveal that lignin in EHR (EHL) possesses a high amount of G and H units which contain 1.9 mmol g<sup>−1</sup> active sites (reaction site with formaldehyde). Fourier-transform infrared (FT-IR) characterization shows that the instead proportions of EHR with 5–30% in EPF adhesives do not show great influence on the chemical structure type and main functional groups of the prepared adhesives. The shear strength measurement results show that the strength of the 10%-EPF adhesive is significantly improved by 29% compared to phenol-formaldehyde (PF) adhesive, which is due to EHL in adhesives enhanced the cross-linking of polymer chains. This work emphasizes the potential benefits of using industrial EHR to develop cost-effective phenol formaldehyde adhesive preparation schemes, therefore giving an additional value to waste from biorefineries.</p>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"8 11","pages":""},"PeriodicalIF":6.5000,"publicationDate":"2024-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Insight Understanding the Replacement Effect of Enzymatic-Hydrolysis Residue Instead of Phenol for Preparing Phenol-Formaldehyde Adhesive\",\"authors\":\"Zhenwen Peng, Aldo Joao Cárdenas-Oscanoa, Youming Dong, Juan He, Caoxing Huang\",\"doi\":\"10.1002/adsu.202400289\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>In order to valorize the enzymatic hydrolysis residues (EHR) from the bioethanol industry, this work studies the effects on the structure, properties as well as shear resistance of EHR-based phenol formaldehyde (EPF) adhesives prepared from EHR instead of commercial phenol. 2D heteronuclear signal quantum coherence NMR (2D HSQC NMR) and <sup>31</sup>P NMR analysis reveal that lignin in EHR (EHL) possesses a high amount of G and H units which contain 1.9 mmol g<sup>−1</sup> active sites (reaction site with formaldehyde). Fourier-transform infrared (FT-IR) characterization shows that the instead proportions of EHR with 5–30% in EPF adhesives do not show great influence on the chemical structure type and main functional groups of the prepared adhesives. The shear strength measurement results show that the strength of the 10%-EPF adhesive is significantly improved by 29% compared to phenol-formaldehyde (PF) adhesive, which is due to EHL in adhesives enhanced the cross-linking of polymer chains. This work emphasizes the potential benefits of using industrial EHR to develop cost-effective phenol formaldehyde adhesive preparation schemes, therefore giving an additional value to waste from biorefineries.</p>\",\"PeriodicalId\":7294,\"journal\":{\"name\":\"Advanced Sustainable Systems\",\"volume\":\"8 11\",\"pages\":\"\"},\"PeriodicalIF\":6.5000,\"publicationDate\":\"2024-06-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advanced Sustainable Systems\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/adsu.202400289\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Sustainable Systems","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/adsu.202400289","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY","Score":null,"Total":0}
引用次数: 0
摘要
为了使生物乙醇工业中的酶水解残留物(EHR)发挥价值,这项工作研究了用 EHR 代替商用苯酚制备的基于 EHR 的苯酚甲醛(EPF)粘合剂对其结构、性能和抗剪切性的影响。二维异核信号量子相干核磁共振(2D HSQC NMR)和 31P NMR 分析表明,EHR(EHL)中的木质素具有大量的 G 和 H 单元,其中包含 1.9 mmol g-1 的活性位点(与甲醛的反应位点)。傅立叶变换红外(FT-IR)表征表明,EPF 粘合剂中 EHR 的比例为 5-30%,对所制备粘合剂的化学结构类型和主要官能团的影响不大。剪切强度测量结果表明,与苯酚-甲醛(PF)粘合剂相比,10%-EPF 粘合剂的强度显著提高了 29%,这是由于粘合剂中的 EHL 增强了聚合物链的交联。这项工作强调了利用工业 EHR 开发具有成本效益的苯酚甲醛粘合剂制备方案的潜在益处,从而为生物炼制厂的废物带来了额外的价值。
Insight Understanding the Replacement Effect of Enzymatic-Hydrolysis Residue Instead of Phenol for Preparing Phenol-Formaldehyde Adhesive
In order to valorize the enzymatic hydrolysis residues (EHR) from the bioethanol industry, this work studies the effects on the structure, properties as well as shear resistance of EHR-based phenol formaldehyde (EPF) adhesives prepared from EHR instead of commercial phenol. 2D heteronuclear signal quantum coherence NMR (2D HSQC NMR) and 31P NMR analysis reveal that lignin in EHR (EHL) possesses a high amount of G and H units which contain 1.9 mmol g−1 active sites (reaction site with formaldehyde). Fourier-transform infrared (FT-IR) characterization shows that the instead proportions of EHR with 5–30% in EPF adhesives do not show great influence on the chemical structure type and main functional groups of the prepared adhesives. The shear strength measurement results show that the strength of the 10%-EPF adhesive is significantly improved by 29% compared to phenol-formaldehyde (PF) adhesive, which is due to EHL in adhesives enhanced the cross-linking of polymer chains. This work emphasizes the potential benefits of using industrial EHR to develop cost-effective phenol formaldehyde adhesive preparation schemes, therefore giving an additional value to waste from biorefineries.
期刊介绍:
Advanced Sustainable Systems, a part of the esteemed Advanced portfolio, serves as an interdisciplinary sustainability science journal. It focuses on impactful research in the advancement of sustainable, efficient, and less wasteful systems and technologies. Aligned with the UN's Sustainable Development Goals, the journal bridges knowledge gaps between fundamental research, implementation, and policy-making. Covering diverse topics such as climate change, food sustainability, environmental science, renewable energy, water, urban development, and socio-economic challenges, it contributes to the understanding and promotion of sustainable systems.