Noriyuki Tsukahara, Ryuichi Arafune and Jun Yoshinobu
{"title":"二维金属有机网络上的元素特异性团簇生长","authors":"Noriyuki Tsukahara, Ryuichi Arafune and Jun Yoshinobu","doi":"10.35848/1347-4065/ad50b3","DOIUrl":null,"url":null,"abstract":"A porous two-dimensional metal–organic network (2D-MON) on a substrate captures deposited metal atoms and metal clusters growing in the pores of the 2D-MON. We found that the growth mechanisms of Ag, In, and Pd clusters in the 2D-MON synthesized from 1,3,5-tris(4-bromophenyl)benzene molecules on Ag(111) are different from each other, and the difference derives from the interaction of an adatom with the 2D-MON. Ag and Pd clusters grow from the 2D-MON since the interaction of Ag and Pd adatoms with the 2D-MON is attractive. In clusters grow inside of the pores of the 2D-MON since the interaction between an In adatom and the 2D-MON is repulsive. The growth process of metal clusters is determined by the element-specific behavior of metal adatoms in the pores, taking into account interactions with the 2D-MON.","PeriodicalId":14741,"journal":{"name":"Japanese Journal of Applied Physics","volume":null,"pages":null},"PeriodicalIF":1.5000,"publicationDate":"2024-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Element-specific cluster growth on the two-dimensional metal–organic network\",\"authors\":\"Noriyuki Tsukahara, Ryuichi Arafune and Jun Yoshinobu\",\"doi\":\"10.35848/1347-4065/ad50b3\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A porous two-dimensional metal–organic network (2D-MON) on a substrate captures deposited metal atoms and metal clusters growing in the pores of the 2D-MON. We found that the growth mechanisms of Ag, In, and Pd clusters in the 2D-MON synthesized from 1,3,5-tris(4-bromophenyl)benzene molecules on Ag(111) are different from each other, and the difference derives from the interaction of an adatom with the 2D-MON. Ag and Pd clusters grow from the 2D-MON since the interaction of Ag and Pd adatoms with the 2D-MON is attractive. In clusters grow inside of the pores of the 2D-MON since the interaction between an In adatom and the 2D-MON is repulsive. The growth process of metal clusters is determined by the element-specific behavior of metal adatoms in the pores, taking into account interactions with the 2D-MON.\",\"PeriodicalId\":14741,\"journal\":{\"name\":\"Japanese Journal of Applied Physics\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.5000,\"publicationDate\":\"2024-06-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Japanese Journal of Applied Physics\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://doi.org/10.35848/1347-4065/ad50b3\",\"RegionNum\":4,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"PHYSICS, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Japanese Journal of Applied Physics","FirstCategoryId":"101","ListUrlMain":"https://doi.org/10.35848/1347-4065/ad50b3","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"PHYSICS, APPLIED","Score":null,"Total":0}
Element-specific cluster growth on the two-dimensional metal–organic network
A porous two-dimensional metal–organic network (2D-MON) on a substrate captures deposited metal atoms and metal clusters growing in the pores of the 2D-MON. We found that the growth mechanisms of Ag, In, and Pd clusters in the 2D-MON synthesized from 1,3,5-tris(4-bromophenyl)benzene molecules on Ag(111) are different from each other, and the difference derives from the interaction of an adatom with the 2D-MON. Ag and Pd clusters grow from the 2D-MON since the interaction of Ag and Pd adatoms with the 2D-MON is attractive. In clusters grow inside of the pores of the 2D-MON since the interaction between an In adatom and the 2D-MON is repulsive. The growth process of metal clusters is determined by the element-specific behavior of metal adatoms in the pores, taking into account interactions with the 2D-MON.
期刊介绍:
The Japanese Journal of Applied Physics (JJAP) is an international journal for the advancement and dissemination of knowledge in all fields of applied physics. JJAP is a sister journal of the Applied Physics Express (APEX) and is published by IOP Publishing Ltd on behalf of the Japan Society of Applied Physics (JSAP).
JJAP publishes articles that significantly contribute to the advancements in the applications of physical principles as well as in the understanding of physics in view of particular applications in mind. Subjects covered by JJAP include the following fields:
• Semiconductors, dielectrics, and organic materials
• Photonics, quantum electronics, optics, and spectroscopy
• Spintronics, superconductivity, and strongly correlated materials
• Device physics including quantum information processing
• Physics-based circuits and systems
• Nanoscale science and technology
• Crystal growth, surfaces, interfaces, thin films, and bulk materials
• Plasmas, applied atomic and molecular physics, and applied nuclear physics
• Device processing, fabrication and measurement technologies, and instrumentation
• Cross-disciplinary areas such as bioelectronics/photonics, biosensing, environmental/energy technologies, and MEMS